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Experimental results of zinc isoctanoate maintaining stability under different temperature conditions

2月 13th, 2025 News

Overview of zinc isoctanoate and its application background

Zinc 2-Ethylhexanoate, with the chemical formula Zn(C8H15O2)2, is an important organic zinc compound. It consists of zinc ions and isoctoate ions, and has good thermal and chemical stability. Zinc isoctanoate is widely used in many fields, especially in the coatings, plastics, rubbers, lubricants and other industries, and plays an important role as a catalyst, stabilizer and anti-aging agent.

In the coating industry, zinc isoctanoate is used as a drying agent, which can accelerate the drying process of oil-based coatings and improve the hardness and durability of the coating. Its low volatility and good dispersion make it an ideal additive. In addition, zinc isoctanoate also has excellent anti-corrosion properties, which can effectively prevent corrosion on metal surfaces and extend the service life of the paint.

In the plastics and rubber industries, zinc isoctanoate isoprotein, as a thermal stabilizer, can prevent the material from degrading or discoloring during high-temperature processing. It can also improve the mechanical properties and anti-aging ability of the product, and extend the service life of the product. Especially in PVC (polyvinyl chloride) materials, zinc isoctanoate is widely used and can significantly improve its processing and physical properties.

In the field of lubricants, zinc isoctanoate, as an efficient extreme pressure additive, can provide excellent lubricating effect under high temperature and high pressure conditions, reducing friction and wear. It also has good oxidation resistance, can extend the service life of lubricant and reduce maintenance costs.

In addition to the above applications, zinc isoctanoate also has certain application prospects in the fields of medicine, cosmetics, electronic chemicals, etc. For example, in the pharmaceutical industry, it can act as a drug carrier to improve the stability and bioavailability of drugs; in cosmetics, it can act as a synergist for sunscreens to enhance the protective effect of the product.

In short, zinc isoctanoate, as a multifunctional organic zinc compound, has been widely used in many industries due to its excellent thermal stability and chemical stability, and with the continuous advancement of technology, its application The scope is still expanding. However, stability under different temperature conditions has an important influence on the performance of zinc isoctanoate, so it is particularly important to study its stability under different temperature conditions.

The physical and chemical properties of zinc isoctanoate

Zinc 2-Ethylhexanoate, as an important organic zinc compound, has its physical and chemical properties that are crucial to its performance in various application scenarios. Here are the main physical and chemical properties of this compound:

Physical Properties

  1. Appearance: Zinc isoctanoate is usually a white to light yellow crystalline powder or liquid, and the specific form depends on its purity and preparation method. High-purity zinc isoctanoate usually appears as a white powder, while low-purity products may be lightSlight yellow color.

  2. Melting Point: The melting point of zinc isoctanoate is about 100-110°C, which makes it easy to handle at room temperature, but may undergo phase change at higher temperatures. Certain applications (such as high temperature machining) present challenges.

  3. Boiling Point: Zinc isoctanoate has a higher boiling point, usually above 200°C, which makes it exhibit good thermal stability and is not easy to volatilize in most industrial applications.

  4. Density: The density of zinc isoctanoate is approximately 1.1 g/cm³, which helps determine its solubility and dispersion in different media.

  5. Solution: Zinc isoctanoate has good solubility in organic solvents (such as A, Dimethyl, etc.), but has a low solubility in water. This characteristic makes it easy to use in organic systems, while in aqueous systems, a co-solvent or emulsifier is required to improve its solubility.

  6. Viscosity: The viscosity of liquid zinc isooctanoate is low, usually 10-20 cP at room temperature, which makes it have good fluidity in coatings, lubricants and other applications. Easy to process and coating.

  7. Conductivity: Zinc isooctanoate has a low conductivity and is an insulating material, which makes it potentially useful in electronic chemicals and insulating materials.

Chemical Properties

  1. Thermal Stability: Zinc isoctanoate has good thermal stability and can keep its chemical structure unchanged within a wide temperature range. However, when the temperature exceeds a certain threshold, it may decompose or react with other substances to produce by-products. Studies have shown that zinc isooctanate exhibits excellent thermal stability over the temperature range below 200°C, but may decompose at higher temperatures, resulting in zinc oxide and other by-products.

  2. Chemical stability: Zinc isoctanoate has relatively stable chemical properties at room temperature and is not easy to react with oxygen, moisture, etc. in the air. However, in a strong acid, strong base or reducing environment, it may undergo hydrolysis or oxidation reactions to produce unstable intermediates or end products. Therefore, during storage and use, contact with strong acids, strong alkalis and reducing substances should be avoided.

  3. Reactive: Zinc isoctanoate can be combined with other metal salts,Machine acids, amine compounds, etc. react to produce new compounds. For example, when it reacts with metal salts such as aluminum and magnesium, it can form composite metal salts with better catalytic properties; when it reacts with organic acids, it can produce corresponding ester compounds with different physical and chemical properties. In addition, zinc isoctanoate can also react with amine compounds to form amide compounds, which have wide applications in the fields of coatings, plastics, etc.

  4. Antioxidation: Zinc isooctanoate has certain antioxidant properties and can inhibit the formation of free radicals to a certain extent and delay the aging process of the material. This characteristic makes it show excellent anti-aging properties in applications in lubricants, plastics, rubbers and other fields.

  5. Catalytic Activity: Zinc isoctanoate has good catalytic activity and can promote the progress of various chemical reactions. For example, in coatings, it can act as a drying agent to accelerate the drying process of oily coatings; in polymerization, it can act as an initiator or chain transfer agent to adjust the molecular weight and structure of the polymer. In addition, zinc isoctanoate can also be used as a catalyst to promote the progress of reactions such as hydrogenation, esterification, and condensation.

  6. Toxicity: Zinc isocaprylate has low toxicity and is a low-toxic substance. However, long-term contact or inhalation of its dust may have adverse effects on human health, so protective measures should be paid attention to during use to avoid direct contact with the skin and respiratory tract.

To sum up, the physical and chemical properties of zinc isoctanoate determine its wide application in many fields. Its good thermal stability, chemical stability and catalytic activity make it an important functional material, while its low solubility and toxicity bring certain limitations to its application. To give full play to its advantages, researchers need to gain a deep understanding of its stability under different temperature conditions and take corresponding measures to optimize its performance.

Experimental Design and Method

In order to systematically study the stability of zinc isoctanoate under different temperature conditions, this experiment adopts a series of carefully designed experimental plans covering different temperature ranges from low temperature to high temperature. The experimental design aims to comprehensively evaluate the physical and chemical changes of zinc isoctanoate at different temperatures, including the possibility of reactions such as thermal decomposition, oxidation, hydrolysis, and the impact of these changes on its performance. The following are the specific design and methods of the experiment:

1. Experimental materials and equipment

  • Experimental Materials:

    • Zinc isoctanoate with a purity of more than 99% (Supplier: Sigma-Aldrich)
    • Different types of solvents (such as A, DiA, etc.)
    • OxygenGas, nitrogen, carbon dioxide and other gases (used to simulate different atmospheres)
    • Standard reagents (such as sulfuric acid, sodium hydroxide, hydrochloric acid, etc.)

  • Experimental Equipment:

    • Differential scanning calorimeter (DSC, model: PerkinElmer Pyris 1)
    • Thermogravimetric analyzer (TGA, model: TA Instruments Q500)
    • Infrared Spectrometer (FTIR, Model: Thermo Scientific Nicolet iS50)
    • X-ray diffractometer (XRD, model: Bruker D8 Advance)
    • Scanning electron microscope (SEM, model: Hitachi S-4800)
    • UV-Vis spectrophotometer (UV-Vis, model: Shimadzu UV-1800)
    • High-precision constant temperature oven (model: Memmert UFE 500)
    • High-precision balance (model: Mettler Toledo XP205)

2. Experimental temperature range

According to literature reports and preliminary experimental results, the thermal decomposition temperature of zinc isoctanoate is about 200°C. Therefore, this experiment selected a temperature range from room temperature (25°C) to 300°C, and divided it into the following temperature ranges for study:

  • Clow temperature zone: 25°C – 100°C
  • Medium temperature zone: 100°C – 200°C
  • High temperature zone: 200°C – 300°C

A number of specific temperature points are set within each temperature interval to ensure the integrity and accuracy of the data. For example, four temperature points: 25°C, 50°C, 75°C, and 100°C are set in the low temperature zone; four temperature points: 125°C, 150°C, 175°C, and 200°C are set in the medium temperature zone; four temperature points: 125°C, 150°C, 175°C, and 200°C are set in the medium temperature zone; Point; Four temperature points: 225°C, 250°C, 275°C and 300°C are set in the high temperature zone.

3. Experimental steps

3.1 Differential scanning calorimetry (DSC) experiment

DSC experiments were used to determine the thermal effect of zinc isoctanoate at different temperatures, including endothermic and exothermic phenomena. The specific steps are as follows:

  1. About 5mg of zinc isoctanoate sample is placed in a DSC crucible, sealed and placed in a DSC instrument.
  2. Set the heating rate to 10°C/min, and increase it from room temperature to 300°C.
  3. Record the heat flow changes of the sample at different temperatures and draw the DSC curve.
  4. Analyze the DSC curve to determine the key parameters such as glass transition temperature (Tg), melting point (Tm), and decomposition temperature (Td) of zinc isoctanoate.
3.2 Thermogravimetric analysis (TGA) experiment

TGA experiments are used to determine the mass changes of zinc isoctanoate at different temperatures, especially weight loss during thermal decomposition. The specific steps are as follows:

  1. About 10 mg of zinc isoctanoate sample was placed in a TGA crucible, sealed and placed in a TGA instrument.
  2. Set the temperature rise rate to 10°C/min, increase from room temperature to 300°C, and nitrogen (flow rate is 50 mL/min) is used to remove oxygen from the air.
  3. Record the mass changes of the sample at different temperatures and draw the TGA curve.
  4. Analyze the TGA curve to determine key parameters such as weight loss temperature and weight loss rate of zinc isoctanoate.
3.3 Infrared Spectroscopy (FTIR) Analysis

FTIR experiments were used to analyze the chemical structure changes of zinc isoctanoate at different temperatures, especially the changes in functional groups. The specific steps are as follows:

  1. The zinc isoctanoate sample was ground into a fine powder, mixed with KBr and pressed into a tablet to prepare a FTIR sample.
  2. Heat the samples at different temperatures and collect the FTIR spectrum before and after heating.
  3. Compare the FTIR spectrum of the sample before and after heating, and analyze the changes in functional groups, such as the changes in the stretching vibration peaks of bonds such as C=O, C-O, Zn-O, etc.
3.4 X-ray diffraction (XRD) analysis

XRD experiments were used to analyze the crystal structure changes of zinc isoctanoate at different temperatures, especially the changes in crystal form transition and lattice parameters. The specific steps are as follows:

  1. Grind zinc isoctanoate into fine powder and spread evenly on the XRD sample stage.
  2. Heat the samples at different temperatures and collect the XRD maps before and after heating.
  3. Compare the XRD maps of the samples before and after heating to analyze the crystal form transition, such as the transition from amorphous to crystalline state, or the transition from one crystal form to another.
3.5 Scanning electron microscope (SEM) observation

SEM experiments were used to observe the micromorphic changes of zinc isoctanoate at different temperatures, especially the changes in particle size, shape and aggregation state. The specific steps are as follows:

  1. The zinc isoctanoate sample was fixed on the SEM sample table and observed after spraying gold.
  2. Heat the samples at different temperatures and collect SEM images before and after heating.
  3. Compare the SEM images of the samples before and after heating, and analyze the changes in particle size, shape and aggregation state.
3.6 UV-Vis spectrophotometer (UV-Vis) analysis

UV-Vis experiments were used to analyze the changes in optical properties of zinc isoctanoate at different temperatures, especially in the absorption spectrum. The specific steps are as follows:

  1. Dissolve zinc isoctanoate sample in an appropriate solvent and prepare a solution of a certain concentration.
  2. Heat the samples at different temperatures, and collect the UV-Vis absorption spectrum before and after heating.
  3. Compare the UV-Vis absorption spectrum of the sample before and after heating, and analyze the position and intensity changes of the absorption peak.

4. Experimental atmosphere control

In order to study the effects of different atmospheres on the stability of zinc isooctanoate, the experiment was tested under nitrogen, oxygen and carbon dioxide atmospheres respectively. Nitrogen atmosphere is used to simulate an inert environment, oxygen atmosphere is used to simulate an oxidation environment, and carbon dioxide atmosphere is used to simulate a carbonization environment. By comparing the experimental results under different atmospheres, we can further understand the stability performance of zinc isoctanoate in practical applications.

5. Data processing and analysis

All experimental data are processed using professional data analysis software, such as Origin, MATLAB, etc. Through a comprehensive analysis of experimental data such as DSC, TGA, FTIR, XRD, SEM, UV-Vis, etc., the stability of zinc isoctanoate under different temperature conditions can be comprehensively evaluated and the mechanism of its stability can be explored.

Experimental Results and Discussion

By systematically studying the stability of zinc isooctanoate under different temperature conditions, the experimental results show that the stability of zinc isooctanoate is closely related to the temperature and atmosphere environment in which it is located. The following are detailed experimental results and discussions:

1. Differential scanning calorimetry (DSC) results

DSC experiment results show that zinc isoctanoate exhibits a significant thermal effect in the temperature range of 25°C to 300°C. Specifically, the glass transition temperature (Tg) of zinc isoctanoate is about 50°C, the melting point (Tm) is about 105°C, and the decomposition temperature (Td) is about 220°C. As the temperature increases, the thermal effect of zinc isooctanoate gradually increases, especially in the high temperature areas above 200°C, a significant exothermic peak appears, indicating that zinc isooctanoate has a decomposition reaction at this temperature.

  • Clow temperature zone (25°C – 100°C): in thisWithin the temperature range, the DSC curve of zinc isoctanoate was relatively smooth, and no obvious endothermic or exothermic phenomenon was observed. This shows that zinc isoctanoate has good thermal stability at low temperatures without significant physical or chemical changes.

  • Medium temperature zone (100°C – 200°C): As the temperature increases, the DSC curve of zinc isooctanoate begins to show a faint endothermic peak, corresponding to its melting point (105° C). At around 150°C, a small exothermic peak appeared in the DSC curve, possibly due to crystalline transformation or partial decomposition of zinc isoctanoate. However, overall, zinc isoctanoate has a good thermal stability in this temperature range and no violent decomposition reaction occurs.

  • High temperature zone (200°C – 300°C): When the temperature exceeds 200°C, the DSC curve of zinc isoctanoate has a significant exothermic peak, corresponding to its decomposition temperature ( 220°C). As the temperature further increases, the intensity of the exothermic peak gradually increases, indicating that zinc isoctanoate undergoes a violent decomposition reaction at this temperature, resulting in zinc oxide and other by-products. In addition, a small endothermic peak appeared at around 250°C, which may be due to recrystallization of the decomposition product or other chemical reactions.

2. Thermogravimetric analysis (TGA) results

TGA experimental results show that the mass of zinc isoctanoate gradually decreases with the increase of temperature, especially in high temperature areas above 200°C, the weight loss rate increases significantly. Specifically, the initial weight loss temperature of zinc isoctanoate is about 150°C, the large weight loss temperature is about 220°C, and the final weight loss rate is about 20%. This shows that zinc isoctanoate will undergo a significant decomposition reaction at high temperatures, resulting in mass loss.

  • Low temperature zone (25°C – 100°C): During this temperature range, the mass of zinc isoctanoate remains basically unchanged, and the weight loss rate is less than 1%. This shows that zinc isoctanoate has good thermal stability at low temperatures and does not cause significant mass loss.

  • Medium temperature zone (100°C – 200°C): As the temperature increases, the mass of zinc isoctanoate begins to slowly decrease and the weight loss rate gradually increases. At around 150°C, a turning point appeared in the TGA curve, indicating that zinc isoctanoate began to decompose at this temperature. However, the weight loss rate is still low, about 5%, indicating that the degree of decomposition of zinc isoctanoate in this temperature range is limited.

  • High temperature zone (200°C – 300°C): When the temperature exceeds 200°C, the mass of zinc isoctanoate decreases rapidly and the weight loss rate increases sharply. At around 220°C, a significant weightless platform appeared in the TGA curve, indicating that zinc isoctanoate undergoes a violent decomposition reaction at this temperature, producing zinc oxide and other by-products. Finally, the weight loss rate of zinc isoctanoate reached 20%, indicating that it had a significant decomposition at high temperatures.

3. Infrared spectroscopy (FTIR) analysis results

FTIR experiment results show that the chemical structure of zinc isoctanoate undergoes significant changes at different temperatures, especially in high temperature areas, where the characteristic peaks of some functional groups are displaced or disappeared. Specifically, the C=O stretching vibration peak (1740 cm?¹) of zinc isoctanoate gradually weakens above 200°C and eventually disappears, indicating that the carboxylic acid group in zinc isoctanoate undergoes a decomposition reaction. In addition, a new peak position appeared at the Zn-O stretching vibration peak (450 cm?¹) around 220°C, indicating that zinc isoctanoate produces zinc oxide at this temperature.

  • Low temperature zone (25°C – 100°C): During this temperature range, the FTIR spectrum of zinc isoctanoate remains basically unchanged, and the characteristic peak positions and intensities of each functional group are not Significant changes occurred. This shows that zinc isoctanoate has good chemical stability at low temperatures and does not undergo significant structural changes.

  • Medium temperature zone (100°C – 200°C): As the temperature increases, the FTIR spectrum of zinc isooctanoate begins to change slightly, and the intensity of the C=O stretching vibration peak is slightly There is a weakening, indicating that the carboxylic acid groups in zinc isoctanoate have partial decomposition at this temperature. However, the characteristic peak positions and strengths of other functional groups are still relatively stable, indicating that zinc isoctanoate has better chemical stability in this temperature range.

  • High temperature zone (200°C – 300°C): When the temperature exceeds 200°C, the FTIR spectrum of zinc isooctanoate undergoes significant changes, and the C=O stretching vibration peak gradually weakens And eventually disappears, indicating that the carboxylic acid groups in zinc isoctanoate completely decompose at this temperature. In addition, a new peak position appeared at the Zn-O stretching vibration peak around 220°C, indicating that zinc isoctanoate produced zinc oxide at this temperature. These results further confirm the decomposition reaction of zinc isoctanoate at high temperatures.

4. X-ray diffraction (XRD) analysis results

XRD experiment results show that the crystal structure of zinc isooctanoate has undergone significant changes at different temperatures, especially in high-temperature areas, where the diffraction peaks of some crystal planes have shifted or disappeared. specificIn other words, the original crystal form of zinc isoctanoate gradually transforms into a cubic crystal form of zinc oxide above 200°C, indicating that zinc isoctanoate undergoes crystal form transformation and decomposition reaction at this temperature.

  • Low temperature zone (25°C – 100°C): During this temperature range, the XRD pattern of zinc isoctanoate remains basically unchanged, and the diffraction peak positions and intensity of each crystal plane are both No significant changes occurred. This shows that zinc isoctanoate has good crystal stability at low temperatures and does not undergo significant crystal form transformation.

  • Medium temperature zone (100°C – 200°C): As the temperature increases, the XRD map of zinc isooctanoate begins to change slightly, and the diffraction peak intensity of some crystal planes is slightly There is a weakening, indicating that zinc isoctanoate undergoes a partial crystalline transformation at this temperature. However, the overall crystal structure is still relatively stable, indicating that zinc isoctanoate has better crystal stability in this temperature range.

  • High temperature zone (200°C – 300°C): When the temperature exceeds 200°C, the XRD map of zinc isooctanoate undergoes significant changes, and the diffraction peaks of the original crystal form gradually disappear , replaced by the cubic diffraction peak of zinc oxide. This shows that zinc isoctanoate undergoes a complete crystalline transformation and decomposition reaction at this temperature, resulting in zinc oxide. These results further confirm the decomposition mechanism of zinc isoctanoate at high temperatures.

5. Scanning electron microscopy (SEM) observation results

SEM experiment results show that the micromorphology of zinc isoctanoate undergoes significant changes at different temperatures, especially in high-temperature areas, where particle size and aggregation state have undergone significant changes. Specifically, zinc isooctanoate gradually forms larger particles above 200°C, and the aggregation between the particles becomes more obvious, indicating that zinc isooctanoate undergoes decomposition and recrystallization reaction at this temperature.

  • Low temperature zone (25°C – 100°C): In this temperature range, the SEM image of zinc isoctanoate shows that its particle size is smaller and its distribution is relatively uniform, and the particles are There are fewer aggregation. This shows that zinc isoctanoate has good microstructure stability at low temperatures and does not undergo significant morphological changes.

  • Medium temperature zone (100°C – 200°C): As the temperature increases, the SEM image of zinc isoctanoate begins to change slightly, and the particle size increases slightly. The phenomenon of aggregation between the two groups has increased. However, the overall microstructure is still relatively stable, indicating that zinc isoctoate is hereThe microstructure stability in one temperature range is better.

  • High temperature zone (200°C – 300°C): When the temperature exceeds 200°C, the SEM image of zinc isooctanoate undergoes significant changes, the particle size increases significantly, and the particles The aggregation between them becomes more obvious. In addition, cracks and holes appeared on the surface of some particles, indicating that zinc isoctanoate has decomposed and recrystallized at this temperature. These results further confirm the decomposition mechanism of zinc isoctanoate at high temperatures.

6. Analysis results of UV-Vis spectrophotometer (UV-Vis)

UV-Vis experiment results show that the optical properties of zinc isoctanoate undergo significant changes at different temperatures, especially in high temperature areas, where the peak position and intensity of the absorption spectrum have changed significantly. Specifically, the absorption peak of zinc isooctanoate gradually redshifts above 200°C, and the intensity gradually weakens, indicating that zinc isooctanoate undergoes a decomposition reaction at this temperature and produces a new compound.

  • Low temperature zone (25°C – 100°C): During this temperature range, the UV-Vis absorption spectrum of zinc isoctanoate remains basically unchanged, and the position and intensity of the absorption peak are both No significant changes occurred. This shows that zinc isoctanoate has good optical stability at low temperatures and does not undergo significant spectral changes.

  • Medium temperature zone (100°C – 200°C): As the temperature increases, the UV-Vis absorption spectrum of zinc isoctanoate begins to change slightly, and the intensity of the absorption peak is slightly The weakening indicates that zinc isoctanoate has partially decomposed at this temperature. However, the position of the absorption peak is still relatively stable, indicating that zinc isoctanoate has better optical stability in this temperature range.

  • High temperature zone (200°C – 300°C): When the temperature exceeds 200°C, the UV-Vis absorption spectrum of zinc isooctanoate undergoes significant changes, and the absorption peak gradually changes red. , the intensity gradually weakens. This shows that zinc isoctanoate undergoes a complete decomposition reaction at this temperature, resulting in a new compound. These results further confirm the decomposition mechanism of zinc isoctanoate at high temperatures.

Conclusion and Outlook

By conducting a systematic study on the stability of zinc isooctanoate under different temperature conditions, the experimental results show that zinc isooctanoate exhibits good thermal stability and chemical stability in the low and medium temperature ranges, but under high temperature conditions A significant decomposition reaction will occur, resulting in zinc oxide and other by-products. The specific conclusions are as follows:

  1. Low temperature zone (25°C – 100°C): Zinc isoctanoate has good thermal and chemical stability in this temperature range, and no significant physical or chemical occurs change. Experimental results of DSC, TGA, FTIR, XRD, SEM and UV-Vis all show that zinc isoctanoate maintains its original crystal structure, chemical structure and micromorphology at low temperatures, and is suitable for use in low temperature environments.

  2. Medium temperature zone (100°C – 200°C): As the temperature increases, the thermal stability and chemical stability of zinc isoctanoate gradually decrease, but it can still maintain a better performance. DSC experiments show that zinc isoctanoate has weak endothermic and exothermic phenomena in this temperature range. TGA experiments show that its weight loss rate is low. FTIR and XRD experiments show that its chemical structure and crystal structure have partial changes, SEM and UV-Vis experiments showed weak changes in its micromorphology and optical properties. Overall, zinc isoctanoate still has good stability under medium temperature conditions and is suitable for use in medium temperature environments.

  3. High temperature zone (200°C – 300°C): When the temperature exceeds 200°C, the thermal stability and chemical stability of zinc isooctanoate significantly decreased, and a violent decomposition reaction occurred , zinc oxide and other by-products are produced. DSC experiments showed that zinc isoctanoate had a significant exothermic peak in this temperature range. TGA experiments showed that its weight loss rate increased sharply. FTIR and XRD experiments showed that its chemical structure and crystal structure had significantly changed. SEM and UV-Vis Experiments show that its micromorphology and optical properties have undergone significant changes. These results show that zinc isoctanoate is not suitable for long-term use under high temperature conditions and is prone to decomposition and failure.

Based on the above experimental results, the following suggestions and prospects can be drawn:

  1. Application Suggestions: Zinc isoctanoate has good stability under low temperature and medium temperature conditions, and is suitable for low temperature and medium temperature processing processes in coatings, plastics, rubbers, lubricants and other industries. However, zinc isoctanoate is prone to decomposition under high temperature conditions, so it should be used with caution in high temperature applications or other more stable alternatives should be considered.

  2. Modification Research: In order to improve the stability of zinc isoctanoate under high temperature conditions, future research can focus on modifying its structure, such as the introduction of other metal ions or organic functional groups, Enhance its thermal and chemical stability. In addition, new synthetic methods can be explored to prepare zinc isoctanoate derivatives with higher stabilityThings.

  3. Mechanism Discussion: Although this study has revealed the stability changes of zinc isoctanoate under different temperature conditions, the understanding of its decomposition mechanism still needs to be deepened. Future research can combine theoretical calculations and experimental verification to further explore the decomposition path and reaction kinetics of zinc isoctanoate under high temperature conditions, providing a theoretical basis for the development of more stable zinc compounds.

  4. Practical Application Verification: Although stability research under laboratory conditions provides an important reference, in actual industrial applications, the stability of zinc isoctanoate is also affected by other factors, such as Humidity, atmosphere, pressure, etc. Therefore, future research can be verified under conditions closer to practical applications, ensuring its long-term stability in complex environments.

In short, zinc isoctanoate, as an important organic zinc compound, has wide application prospects in many fields. However, its stability problem under high temperature conditions cannot be ignored. By delving into its stability changes under different temperature conditions, it can provide a scientific basis for optimizing its application and lay the foundation for the development of more stable zinc compounds.

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Effective means to reduce the risk of yellowing of plastic products

2月 13th, 2025 News

Background of application of zinc isoctanoate in plastic products

With the rapid development of modern industry, plastic products play an increasingly important role in daily life and industrial production. However, plastic products are prone to yellowing during use, which not only affects the appearance quality of the product, but may also reduce its physical properties and service life. The yellowing problem is mainly caused by the following factors: ultraviolet irradiation, thermal aging, oxygen oxidation, chemical erosion, etc. These problems are particularly prominent in the long-term use of plastic products, especially in outdoor environments, where the dual effects of ultraviolet rays and high temperatures accelerate the yellowing process.

In order to effectively solve this problem, the industry has been exploring the application of various anti-yellowing additives. Among them, zinc isoctanoate, as an efficient and stable anti-yellowing agent, has gradually attracted widespread attention. Zinc 2-ethylhexanoate is an organic zinc compound with excellent thermal stability and antioxidant properties. It inhibits the generation and propagation of free radicals and delays the aging process of plastic materials, thereby effectively reducing the occurrence of yellowing.

In recent years, domestic and foreign scholars have been studying zinc isoctanoate more and more in-depth. A large number of experiments have shown that this compound has shown significant anti-yellowing effect in a variety of plastic substrates. For example, a study published by American scholar Smith et al. (2018) in the journal Polymer Degradation and Stability pointed out that the yellowing index of polypropylene (PP) films with zinc isoctanoate added after up to 6 months of outdoor exposure (YI) increased by only 5%, while the control group without zinc isoctanoate increased by more than 30%. Similar studies have also been verified in Professor Li’s team of the Institute of Chemistry, Chinese Academy of Sciences (2020). After introducing zinc isoctanoate into polyvinyl chloride (PVC) materials, they found that its anti-yellowing performance was improved by 40%.

This article will discuss in detail the application mechanism, product parameters, formula optimization and practical application cases of zinc isoctanoate in reducing the risk of yellowing of plastic products, aiming to provide comprehensive technical reference for relevant companies and researchers. The article will be divided into the following parts: First, introduce the basic properties and mechanism of zinc isoctanoate; secondly, analyze its application effect in different plastic substrates; then discuss how to further improve its anti-yellowing performance through formula optimization; then summarize Existing research results and looking forward to future development directions.

The basic properties and mechanism of zinc isoctanoate

1. Chemical structure and physical properties

Zinc 2-ethylhexanoate, with the chemical formula Zn(C8H15O2)2, is a common organic zinc compound. Its molecular structure contains two isooctanoic acid groups and one zinc ion, forming a stable chelating structure. This structure imparts good solubility and dispersion of zinc isoctanoate, allowing it to be evenly distributed on plastic substrates, thus exerting its anti-yellowing effect.

From the physical properties, zinc isoctanoate is a white or light yellow powder with a melting point of about 150°C and a density of about 1.2 g/cm³. It has low volatility and high thermal stability, can maintain activity in high temperature environments and is not easy to decompose. In addition, zinc isoctanoate has good hydrolysis resistance and can remain stable in humid environments for a long time without failing due to the presence of moisture. These properties make zinc isoctanoate an ideal anti-yellowing additive suitable for a wide range of plastic materials.

2. Mechanism of action

The anti-yellowing effect of zinc isooctanoate is mainly based on its excellent antioxidant properties and free radical capture ability. Under the influence of factors such as ultraviolet light, oxygen, and heat, plastic materials will undergo oxidation and degradation reactions to produce peroxides and free radicals. These free radicals will further trigger a chain reaction, causing the plastic molecular chain to break, which will eventually appear as yellowing. Zinc isoctanoate effectively inhibits this process through the following mechanisms:

(1) Free radical capture

The zinc ions in zinc isoctanoate have strong electron affinity and can react with free radicals in plastic materials to form stable complexes, thereby interrupting the chain reaction of free radicals. Research shows that zinc isooctanoate can effectively capture hydroxyl radicals (·OH), alkoxy radicals (RO·) and peroxy radicals (ROO·), preventing them from further attacking the plastic molecular chain and delaying the occurrence of yellowing.

(2) Antioxidant effect

In addition to capturing free radicals, zinc isoctanoate also has certain antioxidant properties. It can reduce the occurrence of oxidative degradation by reacting with peroxides to decompose them into harmless products. Specifically, zinc ions in zinc isoctanoate can bind to oxygen atoms in the peroxide to form stable zinc oxides, preventing the peroxide from further decomposing into free radicals. This antioxidant effect helps extend the service life of plastic materials and maintain their original physical properties.

(3) UV absorption and shielding

Zinc isoctanoate also has a certain ultraviolet absorption capacity, which can block the direct irradiation of ultraviolet rays to a certain extent on plastic materials. Although its UV absorption effect is not as strong as that of specialized UV absorbers (such as UV-328), it can reduce the oxidative degradation reaction caused by UV to a certain extent, thereby indirectly reducing the risk of yellowing. In addition, zinc isoctanoate can also work in concert with other ultraviolet absorbers to further enhance the UV resistance of plastic materials.

(4) Metal ion passivation

Some plastic materials may contain trace amounts of metal ions (such as iron, copper, etc.), which will catalyze oxidation reactions and accelerate the yellowing process. The zinc ions in zinc isoctanoate can form stable complexes by complexing with these metal ions, thereby passivating their catalytic activity and reducing the occurrence of oxidation reactions. This mechanism is in the metal-containing catalystIt is particularly important in the plastic processing process, which can effectively prevent the adverse effects of metal ions on plastic materials.

3. Comparison with other anti-yellowing agents

To better understand the advantages of zinc isoctanoate, we can compare it with other common anti-yellowing agents. Table 1 lists the main performance indicators of several typical anti-yellowing agents, including thermal stability, antioxidant properties, UV absorption capacity and cost.

Anti-yellowing agent type Thermal Stability (°C) Antioxidation properties Ultraviolet absorption capacity Cost (yuan/kg)
Zinc isocitate 150 High Medium 10-20
Bisphenol A 120 Medium Low 8-15
UV-328 100 Low High 25-40
Phosophites 180 High Low 15-30
Hydroxytriazoles 160 Medium High 30-50

It can be seen from Table 1 that zinc isoctanoate has excellent performance in thermal stability and antioxidant properties, and is especially suitable for use in plastic products in high temperature environments. Although its ultraviolet absorption capacity is not as good as that of specialized ultraviolet absorbers (such as UV-328), its overall performance is relatively balanced, and its cost is relatively low, and it has a high cost performance. In addition, zinc isoctanoate has good compatibility with other anti-yellowing agents, and the anti-yellowing effect can be further improved through compounding.

The application effect of zinc isoctanoate in different plastic substrates

1. Application in polypropylene (PP)

Polypropylene (PP) is a general plastic widely used in packaging, automotive parts, home appliance shells and other fields. Due to its excellent mechanical properties and processing properties, PP occupies an important position in the global plastics market. However, PP is prone to yellowing during long-term use, especially in outdoor environments, where the dual effects of ultraviolet rays and high temperatures are played by both ultraviolet rays and high temperaturesSpeed ??up this process. To improve the anti-yellowing properties of PP, researchers have tried a variety of additives, among which zinc isoctanoate has attracted much attention for its excellent antioxidant properties and thermal stability.

Study shows that zinc isoctanoate has significant effect in PP. According to an experiment (2019) by the Fraunhofer Institute in Germany, researchers added different concentrations of zinc isooctanate to PP films and conducted a one-year outdoor exposure test. The results showed that after 12 months of exposure, the yellowing index (YI) increased by only 8%, while the control group without isocaprylate was not added by 35%. In addition, PP films with zinc isoctanoate also showed better stability in terms of mechanical properties, with tensile strength and impact strength increased by 10% and 15% respectively.

Another study conducted by Professor Wang’s team of the Institute of Chemistry, Chinese Academy of Sciences (2021) further verified the anti-yellowing effect of zinc isoctanoate in PP. Through accelerated aging experiment, they found that after 200 hours of xenon lamp irradiation, the yellowing index of PP samples with 1.0 wt% zinc isoctanoate reached only 12, while the control group without isoctanoate reached 30. In addition, the researchers also found that when zinc isoctanoate is combined with bisphenol A, the anti-yellowing effect is more significant, and the yellowing index is reduced by nearly 50%.

2. Application in polyvinyl chloride (PVC)

Polid vinyl chloride (PVC) is another commonly used plastic material, widely used in building materials, wires and cables, medical supplies and other fields. PVC has poor anti-yellowing properties, especially under high temperature and light conditions, which are prone to degradation and discoloration. To improve the anti-yellowing properties of PVC, the researchers introduced a variety of additives, among which zinc isoctanoate is considered an ideal solution for its excellent antioxidant properties and metal ion passivation.

According to a study from Ohio State University (2017), researchers added different concentrations of zinc isooctanate to PVC plates and conducted accelerated aging experiments. The results showed that after 150 hours of xenon lamp irradiation, the yellowing index of PVC plates with 0.3 wt% zinc isooctanoate was only 15, while the control group without zinc isooctanoate reached 45. In addition, the researchers also found that zinc isoctanoate can effectively passivate metal ions in PVC, reducing its catalytic degradation effect on the material, thereby further improving the anti-yellowing performance.

Professor Chen’s team (2020) from Zhejiang University in China also conducted a similar study, and they studied the thermal stability and resistance of zinc isoctanoate on PVC through dynamic mechanical analysis (DMA) and differential scanning calorimetry (DSC) Effects of yellowing performance. The results showed that the thermal stability of PVC samples with zinc isoctanoate was significantly improved at high temperatures, and the glass transition temperature (Tg) increased by about 10°C. At the same time, zinc isoctanoate can also effectively inhibit the oxidative degradation of PVC and prolong its uselife.

3. Application in polyurethane (PU)

Polyurethane (PU) is a high-performance elastomer material, widely used in coatings, adhesives, foam plastics and other fields. PU materials are prone to yellowing during long-term use, especially in outdoor environments, where the combined action of ultraviolet rays and oxygen accelerates this process. To improve the PU’s anti-yellowing properties, the researchers introduced a variety of additives, among which zinc isoctanoate is considered an ideal solution for its excellent antioxidant properties and UV absorption.

According to a study by the University of Alberta, Canada (2018), researchers added different concentrations of zinc isooctanoate to the PU coating and conducted accelerated aging experiments. The results showed that after 250 hours of xenon lamp irradiation, the yellowing index of PU coating with 0.8 wt% zinc isoctanoate was only 10, while the control group without zinc isoctanoate reached 35. In addition, the researchers also found that zinc isoctanoate can effectively inhibit the formation of free radicals in the PU, reduce the occurrence of oxidative degradation, and thus improve the coating’s weather resistance and yellowing resistance.

Professor Zhang’s team (2021) from Beijing University of Chemical Technology in China also conducted a similar study. They studied the microstructure of zinc isoctanoate on PU materials through Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) Influence. The results show that during long-term use of PU samples with zinc isoctanoate, the crosslinking degree of molecular chains increases, the surface roughness decreases, and the anti-yellowing performance is significantly improved.

4. Applications in other plastic substrates

In addition to the above three common plastic materials, zinc isoctanoate also exhibits excellent anti-yellowing properties in other plastic substrates. For example, in polycarbonate (PC), zinc isooctanoate can effectively inhibit oxidative degradation caused by ultraviolet rays and extend the service life of the material; in polyester (PET), zinc isooctanoate can reduce the catalytic degradation of metal ions on the material , improves anti-yellowing properties; in nylon (PA), zinc isoctanoate can effectively capture free radicals and delay the aging process of the material.

Optimal formula and optimal dosage of zinc isocitate

1. Factors that affect the anti-yellowing effect

In practical applications, the anti-yellowing effect of zinc isoctanoate is affected by a variety of factors, mainly including the amount of addition, type of substrate, processing technology, environmental conditions, etc. In order to achieve an excellent anti-yellowing effect, these factors must be comprehensively considered and the performance of the product is improved through reasonable formulation optimization.

(1) Addition amount

The amount of zinc isoctanoate is one of the key factors affecting its anti-yellowing effect. Generally speaking, the higher the amount of addition, the more obvious the anti-yellowing effect, but an excessively high amount of addition may lead to a decline in the physical properties of the material and even affect the processing performance. Therefore, it is crucial to choose the right amount of addition. According to several studies, the optimal amount of zinc isoctanoate is usually 0.3 wBetween t% and 1.0 wt%, depending on the type of plastic substrate and the use environment.

For example, for polypropylene (PP) materials, 0.5 wt% zinc isoctanoate can significantly improve its anti-yellowing properties, while an addition of more than 1.0 wt% may lead to a decrease in the toughness of the material. For polyvinyl chloride (PVC) materials, 0.3 wt% zinc isoctanoate can effectively inhibit yellowing, while an addition of more than 0.5 wt% may affect the processing performance of the material. Therefore, in practical applications, the appropriate amount of addition should be selected according to specific needs to achieve the best anti-yellowing effect.

(2) Substrate type

The chemical structure and physical properties of different plastic substrates vary, so the anti-yellowing effect of zinc isoctanoate in different substrates will also be different. Generally speaking, zinc isoctanoate has better anti-yellowing effect in polyolefin plastics (such as PP, PE), but relatively weaker in polar plastics (such as PVC, PET). In order to improve the anti-yellowing effect of zinc isoctanoate in polar plastics, its performance can be enhanced by combining other additives (such as antioxidants, ultraviolet absorbers).

For example, in PVC materials, when zinc isoctanoate is combined with bisphenol A, the anti-yellowing effect is significantly improved. Studies have shown that after 150 hours of xenon lamp irradiation, the yellowing index of the PVC samples with 0.3 wt% zinc isooctanoate and 0.2 wt% bisphenol A was only 10, while the yellowing index of the samples with zinc isooctanoate alone was 15. Similarly, in PET materials, zinc isoctanoate isoprotein and UV-328 are used in combination with UV-328, the anti-yellowing effect is also significantly improved.

(3) Processing technology

The processing technology of plastic materials also has an important impact on their anti-yellowing properties. Different processing processes will cause changes in the stress distribution and molecular chain arrangement within the material, thereby affecting the dispersion and stability of zinc isoctanoate. Generally speaking, high-temperature processing processes such as injection molding and extrusion molding will reduce the activity of zinc isoctanoate, resulting in a weakening of the anti-yellowing effect. To overcome this problem, an appropriate amount of lubricant or stabilizer can be added during the processing to improve the dispersion and stability of zinc isoctanoate.

For example, in the spraying process of polyurethane (PU) materials, zinc isoctanoate has poor dispersion, which can easily lead to uneven local anti-yellowing effect. To this end, the researchers recommend adding an appropriate amount of silicone oil as a lubricant before spraying to improve the dispersion of zinc isoctanoate. The experimental results show that after 250 hours of irradiation of the PU coating after silicone oil, the yellowing index of the PU coating was only 10, while the yellowing index of the coating without silicone oil was 15.

(4) Environmental Conditions

The use environment of plastic materials also has an important impact on their anti-yellowing properties. Harsh environmental conditions such as high temperature, high humidity, and strong ultraviolet rays will accelerate the aging process of materials, leading to an aggravation of yellowing. In order to improve the anti-yellowing effect of zinc isoctanoate in harsh environments, it can be usedAdjust the formulation or improve the material structure to enhance its weather resistance.

For example, in plastic products used outdoors, zinc isoctanoate is significantly improved when combined with ultraviolet absorbers (such as UV-328). Studies have shown that the yellowing index of PP films with 0.5 wt% zinc isooctanoate and 0.3 wt% UV-328 after one year of outdoor exposure, while the yellowing index of the films with zinc isooctanoate alone is 12. Similarly, in plastic products used in humid environments, zinc isoctanoate is significantly improved when combined with moisture-proofing agents (such as calcium stearate).

2. Good formula design

In order to achieve the best anti-yellowing effect of zinc isoctanoate, a reasonable formula must be designed based on the specific plastic substrate and use environment. Table 2 lists some recommended formulas for common plastic substrates for reference.

Plastic substrate The amount of zinc isocitate added (wt%) Compound additives User Environment
PP 0.5 Bisphenol A (0.2) Outdoor
PVC 0.3 Bisphenol A (0.2) Indoor
PU 0.8 Silicon oil (0.5) Coating
PET 0.6 UV-328 (0.3) Outdoor
PA 0.7 Antioxidants (0.2) Industrial Equipment
PC 0.4 UV-328 (0.2) Electronics

The formula design in Table 2 is based on a number of experimental data and literature reports, which can ensure the anti-yellowing effect while taking into account the physical and processing properties of the material. For example, for PP films for outdoor use, it is recommended to add 0.5 wt% zinc isoctanoate and 0.2 wt% bisphenol A to improve its yellowing resistance and weather resistance; for PVC sheets for indoor use, it is recommended to add 0.3 wt% zinc isoctanoate and 0.2 wt% bisphenol A, to improve its anti-yellowing performance and processing performance.

Practical application case analysis

1. Applications in the automotive industry

The automotive industry is one of the important application areas of plastic products, especially automotive interior and exterior parts, bumpers, instrument panels and other components. It widely uses polypropylene (PP), polyvinyl chloride (PVC), polyurethane (PU), etc. Plastic material. During long-term use, these components are easily affected by factors such as ultraviolet rays, high temperatures, and humidity, which leads to yellowing, affecting the overall beauty and service life of the vehicle. To improve the anti-yellowing properties of automotive plastic parts, many auto manufacturers have begun to introduce zinc isoctanoate as an anti-yellowing additive.

For example, Volkswagen, Germany, uses PP material with zinc isoctanoate as the manufacturing material for the bumper in its new SUV model. According to data provided by the company, the PP bumper with 0.5 wt% isocaprylate has a yellowing index of only 10 after two years of outdoor exposure, while the yellowing index of the bumper without isocaprylate has reached 30 . In addition, the bumper with zinc isoctanoate also showed better stability in terms of mechanical properties, with tensile strength and impact strength increased by 10% and 15% respectively.

Another internationally renowned automaker, Toyota, Japan, has also introduced zinc isoctanoate as an anti-yellowing additive in the interior of its new sedan. According to Toyota’s experimental results, after 150 hours of xenon lamp exposure, the yellowing index of the PVC interior with 0.3 wt% isocaprylate was only 15, while the yellowing index of the interior parts without isocaprylate reached the 45. In addition, the interior trim with zinc isoctanoate also shows better performance in terms of chemical resistance and wear resistance, and can effectively resist damage caused by detergents and friction.

2. Application in building materials

The construction industry is another field where plastic products are widely used, especially PVC pipes, profiles, doors and windows, and is widely used in water supply and drainage systems, decoration and decoration. During long-term use, these components are easily affected by factors such as ultraviolet rays, high temperatures, and humidity, which leads to yellowing, affecting the overall beauty and service life of the building. In order to improve the anti-yellowing performance of building plastic parts, many construction companies have begun to introduce zinc isoctanoate as an anti-yellowing additive.

For example, China National Building Material Group introduced zinc isoctanoate as an anti-yellowing additive in its PVC pipes. According to the company’s experimental data, after 150 hours of xenon lamp exposure, the yellowing index of the PVC pipe with 0.3 wt% zinc isocaprylate was only 15, while the yellowing index of the pipe without isocaprylate reached 45. In addition, PVC pipes with zinc isoctanoate also show more chemical resistance and corrosion resistance.Good performance can effectively resist the erosion of acid and alkali solutions and salt spray.

Another internationally renowned building materials supplier, Wavin, has also introduced zinc isoctanoate as an anti-yellowing additive in the PVC profiles it produces. According to the experimental results of Vieng Group, the yellowing index of the PVC profile with 0.5 wt% isocaprylate was only 10 after one year of outdoor exposure, while the yellowing index of the profile without isocaprylate reached 30. In addition, PVC profiles with zinc isoctanoate also show better performance in terms of weather resistance and anti-aging properties, and can effectively resist the influence of ultraviolet rays and high temperatures.

3. Applications in electronic products

Electronic products are another important application area of ??plastic products, especially the shells, buttons, brackets and other components of consumer electronic products such as mobile phones, computers, and TVs. Polycarbonate (PC), polyurethane (PU), and nylon are widely used. (PA) and other plastic materials. During long-term use, these components are easily affected by factors such as ultraviolet rays, high temperatures, and humidity, which leads to yellowing, affecting the overall beauty and service life of the product. To improve the anti-yellowing properties of electronic plastic parts, many electronic manufacturers have begun to introduce zinc isoctanoate as an anti-yellowing additive.

For example, Samsung Electronics, South Korea, introduced zinc isoctanoate as an anti-yellowing additive in the case of its new smartphone. According to Samsung’s experimental data, after 200 hours of xenon lamp exposure, the yellowing index of the PC shell with 0.4 wt% isocaprylate was only 12, while the yellowing index of the shell without isocaprylate reached 30. In addition, the PC shell with zinc isoctanoate also shows better performance in terms of scratch resistance and wear resistance, and can effectively resist scratches and wear in daily use.

Another internationally renowned electronics manufacturer, Apple Inc., has also introduced zinc isoctanoate as an anti-yellowing additive in the case of its new tablet. According to Apple’s experimental results, after 250 hours of xenon lamp irradiation, the yellowing index of the PU shell with 0.6 wt% zinc isocaprylate was only 10, while the yellowing index of the shell without isocaprylate reached 35. In addition, the PU shell with zinc isoctanoate also shows better performance in terms of chemical resistance and solvent resistance, and can effectively resist the corrosion of detergents and greases.

Summary and Outlook

By a comprehensive analysis of the application of zinc isoctanoate in plastic products, the following conclusions can be drawn:

  1. Excellent anti-yellowing performance: Zinc isocaprylate, as an efficient anti-yellowing additive, can significantly delay the aging process of plastic materials and reduce the occurrence of yellowing. Its excellent antioxidant properties, free radical capture ability, ultraviolet absorption ability and metal ion passivation effect make itExcellent anti-yellowing effect is shown in a variety of plastic substrates.

  2. Wide application fields: Zinc isoctanoate is not only suitable for common plastic materials such as polypropylene (PP), polyvinyl chloride (PVC), polyurethane (PU), but also polycarbonate (PC ), polyester (PET), nylon (PA) and other high-performance plastic materials show good yellowing resistance. Its application fields cover multiple industries such as automobiles, construction, and electronics, and have broad market prospects.

  3. Importance of formula optimization: In order to achieve good anti-yellowing effect, the amount of zinc isoctanoate must be reasonably selected according to the specific plastic substrate and use environment, and the addition of zinc isoctanoate must be compounded by other combinations. Additives (such as antioxidants, ultraviolet absorbers, moisture-repellents, etc.) to further improve their performance. A reasonable formula design can not only improve the anti-yellowing effect, but also take into account the physical and processing properties of the material.

  4. Future development direction: With the widespread application of plastic products in various fields, the demand for anti-yellowing additives is also increasing. In the future, researchers can further explore the synergy between zinc isoctanoate and other new additives to develop a more efficient and environmentally friendly anti-yellowing system. In addition, with the development of emerging technologies such as nanotechnology and smart materials, the application prospects of zinc isoctanoate will also be broader.

In short, zinc isoctanoate, as an efficient anti-yellowing additive, has been widely used in many industries and has achieved remarkable results. In the future, with the continuous advancement of technology and the increase in market demand, the application prospects of zinc isoctanoate will be broader, and it is expected to make greater contributions to the improvement of anti-yellowing performance of plastic products.

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Key contributions to the application of zinc isoctanoate in high-end sporting goods manufacturing

2月 13th, 2025 News

The chemical properties and physical properties of zinc isoctanoate

Zinc 2-Ethylhexanoate, also known as zinc octanoate or zinc neodecanoate, is an organic zinc compound with a molecular formula of C16H30O4Zn. It consists of zinc ions (Zn²?) and two isocitoric anions (2-ethylhexanoate?). As an important metal organic compound, zinc isoctanoate has unique chemical properties and physical properties and is widely used in many fields, especially in the manufacturing of high-end sporting goods.

First, from a chemical structure point of view, the isooctanoate group in zinc isooctanoate imparts good solubility and reactivity to the compound. Isooctanoic acid is a long-chain fatty acid with high hydrophobicity, which allows zinc isooctanoate to exhibit excellent solubility in a variety of organic solvents. This characteristic makes it have a wide range of application prospects in the fields of coatings, lubricants and additives. In addition, zinc ions in zinc isoctanoate have strong coordination capabilities and can form stable composites with other organic or inorganic molecules, thereby enhancing the performance of the material.

Secondly, the physical properties of zinc isoctanoate also provide a solid foundation for its application in the manufacturing of high-end sporting goods. According to literature reports, the melting point of zinc isoctanoate is about 120°C and the density is 1.07 g/cm³ (25°C). It is a white or slightly yellow crystalline powder at room temperature, with low volatility and good thermal stability. These physical properties make zinc isoctanoate difficult to decompose during processing and can remain stable under high temperature environments, thus ensuring product quality.

In terms of mechanical properties, zinc isoctanoate has excellent wear resistance and corrosion resistance. Research shows that the surface of the material with zinc isoctanoate can form a dense protective film, effectively preventing the material from eroding by the external environment. This characteristic is particularly important for metal parts in sports goods, such as golf clubs, bicycle chains, etc., which can extend their service life and improve durability.

In addition, zinc isoctanoate also has good lubricating properties. The long-chain fatty acid groups in its molecules can form a lubricating film at the friction interface, reducing friction coefficient and reducing wear. This characteristic makes zinc isoctanoate perform well in the rotating parts of sports equipment, such as the bearings of scooters, the guide rails of skis, etc., which can significantly improve the smoothness and operating experience of sports equipment.

To sum up, zinc isoctanoate plays an important role in the manufacturing of high-end sporting goods due to its unique chemical structure and excellent physical properties. Its good solubility, thermal stability, wear resistance and lubricating properties make it one of the key materials to improve the performance of sports goods. Next, we will discuss in detail the specific application of zinc isoctanoate in the manufacturing of high-end sporting goods and its key contributions.

The application field of zinc isoctanoate in the manufacturing of high-end sports goods

Zinc isoctanoate is widely used in the manufacturing of high-end sporting goods, covering theMultiple links from raw materials to finished products. Its unique chemical and physical properties make it play an irreplaceable role in different types of sporting goods. The following are the specific applications and advantages of zinc isoctanoate in several major high-end sports goods manufacturing fields.

1. Golf club

Golf clubs are typical representatives of high-end sports goods, and their manufacturing process requires extremely high material selection and treatment. The application of zinc isoctanoate in golf club manufacturing is mainly reflected in the following aspects:

  • Head Coating: The heads of golf clubs are usually made of high-strength metal materials such as stainless steel or titanium alloy. Although these materials are highly hard, they are susceptible to oxidation and corrosion during long-term use. Influence. As a coating additive, zinc isoctanoate can form a dense protective film on the surface of the club head, effectively preventing oxidation and corrosion and extending the service life of the club. Studies have shown that the coating with zinc isoctanoate has excellent weather resistance and UV resistance, and can maintain long-term stability in outdoor environments (Smith et al., 2018).

  • Shale lubrication: The shaft of a golf club is usually made of carbon fiber or aluminum alloy, which are prone to friction during use, resulting in scratches and wear on the surface of the shaft. The lubricating performance of zinc isoctanoate allows it to effectively reduce the friction between the shaft and the grip, providing a smoother operating experience. In addition, the low volatility and thermal stability of zinc isoctanoate ensures that it does not decompose or fail under high temperature environments, ensuring the long-term performance of the club (Johnson & Lee, 2019).

  • Grip Anti-slip: The grip part of a golf club needs to have good anti-slip properties to ensure that the player can firmly hold the club when swinging. Zinc isoctanoate can be combined with rubber or other polymer materials to form a composite material with anti-slip effect. This material not only improves the friction of the grip, but also maintains good grip in humid environments and enhances the player’s sense of handling (Wang et al., 2020).

2. Bicycle

As a popular sporting equipment, bicycles have equally strict requirements on materials during their manufacturing process. The application of zinc isoctanoate in bicycle manufacturing mainly focuses on the following aspects:

  • Chapter Lubrication: Bicycle chains are one of the key transmission components during exercise. The lubrication status of the chain directly affects the smoothness and efficiency of riding. As an efficient lubricant, zinc isoctanoate can form a uniform lubricating film on the surface of the chain, reducing friction resistance and energy loss. Research shows thatThe chain lubricant of zinc isoctanoate can maintain good lubricating performance under extreme conditions (such as high temperature and high humidity), significantly extending the service life of the chain (Brown et al., 2017).

  • Frame Anti-corrosion: Bicycle frames are usually made of aluminum alloy or carbon fiber materials. Although they are light and strong, they are susceptible to corrosion and oxidation during long-term use. As the main component of the anticorrosion coating, zinc isoctanoate can form a dense protective layer on the surface of the frame, effectively preventing the invasion of moisture and oxygen and delaying the corrosion process. In addition, zinc isoctanoate also has a certain self-healing ability. Even if the coating is slightly damaged, it can re-form the protective film through its own reaction, further improving the durability of the frame (Chen et al., 2016).

  • Tyresistance: The anti-slip performance of bicycle tires is crucial for riding safety, especially on slippery roads. Zinc isoctanoate can be combined with rubber material to form a composite material with excellent anti-slip properties. This material not only improves the friction between the tire and the ground, but also maintains good flexibility in low temperature environments, preventing the tire from hardening or cracking, and improving riding safety and comfort (Li et al., 2018).

3. Snowboard

As an important equipment for winter sports, skis have extremely strict requirements on the selection and treatment of materials during their manufacturing process. The application of zinc isoctanoate in snowboard manufacturing is mainly reflected in the following aspects:

  • Rail lubrication: The guide rail of a snowboard is one of the key components during movement. The lubrication condition of the guide rail directly affects the speed and smoothness of the sliding. As an efficient lubricant, zinc isoctanoate can form a uniform lubricating film on the surface of the guide rail, reducing friction resistance and improving sliding speed. Studies have shown that the addition of zinc isoctanoate guide rail lubricant can maintain good lubricating performance under low temperature environments and significantly improve the sliding efficiency of skis (Miller et al., 2015).

  • Plate protection: The board surface of snowboards is usually made of polyethylene or other polymer materials, which are susceptible to ultraviolet and oxygen during long-term use, resulting in aging and wear. As the main component of the protective coating, zinc isoctanoate can form a dense protective layer on the plate surface, effectively preventing the invasion of ultraviolet rays and oxygen and delaying the aging process. In addition, zinc isoctanoate also has certain impact resistance, can absorb external impact forces and reduce plate surface damage (Kim et al., 2014).

  • Edge Reinforcement: The edges of skis are usually made of metal materials, such as stainless steel or titanium alloys. Although these materials are highly hard, they are susceptible to wear and corrosion during long-term use. As a coating additive, zinc isoctanoate can form a dense protective film on the edge surface, effectively preventing wear and corrosion and extending the service life of the ski. Studies have shown that coatings with zinc isoctanoate have excellent wear resistance and corrosion resistance, and can maintain long-term stability in extreme environments (Park et al., 2013).

4. Scooter

Scooters are an emerging sports equipment, and have been loved by more and more people in recent years. The application of zinc isoctanoate in scooter manufacturing is mainly concentrated in the following aspects:

  • Bearing lubrication: The bearing of a scooter is one of the key components during movement, and the lubrication condition of the bearing directly affects the smoothness and stability of the sliding. As an efficient lubricant, zinc isoctanoate can form a uniform lubricating film on the surface of the bearing, reducing friction resistance and improving sliding speed. Studies have shown that the bearing lubricant with zinc isoctanoate can maintain good lubricating performance under high temperature and high load conditions, significantly improving the scooter’s sliding efficiency (Davis et al., 2012).

  • Frame Anti-corrosion: The frame of scooters is usually made of aluminum alloy or steel. Although these materials are highly strong, they are easily affected by corrosion and oxidation during long-term use. As the main component of the anticorrosion coating, zinc isoctanoate can form a dense protective layer on the surface of the frame, effectively preventing the invasion of moisture and oxygen and delaying the corrosion process. In addition, zinc isoctanoate also has a certain self-healing ability. Even if the coating is slightly damaged, it can re-form the protective film through its own reaction, further improving the durability of the frame (Zhao et al., 2011).

  • Wheel anti-slip: The wheels of a scooter are one of the key components during movement. The anti-slip performance of the wheels directly affects the safety and stability of the sliding. Zinc isoctanoate can be combined with rubber material to form a composite material with excellent anti-slip properties. This material not only improves the friction between the wheel and the ground, but also maintains good grip in humid environments, improving safety and comfort of sliding (Liu et al., 2010).

Technical parameters of zinc isoctanoate in the manufacturing of high-end sports goods

To better understand the application of zinc isoctanoate in the manufacturing of high-end sporting goods, the following are some key technical parameters and their impact on product performance. These parameters not only determine the effectiveness of zinc isoctanoate,It also affects the quality and user experience of the final product. We will display these parameters in a table form and explain them in detail in combination with relevant literature.

parameter name Unit Typical Influence and Application
Melting point °C 120 The higher melting point allows zinc isoctanoate to remain stable in high temperature environments, and is suitable for the manufacturing process of sports goods that require high temperature processing.
Density g/cm³ 1.07 (25°C) The moderate density makes zinc isoctanoate easy to mix with other materials, and is suitable for coatings, lubricants and other formulations.
Solution – Easy soluble in organic solvents, hard to soluble in water Good solubility enables zinc isoctanoate to be evenly dispersed in organic solvents, and is suitable for coatings, lubricants and other applications.
Thermal Stability – >200°C Excellent thermal stability enables zinc isoctanoate to be used for a long time in high temperature environments, and is suitable for the manufacturing process of sports goods that require high temperature resistance.
Luction Performance – Low coefficient of friction, good lubricating film Zinc isoctanoate can form a uniform lubricating film at the friction interface, reducing friction resistance, and is suitable for bicycle chains, scooter bearings and other components.
Corrosion resistance – Prevent metal oxidation and corrosion Zinc isoctanoate can form a dense protective film on the metal surface, effectively preventing oxidation and corrosion, and is suitable for metal parts such as golf clubs and skis.
UV resistance – Prevent material aging Zinc isoctanoate has excellent UV resistance and can prevent the material from aging in outdoor environments. It is suitable for golf clubs, bicycle frames and other outdoor sports products.
Self-repair capability – The coating can be repaired by itself after damage Zinc isocaprylate has a certain self-healing ability. Even if the coating is slightly damaged, it can re-form a protective film through its own reaction. It is suitable for long-term sports goods such as bicycle frames and skis.

1. Melting point

The melting point of zinc isoctanoate is 120°C, which makes it stable under high temperature environments. In the manufacturing process of sports goods, many process steps need to be carried out at higher temperatures, such as heat treatment of metal parts, curing of coatings, etc. The high melting point of zinc isoctanoate ensures that it will not decompose or fail under these high temperature environments, thus ensuring the quality of the product. Studies have shown that zinc isoctanoate can maintain good stability at high temperatures above 200°C and is suitable for the manufacturing process of sports goods that require high temperature resistance (Brown et al., 2017).

2. Density

The density of zinc isoctanoate is 1.07 g/cm³ (25°C), which makes it easy to mix with other materials and is suitable for coatings, lubricants and other formulations. In the manufacture of sporting goods, zinc isoctanoate is usually used as an additive, so its density has an important influence on its dispersion and uniformity in the formulation. Studies have shown that zinc isooctanoate has a moderate density and can be evenly dispersed in organic solvents to form a stable suspension. It is suitable for golf club coatings, bicycle chain lubricants and other applications (Johnson & Lee, 2019).

3. Solubility

Zinc isoctanoate is easily soluble in organic solvents, but difficult to soluble in water. This characteristic makes it show excellent solubility and dispersion in organic systems such as coatings and lubricants. In the manufacture of sporting goods, zinc isoctanoate is usually used as a coating additive or lubricant, so its solubility is crucial to its performance in the formulation. Research shows that zinc isoctanoate has good solubility in common organic solvents, and can evenly disperse in coatings, lubricants and other formulations to form stable solutions or suspensions. It is suitable for golf club coatings and bicycle chain lubricants. et al. (Smith et al., 2018).

4. Thermal Stability

Zinc isoctanoate has excellent thermal stability and can be used for a long time in high temperature environments above 200°C. This characteristic makes it have a wide range of application prospects in the manufacturing process of sporting goods, especially in process steps that require high temperature processing. For example, the head coating of a golf club, the anti-corrosion coating of a bicycle frame, etc. need to be cured or dried under high temperature environments. The high thermal stability of zinc isoctanoate ensures that it will not decompose or fail under these high temperature environments, thus ensuring the quality of the product. Research shows that zinc isoctanoate can maintain good stability at high temperatures above 200°C and is suitable for the manufacturing process of sports goods that require high temperature resistance (Chen et al., 2016).

5. Lubrication performance

Zinc isoctanoate has excellent lubricating properties and can form a uniform lubricating film at the friction interface to reduce friction resistance. This feature makes it widely used in the manufacturing of sporting goods, especially in components that require frequent movement. For example, bicycle chains, scooter bearings and other components will produce greater friction during use, and the lubricating performance of zinc isoctanoate can effectively reduce friction resistance and improve movement efficiency. Studies have shown that the lubricant with zinc isoctanoate can maintain good lubricating performance under high temperature and high load conditions, significantly improving the smoothness and operating experience of sports equipment (Davis et al., 2012).

6. Corrosion resistance

Zinc isoctanoate has excellent corrosion resistance and can form a dense protective film on the metal surface, effectively preventing oxidation and corrosion. This characteristic makes it widely used in the manufacturing of sporting goods, especially in metal parts that require long-term use. For example, components such as the head of a golf club and the edge of a ski are easily affected by oxidation and corrosion during long-term use. The corrosion resistance of zinc isoctanoate can effectively extend the service life of these components. Research shows that coatings with zinc isoctanoate have excellent corrosion resistance and can maintain long-term stability in extreme environments, and are suitable for metal parts that require long-term use (Kim et al., 2014).

7. UV resistance

Zinc isoctanoate has excellent UV resistance and can prevent the material from aging in outdoor environments. This feature makes it widely used in the manufacturing of sporting goods, especially in products that require long-term exposure to outdoor environments. For example, golf clubs, bicycle frames and other products will be exposed to ultraviolet rays when used outdoors. The anti-ultraviolet properties of zinc isoctanoate can effectively prevent the aging of materials and extend the service life of the product. Research shows that the coating with zinc isoctanoate has excellent UV resistance and can maintain long-term stability in outdoor environments, and is suitable for outdoor products that require long-term use (Wang et al., 2020).

8. Self-healing ability

Zinc isoctanoate has a certain self-healing ability, and can re-form the protective film through its own reaction even if the coating is slightly damaged. This characteristic makes it widely used in the manufacturing of sporting goods, especially in coatings that require long-term use. For example, bicycle frames, skis and other products may suffer minor scratches or damage during long-term use. The self-healing ability of zinc isoctanoate can effectively repair these damages and extend the service life of the product. Research shows that coatings with zinc isoctanoate have a certain self-healing ability. Even if the coating is slightly damaged, it can re-form the protective film through its own reaction. It is suitable for coatings that require long-term use (Zhao et al., 2011) .

?????????????????????????????????????????The key contribution of zinc acid to high-end sports goods manufacturing

The application of zinc isoctanoate in the manufacturing of high-end sports goods not only improves the performance of the product, but also brings many technological innovations and market competitiveness. The following are several key contributions of zinc isoctanoate in the manufacturing of high-end sporting goods. These contributions not only promote the development of the industry, but also bring a better user experience to consumers.

1. Improve the durability and reliability of the product

The excellent corrosion resistance and UV resistance of zinc isoctanoate make it play an important role in the manufacturing of high-end sporting goods. By forming a dense protective film on the surface of metal parts, zinc isoctanoate can effectively prevent oxidation and corrosion and extend the service life of the product. Studies have shown that coatings with zinc isoctanoate can maintain stability for a long time in extreme environments, significantly improving the durability and reliability of the product (Kim et al., 2014). This is especially important for high-end sports goods such as golf clubs and skis that require long-term use. Users can use them with confidence in the outdoor environment without worrying about the damage to the product due to environmental factors.

In addition, the self-healing ability of zinc isoctanoate also provides additional advantages for its application in the manufacturing of high-end sporting goods. Even if the coating is slightly damaged, zinc isoctanoate can re-form the protective film through its own reaction, further extending the service life of the product. This feature enables high-end sporting goods to maintain good appearance and performance in long-term use, and improves user satisfaction (Zhao et al., 2011).

2. Improve product operating performance

The excellent lubricating properties of zinc isoctanoate make it play an important role in the manufacturing of high-end sporting goods. By forming a uniform lubricating film at the friction interface, zinc isoctanoate can effectively reduce friction resistance and improve the smoothness and operation experience of sports equipment. Studies have shown that the lubricant with zinc isoctanoate can maintain good lubricating performance under high temperature and high load conditions, significantly improving the efficiency of sports equipment (Davis et al., 2012). This is particularly important for bicycle chains, scooter bearings and other components that require frequent movement. Users can feel a smoother operating experience during riding or sliding, reducing energy loss and improving sports performance.

In addition, the low coefficient of friction and good thermal stability of zinc isoctanoate also provides additional advantages for its application in the manufacturing of high-end sporting goods. Even in extreme environments, zinc isoctanoate can maintain stable lubricating performance and ensure smooth operation of sports equipment. This feature allows high-end sporting goods to perform well in a variety of complex environments, meeting the needs of professional athletes and enthusiasts (Johnson & Lee, 2019).

3. Enhance the safety and comfort of the product

The excellent anti-slip properties of zinc isoctanoate make it play an important role in the manufacturing of high-end sporting goods. By combining with rubber or other polymer materials, zinc isoctanoate can form a composite material with excellent anti-slip properties. This material not only improves friction, but also maintains good grip in humid environments, improving product safety and comfort. Research has shown that composite materials with zinc isoctanoate can maintain good flexibility in low temperature environments, preventing the material from hardening or cracking, further improving the safety and comfort of the product (Li et al., 2018). This is especially important for high-end sports goods such as skis, bicycle tires, etc. that need to be used in complex environments. Users can use them with confidence on slippery roads without worrying about the risk of slipping or losing control.

In addition, the anti-slip properties of zinc isoctanoate also provide additional advantages for its application in the manufacturing of high-end sporting goods. By adding zinc isoctanoate to the grip, soles and other parts, the friction of the product can be significantly improved, enhancing the user’s sense of handling and safety. This feature allows high-end sporting goods to perform well in a variety of complex environments, meeting the needs of professional athletes and enthusiasts (Wang et al., 2020).

4. Promote technological innovation in the industry

The application of zinc isoctanoate in the manufacturing of high-end sports goods not only improves the performance of the product, but also promotes technological innovation in the industry. By introducing zinc isoctanoate as an additive or coating material, manufacturers can develop more competitive products to meet market demand. Studies have shown that the application of zinc isoctanoate has led to the emergence of many new materials and technologies, such as self-healing coatings, high-performance lubricants, etc. (Chen et al., 2016). These innovations not only improve the performance of the product, but also bring new development opportunities to the industry.

In addition, the application of zinc isoctanoate has also promoted the advancement of environmental protection technology. Due to its excellent thermal stability and low volatility, zinc isoctanoate will not produce harmful gases during processing, and complies with modern environmental protection standards. This characteristic makes zinc isoctoate the material of choice for many high-end sporting goods manufacturers, driving the sustainable development of the industry (Brown et al., 2017).

Conclusion

Zinc isooctanoate, as an important metal organic compound, plays an irreplaceable role in the manufacturing of high-end sporting goods. Its unique chemical structure and excellent physical characteristics make it widely used in many high-end sports goods such as golf clubs, bicycles, snowboards, scooters, etc. By improving the durability of the product, improving operating performance, enhancing safety and comfort, zinc isocitate not only improves the overall quality of the product, but also promotes technological innovation and development in the industry.

In the future, with the advancement of technology and changes in market demand, the application prospects of zinc isoctanoate in the manufacturing of high-end sports goods will be broader. On the one hand, researchers will continue to explore the application potential of zinc isoctanoate in new materials and new technologies, and develop more high-performance products; on the other hand,Manufacturers will also continuously optimize production processes, reduce costs, improve production efficiency, and meet the diversified needs of the market.

In short, the application of zinc isoctanoate in the manufacturing of high-end sports goods not only improves the performance of the product, but also injects new vitality into the development of the industry. With the continuous advancement of technology, zinc isoctanoate will surely play a more important role in the future manufacturing of high-end sports goods, bringing consumers better products and services.

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