Case Study on the Application of Tin Butyl Mercaptate in Polyvinyl Chloride (PVC) Stabilizer

Introduction

Butylmercaptostannane, chemical formula C4H10OSSn, CAS number 26410-42-4, is an efficient organotin stabilizer that is widely used in polyvinyl chloride (PVC) products to improve the thermal stability of the material. Stability and processing performance. PVC is an extremely important thermoplastic, but it has poor thermal stability and is prone to degradation during processing, resulting in reduced product performance. Therefore, adding appropriate stabilizers is crucial to ensuring the quality of PVC products.

Characteristics of butyltin mercaptide

As a thiol metal compound, butyltin mercaptide has good thermal stability and transparency, and can effectively inhibit the dehydrochlorination reaction of PVC at high temperatures and prevent polymer chain breakage, thus extending the service life of PVC. . In addition, it can provide good initial coloration and long-term stability, allowing PVC products to maintain their original color and mechanical properties.

Application cases

In the production of rigid PVC products, such as profiles, pipes and sheets, tin butylmercaptide is used as a primary stabilizer or part of a co-stabilizer. For example, a PVC profile manufacturer discovered during the production process that the traditionally used calcium zinc stabilizer could not meet the strict requirements of some high-end markets. Especially for products for long-term outdoor use, its weather resistance and color stability were obviously insufficient.

To address this issue, the manufacturer began evaluating and testing the possibility of tin butyl mercaptide as a stabilizer. After a series of laboratory tests and small-scale production tests, the results show that after adding an appropriate amount of butyltin mercaptide, the thermal stability and color stability of PVC profiles are significantly improved. Even under long-term outdoor exposure conditions, the product It can also maintain a low yellowing index without significant decrease in mechanical strength.

Implementation details

In the specific implementation process, the amount of butyltin mercaptide added needs to be adjusted according to the specific requirements of the PVC formula and the expected performance targets. Generally speaking, the addition amount is between 0.1% and 0.5% to achieve good stabilizing effect. In order to ensure uniform dispersion, butyltin mercaptide is usually added to PVC resin during the mixing stage together with other auxiliary stabilizers (such as antioxidants, light stabilizers) and lubricants.

Results and discussion

After the optimized formula, PVC profiles not only show excellent processing fluidity and colorability in the initial processing stage, but also have significantly improved physical properties and appearance quality during the subsequent use cycle. Especially in outdoor environments, the addition of butyltin mercaptide extends the service life of PVC profiles from the original 5-7 years to more than 10 years, greatly improving the market competitiveness of the product.

Conclusion

As a high-performance PVC stabilizer, tin butyl mercaptide can effectively improve the thermal stability and long-term durability of PVC products through its unique chemical structure and mechanism of action. In the PVC processing industry, rational selection and optimization of stabilizer systems are of great significance to the development of high-quality, high value-added PVC products.

References

This case study is based on industry experience and public literature. Specific values ??and case details may vary depending on the experimental conditions of different manufacturers. For more detailed information, it is recommended to refer to professional literature and reports in the relevant field.


Please note that the above case study is constructed based on a general understanding of the properties and applications of tin butyl mercaptide and is not based on a specific actual industrial case . In practical applications, the performance of butyltin mercaptide may be affected by a variety of factors, including but not limited to the type of PVC resin, processing conditions, blend composition, etc. Therefore, when selecting and using butyltin mercaptide as a stabilizer, sufficient testing and evaluation should be carried out to ensure the best results.

Extended reading:

CAS:2212-32-0 – Manufacturer of N,N-Dicyclohexylmethylamine and N,N-Dimethylcyclohexylamine – Shanghai Ohans Co., LTD

N,N-Dicyclohexylmethylamine – Manufacturer of N,N-Dicyclohexylmethylamine and N,N-Dimethylcyclohexylamine – Shanghai Ohans Co ., LTD

bismuth neodecanoate/CAS 251-964-6 – Amine Catalysts (newtopchem.com)

stannous neodecanoate catalysts – Amine Catalysts (newtopchem.com)

polyurethane tertiary amine catalyst/Dabco 2039 catalyst – Amine Catalysts (newtopchem.com)

DMCHA – morpholine

N-Methylmorpholine – morpholine

Polycat 41 catalyst CAS10294-43-5 Evonik Germany – BDMAEE

Polycat DBU catalyst CAS6674-22-2 Evonik Germany – BDMAEE

Butyltin mercaptide synthesis method and technology

Synthesis method and process of tin butyl mercaptide

Butylmercaptostannane, chemical formula C4H10OSSn, is a commonly used organotin compound, mainly used as a stabilizer for polyvinyl chloride (PVC) and is favored for its excellent thermal stability and transparency. . The following will discuss several typical synthesis methods and process flows of butyltin mercaptide.

Synthetic route one: reaction between butyltin chloride and mercaptans

This is one of the common methods for synthesizing tin butyl mercaptide. Butyltin chloride (BuSnCl3) is used as the starting material and reacts with butylthiol (BuSH) under an appropriate solvent and temperature to generate butyltin mercaptide. This reaction can be expressed as:

BuSnCl3+BuSH?Bu2SnS+3HClBuSnCl3?+BuSH?Bu2?SnS+3HCl

Process steps:
  1. Raw material preparation: Weigh butyltin chloride and butylmercaptan in a certain proportion, and prepare a dry reaction vessel and solvent.
  2. Control of reaction conditions: Under nitrogen protection, dissolve the raw materials in a solvent, such as dichloromethane or tetrahydrofuran, and then stir the mixture under mild heating conditions.
  3. By-product removal: After the reaction is completed, unreacted raw materials and by-products are removed by filtration or distillation. For example, hydrochloric acid can be removed by washing with water.
  4. Product purification: Further purify the product through column chromatography, crystallization or distillation.
  5. Finished product inspection: Products need to undergo quality inspection, including the measurement of purity, color, specific gravity, refractive index and other indicators to ensure compliance with standards.

Synthesis Route 2: Reaction of Butyltin Alcohol and Hydrogen Sulfide

Another synthetic route is to use butyltin alcohol (Bu2SnOH) to react with hydrogen sulfide (H2S) to generate butyltin mercaptide. The reaction equation is as follows:

Bu2SnOH+H2S?Bu2SnS+H2OBu2?SnOH+H2?S?Bu2?SnS+H2?O

Process steps:
  1. Raw material mixing: Mix butyltin alcohol and hydrogen sulfide gas under an inert gas environment.
  2. Reaction catalysis: Catalysts (such as acids or bases) may be needed to promote the reaction.
  3. Product isolation: by distillation.??Other physical methods separate products and unreacted raw materials.
  4. Refining: Use appropriate methods to remove impurities and improve product purity.

Process notes:

  • Safety considerations: The raw materials and by-products involved in the synthesis process of butyltin mercaptide may be corrosive or toxic. Appropriate personal protective equipment must be worn during operation and in a well-ventilated environment. carried out under the conditions.
  • Reaction conditions: Controlling reaction temperature, pressure and solvent selection are crucial to the efficiency of the reaction and the purity of the product.
  • Environmental protection measures: By-products produced by the reaction, such as hydrochloric acid or water, need to be properly treated to avoid environmental pollution.

Conclusion

The synthesis of tin butyl mercaptide is a process involving multi-step chemical reactions, which requires precise control of reaction conditions and process parameters. In industrial production, factors such as cost-effectiveness, environmental protection and safety regulations also need to be considered to achieve efficient, green and sustainable production goals. Different synthesis routes are suitable for different production scales and needs, and choosing the appropriate process flow is the key to success.

Extended reading:

CAS:2212-32-0 – Manufacturer of N,N-Dicyclohexylmethylamine and N,N-Dimethylcyclohexylamine – Shanghai Ohans Co., LTD

N,N-Dicyclohexylmethylamine – Manufacturer of N,N-Dicyclohexylmethylamine and N,N-Dimethylcyclohexylamine – Shanghai Ohans Co ., LTD

bismuth neodecanoate/CAS 251-964-6 – Amine Catalysts (newtopchem.com)

stannous neodecanoate catalysts – Amine Catalysts (newtopchem.com)

polyurethane tertiary amine catalyst/Dabco 2039 catalyst – Amine Catalysts (newtopchem.com)

DMCHA – morpholine

N-Methylmorpholine – morpholine

Polycat 41 catalyst CAS10294-43-5 Evonik Germany – BDMAEE

Polycat DBU catalyst CAS6674-22-2 Evonik Germany – BDMAEE

Butyl tin mercaptide market analysis report

Market Overview

As an important organotin compound, butyltin mercaptide is widely used in plastic stabilizers, catalysts and other fields, especially in the processing of polyvinyl chloride (PVC). In recent years, with the growth of global demand for environmentally friendly materials and the continued expansion of the PVC industry, the market demand for butyltin mercaptide has shown a steady upward trend. As one of the world’s largest production and consumption markets of butyltin mercaptide, China’s industry dynamics have an important impact on the global market.

Requirements analysis

The main downstream application markets of butyltin mercaptide include PVC products, coatings, adhesives and other industries. With the widespread application of PVC materials in construction, packaging, automobiles and other fields, the demand for high-quality stabilizers continues to increase, driving the market demand for butyltin mercaptide. In addition, consumers’ emphasis on product safety and environmental protection has prompted the industry to transition to more efficient and less toxic stabilizers. As a relatively environmentally friendly choice, butyl tin mercaptide is expected to further expand market demand.

Supply analysis

China’s production capacity of butyltin mercaptide occupies a dominant position globally. There are many large manufacturers in the industry and the market competition is fierce. However, due to the continuous improvement of environmental protection and safety requirements in the production process, some small or non-compliant production capacities have been gradually phased out, and industry concentration has increased. This has led to a general improvement in product quality on the market, but it has also increased production costs and may put upward pressure on product prices.

Technological innovation

Technological innovation is a key factor driving the development of the butyltin mercaptide market. The development of new synthesis technologies, such as the use of more efficient catalysts and more environmentally friendly production processes, not only improves production efficiency, but also reduces environmental pollution and meets the market’s demand for sustainable development. In addition, the optimization of product performance, such as improving thermal stability and transparency, has also promoted the application of butyltin mercaptide in the high-end market.

Market Challenges

Although the market prospects of butyltin mercaptide are optimistic, it still faces some challenges. First of all, environmental protection regulations are becoming increasingly strict, which puts forward higher requirements for the production of butyltin mercaptide and increases the operating costs of enterprises. Secondly, the emergence of substitutes, such as calcium zinc stabilizers, organotin composite stabilizers, etc., poses a threat to the market share of butyltin mercaptide. Finally, uncertainty in the global supply chain, such as raw material price fluctuations, international trade frictions, etc., may also affect market stability.

Development trends

The butyltin mercaptide market is expected to continue to grow in the next few years, but the growth rate may slow down due to the above-mentioned challenges. The industry will pay more attention to green, environmentally friendly, and efficient production methods, while increasing investment in research and development, improving product performance, and exploring new application areas. In addition, industry consolidation will continue. Large companies will enhance their market competitiveness through mergers and acquisitions, while small companies will need to seek survival space through technological innovation.

Conclusion

The development of the tin butyl mercaptide market is affected by multiple factors, including the growth of downstream demand, the implementation of environmental protection policies, the promotion of technological innovation, etc. . Facing a market environment where challenges and opportunities coexist, companies need to flexibly adjust strategies, strengthen research and development, and increase product added value to maintain competitive advantages. At the same time, the industry should actively respond to the call for environmental protection, promote sustainable development, and jointly build a healthy and stable market ecology.

Please note that the above analysis is based on currently available information and general market trends, and specific market conditions may vary due to changes in a variety of factors. For detailed market data and new developments, it is recommended to refer to new reports from professional market research institutions.

Extended reading:

CAS:2212-32-0 – Manufacturer of N,N-Dicyclohexylmethylamine and N,N-Dimethylcyclohexylamine – Shanghai Ohans Co., LTD

N,N-Dicyclohexylmethylamine – Manufacturer of N,N-Dicyclohexylmethylamine and N,N-Dimethylcyclohexylamine – Shanghai Ohans Co ., LTD

bismuth neodecanoate/CAS 251-964-6 – Amine Catalysts (newtopchem.com)

stannous neodecanoate catalysts – Amine Catalysts (newtopchem.com)

polyurethane tertiary amine catalyst/Dabco 2039 catalyst – Amine Catalysts (newtopchem.com)

DMCHA – morpholine

N-Methylmorpholine – morpholine

Polycat 41 catalyst CAS10294-43-5 Evonik Germany – BDMAEE

Polycat DBU catalyst CAS6674-22-2 Evonik Germany – BDMAEE