Trimethylamine ethylpiperazine: An effective way to reduce the cost of polyurethane products
Introduction
Polyurethane (PU) is a polymer material widely used in the fields of construction, automobile, furniture, shoe materials, etc. Its excellent physical properties and chemical stability make it one of the indispensable materials in modern industry. However, with the rise in raw material prices and the increase in environmental protection requirements, how to reduce the production cost of polyurethane products has become the focus of industry attention. This article will introduce an effective cost reduction method in detail – using Trimethylamine Ethyl Piperazine (TMAEP) as a catalyst and crosslinker in polyurethane production.
I. Basic properties of trimethylamine ethylpiperazine
1.1 Chemical structure
The chemical structure of trimethylamine ethylpiperazine is as follows:
CH3
|
N-CH2-CH2-N-CH2-CH2-CH2-N
| |
CH3 CH3
1.2 Physical Properties
Properties | Value/Description |
---|---|
Molecular formula | C8H18N2 |
Molecular Weight | 142.24 g/mol |
Appearance | Colorless to light yellow liquid |
Boiling point | 210-215°C |
Density | 0.92 g/cm³ |
Solution | Easy soluble in water and organic solvents |
Flashpoint | 85°C |
1.3 Chemical Properties
Trimethylamine ethylpiperazine is a strong basic compound with good catalytic activity and cross-linking properties. The amine group and piperazine ring in its molecular structure make it exhibit excellent catalytic effect in the polyurethane reaction.
Application of bis, trimethylamine ethylpiperazine in polyurethane production
2.1 Catalyst action
Trimethylamine ethylpiperazine as a catalyst can significantly accelerate polyurethaneThe reaction rate of isocyanate and polyol in the reaction. The catalytic mechanism is as follows:
- Activated isocyanate: The amine group in trimethylamine ethylpiperazine can form hydrogen bonds with nitrogen atoms in isocyanate, thereby activating isocyanate molecules.
- Promote reaction: The activated isocyanate molecules are more likely to react with polyols to form polyurethane chains.
2.2 Effect of crosslinking agent
Trimethylamine ethylpiperazine can also be used as a crosslinking agent to react with isocyanate groups in the polyurethane chain by reacting multiple active sites in its molecular structure to form a three-dimensional network structure, thereby improving the mechanical properties and thermal stability of polyurethane products.
2.3 Cost reduction effect
The use of trimethylamine ethylpiperazine as a catalyst and crosslinking agent can significantly reduce the production cost of polyurethane products. Specifically manifested in the following aspects:
- Reduce the amount of catalyst: Trimethylamine ethylpiperazine has high catalytic efficiency and low usage, thereby reducing the cost of the catalyst.
- Shorten the reaction time: Due to its efficient catalytic action, the reaction time of polyurethane is shortened, the production efficiency is improved, and production energy consumption is reduced.
- Improving product performance: Through cross-linking, the mechanical properties and thermal stability of polyurethane products are improved, reducing the cost of subsequent processing and modification.
Triple and Trimethylamine Ethylpiperazine Use Method
3.1 Addition amount
The amount of trimethylamine ethylpiperazine is usually added in an amount of 0.1% to 0.5% of the total weight of the polyurethane. The specific amount of addition can be adjusted according to production requirements and product performance requirements.
3.2 Adding method
Trimethylamine ethylpiperazine can be added to the polyurethane reaction system by:
- Direct addition: Add trimethylamine ethylpiperazine directly to the polyol or isocyanate, stir evenly before reaction.
- Premix and addition: Premix trimethylamine ethylpiperazine with polyol or isocyanate to form a premix and then react.
3.3 Reaction conditions
The best reaction conditions for trimethylamine ethylpiperazine in polyurethane reaction are as follows:
conditions | Value/Description |
---|---|
Reaction temperature | 60-80°C |
Reaction time | 10-30 minutes |
Agitation speed | 500-1000 rpm |
IV. Effect of trimethylamine ethylpiperazine on the performance of polyurethane products
4.1 Mechanical properties
The use of trimethylamine ethylpiperazine as a catalyst and crosslinking agent can significantly improve the mechanical properties of polyurethane products. Specifically manifested in the following aspects:
- Tenable Strength: Through cross-linking, the tensile strength of polyurethane products is increased by 10%-20%.
- Elongation of Break: The elongation of break of polyurethane products after crosslinking increases by 5%-10%.
- Hardness: The cross-linking effect increases the hardness of polyurethane products by 5%-15%.
4.2 Thermal Stability
The crosslinking effect of trimethylamine ethylpiperazine also improves the thermal stability of polyurethane products. Specifically manifested in the following aspects:
- Thermal deformation temperature: The thermal deformation temperature of crosslinked polyurethane products increases by 10%-20%.
- Thermal decomposition temperature: The thermal decomposition temperature of crosslinked polyurethane products increases by 5%-10%.
4.3 Chemical resistance
The crosslinking effect of trimethylamine ethylpiperazine also improves the chemical resistance of polyurethane products. Specifically manifested in the following aspects:
- Acidal and alkali resistance: The stability of crosslinked polyurethane products in acidic and alkaline environments is improved.
- Solvent Resistance: The stability of crosslinked polyurethane products in organic solvents is improved.
V. Market prospects of trimethylamine ethylpiperazine
5.1 Market demand
With the wide application of polyurethane products in construction, automobiles, furniture and other fields, the demand for efficient catalysts and crosslinking agents is increasing. As a high-efficiency, low-cost catalyst and crosslinking agent, trimethylamine ethylpiperazine has broad market prospects.
5.2 Technology development trends
In the future, the technological development trend of trimethylamine ethylpiperazine will focus on the following aspects:
- Green and Environmental Protection: Develop a more environmentally friendly trimethylamine ethylpiperazine production process to reduce the impact on the environment.
- High-efficiency Catalysis: Further improve the catalytic efficiency of trimethylamine ethylpiperazine and reduce the amount of use.
- Multifunctionalization: Develop trimethylamine ethylpiperazine with multiple functions, such as both catalytic and crosslinking functions.
5.3 Market competitiveness
The competitiveness of trimethylamine ethylpiperazine in the market is mainly reflected in the following aspects:
- Cost Advantages: The production cost of trimethylamine ethylpiperazine is low and has a small amount of use, and has a significant cost advantage.
- Performance Advantages: Trimethylamine ethylpiperazine can significantly improve the mechanical properties and thermal stability of polyurethane products, and has significant performance advantages.
- Widely used: Trimethylamine ethylpiperazine has wide application prospects in construction, automobile, furniture and other fields.
VI. Conclusion
Trimethylamine ethylpiperazine, as a high-efficiency, low-cost catalyst and crosslinking agent, has important application value in the production of polyurethane products. Through its efficient catalytic action and cross-linking action, the production cost of polyurethane products can be significantly reduced and the mechanical properties and thermal stability of the products can be improved. In the future, with the continuous advancement of technology and the increase in market demand, the application prospects of trimethylamine ethylpiperazine in the production of polyurethane products will be broader.
Appendix: Trimethylamine ethylpiperazine product parameter table
parameters | Value/Description |
---|---|
Molecular formula | C8H18N2 |
Molecular Weight | 142.24 g/mol |
Appearance | Colorless to light yellow liquid |
Boiling point | 210-215°C |
Density | 0.92 g/cm³ |
Solution | Easy soluble in water and organic solvents |
Flashpoint | 85°C |
Additional amount | 0.1%-0.5% |
Reaction temperature | 60-80°C |
Reaction time | 10-30 minutes |
Agitation speed | 500-1000 rpm |
Through the above detailed introduction and analysis, I believe that readers have a deeper understanding of the application of trimethylamine ethylpiperazine in reducing the cost of polyurethane products. I hope this article can provide valuable reference and guidance for polyurethane product manufacturers and related technical personnel.
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