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Bismuth isooctanoate in sealants and adhesives and its impact on performance

admin 9月 26th, 2024 News

Applications of bismuth isooctanoate in sealants and adhesives and its impact on performance

Introduction

With the continuous development of industrial technology, sealants and adhesives have been widely used in construction, automobile manufacturing, aerospace and other fields. Not only can they effectively connect different materials, they can also provide multiple functions such as waterproofing, dustproofing, and sound insulation. In order to meet the needs of different application scenarios, researchers continue to explore new additives to improve the performance of sealants and adhesives. Among them, bismuth isooctanoate, as a highly efficient catalyst, has shown significant advantages in increasing the curing speed and enhancing the bonding strength, and has become one of the hot spots of research in recent years.

Basic properties of bismuth isooctanoate

Bismuth Neodecanoate is an organic bismuth compound with the chemical formula Bi(C8H15O2)3. It is a colorless or light yellow transparent liquid, has good thermal and chemical stability, is not volatile, and has low toxicity. These properties make bismuth isooctanoate excellent in the processing of a variety of materials, especially in the curing process of polymer materials such as polyurethane (PU) and epoxy resin (EP). It is particularly widely used as a catalyst.

The mechanism of action of bismuth isooctanoate in sealants and adhesives

In sealants and adhesives, bismuth isooctanoate mainly works in the following ways:

Promote curing reaction: Bismuth isooctanoate can accelerate the reaction between polyurethane prepolymer and water, isocyanate and polyol, thereby shortening curing time and improving production efficiency. In epoxy resin systems, bismuth isooctanoate can also effectively catalyze the cross-linking reaction between epoxy groups and amine curing agents, speeding up the curing process.
Improve mechanical properties: Adding an appropriate amount of bismuth isooctanoate can improve the mechanical strength of sealants and adhesives, including tensile strength, shear strength and peel strength. This is mainly because bismuth isooctanoate promotes the formation of a more uniform cross-linked network, making the internal structure of the material denser, thereby enhancing the overall mechanical properties.
Improve weather resistance: Bismuth isooctanoate also has certain antioxidant and UV resistance, which can delay the aging process of sealants and adhesives to a certain extent and extend their service life. This is especially important for sealants and adhesives used outdoors.
Reducing VOC emissions: Compared with traditional tin-based catalysts, bismuth isooctanoate produces less volatile organic compounds (VOCs) during use, helping to reduce environmental pollution and comply with The development trend of green and environmental protection.

Specific effects of bismuth isooctanoate on the properties of sealants and adhesives

1. Curing speed

Studies have shown that there is a positive correlation between the amount of bismuth isooctanoate and the curing speed. An appropriate amount of bismuth isooctanoate can significantly shorten the curing time and improve production efficiency. For example, adding 0.1% to 0.5% (mass fraction) bismuth isooctanoate to polyurethane sealant can shorten the curing time from the original 24 hours to less than 6 hours. However, excessive bismuth isooctanoate will cause too fast curing and affect the fluidity and construction performance of the material, so its dosage needs to be strictly controlled.

2. Bonding strength

Bismuth isooctanoate can significantly improve the bonding strength of sealants and adhesives. Experimental results show that the shear strength of polyurethane adhesives containing 0.2% bismuth isooctanoate on stainless steel and glass substrates increased by 20% and 30% respectively. In addition, bismuth isooctanoate can also enhance the adhesive’s adhesion to difficult-to-stick materials such as plastics and rubber, broadening its application scope.

3. Weather resistance

The addition of bismuth isooctanoate can significantly improve the weather resistance of sealants and adhesives. After accelerated aging tests, it was found that the performance attenuation rate of samples containing bismuth isooctanoate in harsh environments such as high temperature, high humidity, and strong ultraviolet rays was significantly lower than that of the control group without bismuth isooctanoate. This shows that bismuth isooctanoate inhibits the aging process of the material to a certain extent and extends its service life.

4. VOC emissions

Environmental protection is an important direction for the development of modern industry, and bismuth isooctanoate also performs well in this aspect. Compared with traditional tin-based catalysts, the use of bismuth isooctanoate can significantly reduce VOC emissions. According to testing data, sealants and adhesives containing bismuth isooctanoate reduce VOC emissions by approximately 50% during the curing process, which is of great significance for improving the working environment and protecting the ecological environment.

Application cases

1. Automobile manufacturing industry

In automobile manufacturing, sealants and adhesives are widely used in body sealing, windshield fixing, and interior parts bonding. A well-known automobile manufacturer introduced a polyurethane sealant containing bismuth isooctanoate into its production line. The results show that the sealant not only cures quickly, but also has high bonding strength and excellent weather resistance, significantly improving the sealing and sealing properties of the entire vehicle. Security.

2. Construction industry

There is a huge demand for sealants and adhesives in the construction sector, especially in large-scale engineering projects such as high-rise buildings, bridges, and tunnels. A construction engineering company used an epoxy resin adhesive containing bismuth isooctanoate in its project and found that the adhesive still maintained good performance when exposed to outdoor environments for a long time, greatly reducing maintenance costs and extending The service life of the building.

3. Electronic products

Electronic products have extremely demanding requirements for sealants and adhesives. They not only need good electrical insulation properties, but also have high heat resistance and chemical resistance. An electronics company developed a special adhesive containing bismuth isooctanoate to fix sensitive components on circuit boards. Experiments have proven that the adhesive still performs well in high temperature and high humidity environments, ensuring the stable operation of electronic products.

Conclusion

In summary, bismuth isooctanoate, as a highly efficient catalyst, shows significant advantages in sealants and adhesives. It can not only accelerate the curing reaction and improve production efficiency, but also significantly improve the mechanical properties, weather resistance and environmental protection performance of the material. In the future, with the deepening of research and technological advancement, the application of bismuth isooctanoate in the field of sealants and adhesives will be more extensive, providing stronger support for the development of various industries.

Extended reading:
DABCO MP608/Delayed equilibrium catalyst

TEDA-L33B/DABCO POLYCAT/Gel catalyst

Addocat 106/TEDA-L33B/DABCO POLYCAT

3-morpholinopropylamine

Toyocat NP catalyst Tosoh

Toyocat ETS Foaming catalyst Tosoh

Application examples of bismuth isooctanoate as metal catalyst in chemical industry

admin 9月 26th, 2024 News

Application examples of bismuth isooctanoate as a metal catalyst in the chemical industry

Introduction

Bismuth Neodecanoate, as an important organometallic catalyst, has been widely used in the chemical industry because of its unique physical and chemical properties. This article will introduce in detail the application examples of bismuth isooctanoate in different chemical industry fields, and explore its important role and advantages in catalytic reactions.

Basic properties of bismuth isooctanoate

Bismuth isooctanoate is an organic bismuth compound with the chemical formula Bi(C8H15O2)3. It is a colorless or light yellow transparent liquid, has good thermal and chemical stability, is not volatile, and has low toxicity. These properties make it excellent in a variety of chemical reactions, especially in catalytic reactions, where it can significantly increase reaction rates and selectivity.

Application of bismuth isooctanoate in polymer synthesis

1. Polyurethane (PU) synthesis

Polyurethane is an important polymer material widely used in coatings, adhesives, foams and other fields. In the synthesis process of polyurethane, bismuth isooctanoate serves as a catalyst, which can significantly accelerate the reaction between isocyanate and polyol, increase the reaction rate and the molecular weight of the product. Specific application examples are as follows:

Accelerate the curing reaction: Adding 0.1%~0.5% (mass fraction) bismuth isooctanoate to polyurethane coatings can significantly shorten the curing time from the original 24 hours to less than 6 hours . This not only increases production efficiency, but also improves the mechanical properties and weather resistance of the coating.
Improve product performance: Bismuth isooctanoate can also improve the mechanical properties of polyurethane materials, such as tensile strength, shear strength and peel strength. Experimental results show that the shear strength of polyurethane adhesives containing 0.2% bismuth isooctanoate on stainless steel and glass substrates increased by 20% and 30% respectively.

2. Epoxy resin (EP) curing

Epoxy resin is a high-performance thermosetting resin that is widely used in electronic packaging, composite materials, anti-corrosion coatings and other fields. During the curing process of epoxy resin, bismuth isooctanoate serves as a catalyst, which can significantly accelerate the cross-linking reaction between epoxy groups and amine curing agents, improving the curing speed and product performance. Specific application examples are as follows:

Shorten the curing time: Adding 0.1%~0.3% (mass fraction) of bismuth isooctanoate to epoxy resin electronic packaging materials can significantly shorten the curing time from the original 12 hours to within 4 hours. This not only increases production efficiency, but also improves the electrical and mechanical properties of the packaging materials.
Improve heat resistance: Bismuth isooctanoate can also improve the heat resistance of epoxy resin, allowing it to maintain good performance in high temperature environments. Experimental results show that the mechanical and electrical properties of epoxy resin containing 0.2% bismuth isooctanoate did not significantly decrease after continuous use for 1,000 hours at 200°C.

Application of bismuth isooctanoate in organic synthesis

1. Dehydration reaction of alcohol

In organic synthesis, the dehydration reaction of alcohol is an important step and is often used to prepare alkenes and ether compounds. As a catalyst, bismuth isooctanoate can significantly improve the dehydration reaction rate and selectivity of alcohol. Specific application examples are as follows:

Increase the reaction rate: In the reaction of dehydrating ethanol to prepare ethylene, adding 0.5% (mass fraction) bismuth isooctanoate can significantly increase the reaction rate and allow the reaction to proceed at a lower temperature. Reduce the occurrence of side reactions.
Improve selectivity: Bismuth isooctanoate can also improve the selectivity of alcohol dehydration reaction and reduce the formation of by-products. Experimental results show that in a reaction system containing bismuth isooctanoate, the selectivity of ethanol dehydration to ethylene reaches more than 95%.

2. Esterification reaction

Esterification reaction is a common reaction type in organic synthesis and is often used to prepare various ester compounds. Bismuth isooctanoate serves as a catalyst and can significantly increase the rate and yield of the esterification reaction. Specific application examples are as follows:

Increase the reaction rate: In the esterification reaction of acetic acid and ethanol, adding 0.3% (mass fraction) bismuth isooctanoate can significantly increase the reaction rate and make the reaction complete in a shorter time. Finish.
Improving yield: Bismuth isooctanoate can also increase the yield of esterification reaction and reduce the formation of by-products. Experimental results show that in the reaction system containing bismuth isooctanoate, the yield of ethyl acetate reaches more than 90%.

Application of bismuth isooctanoate in fine chemicals

1. Synthesis of pharmaceutical intermediates

In the synthesis of pharmaceutical intermediates, bismuth isooctanoate serves as a catalyst and can significantly increase the rate and selectivity of the reaction. Specific application examples are as follows:

Increase the reaction rate: In the synthesis reaction of certain drug intermediates, adding 0.1%~0.5% (mass fraction) bismuth isooctanoate can significantly increase the reaction rate and make the reaction faster. Completed in a short time.
Improve selectivity: Bismuth isooctanoate can also improve the selectivity of the reaction, reduce the formation of by-products, and improve the purity of the target product. Experimental results show that in the reaction system containing bismuth isooctanoate, the purity of the target product reaches more than 98%.

2. Flavor synthesis

In spicesIn the synthesis, bismuth isooctanoate is used as a catalyst, which can significantly improve the rate and selectivity of the reaction. Specific application examples are as follows:

Improving the reaction rate: In the synthesis reaction of certain fragrance compounds, adding 0.1%~0.5% (mass fraction) of bismuth isooctanoate can significantly increase the reaction rate and make the reaction shorter. completed within the time limit.
Improve selectivity: Bismuth isooctanoate can also improve the selectivity of the reaction, reduce the formation of by-products, and improve the purity of the target product. Experimental results show that in the reaction system containing bismuth isooctanoate, the purity of the target spice reaches more than 95%.

Applications of bismuth isooctanoate in the field of environmental protection

1. Waste gas treatment

In exhaust gas treatment, bismuth isooctanoate serves as a catalyst and can significantly improve the degradation efficiency of organic pollutants in exhaust gas. Specific application examples are as follows:

Improve degradation efficiency: When treating waste gas containing VOCs (volatile organic compounds), adding 0.1%~0.5% (mass fraction) of bismuth isooctanoate can significantly improve the degradation efficiency of VOCs. , reduce pollutant emissions.
Reducing energy consumption: Bismuth isooctanoate can also reduce the energy consumption of waste gas treatment, allowing the reaction to proceed at a lower temperature, reducing energy consumption. Experimental results show that in the reaction system containing bismuth isooctanoate, the degradation efficiency of VOCs reaches more than 90%.

2. Wastewater treatment

In wastewater treatment, bismuth isooctanoate serves as a catalyst and can significantly improve the degradation efficiency of organic pollutants in wastewater. Specific application examples are as follows:

Improve degradation efficiency: When treating wastewater containing organic pollutants, adding 0.1%~0.5% (mass fraction) of bismuth isooctanoate can significantly improve the degradation efficiency of organic pollutants and reduce Discharge of pollutants.
Reducing energy consumption: Bismuth isooctanoate can also reduce the energy consumption of wastewater treatment, allowing the reaction to proceed at a lower temperature, reducing energy consumption. Experimental results show that in the reaction system containing bismuth isooctanoate, the degradation efficiency of organic pollutants reaches more than 90%.

Conclusion

In summary, bismuth isooctanoate, as an efficient metal catalyst, has shown broad application prospects in the chemical industry. It can not only significantly increase reaction rate and selectivity in the fields of polymer synthesis, organic synthesis, fine chemicals and environmental protection, but also improve product performance and environmental performance. In the future, with the deepening of research and technological advancement, the application of bismuth isooctanoate in the chemical industry will be more extensive, providing stronger support for the sustainable development of various industries.

Extended reading:
DABCO MP608/Delayed equilibrium catalyst

TEDA-L33B/DABCO POLYCAT/Gel catalyst

Addocat 106/TEDA-L33B/DABCO POLYCAT

3-morpholinopropylamine

Toyocat NP catalyst Tosoh

Toyocat ETS Foaming catalyst Tosoh

Analysis of the catalytic effect of bismuth isooctanoate in the curing process of thermosetting resins

admin 9月 26th, 2024 News

Analysis of the catalytic effect of bismuth isooctanoate in the curing process of thermosetting resin

Abstract

Thermosetting resin is a type of polymer material that forms a three-dimensional network structure through chemical cross-linking reactions. It is widely used in composite materials, coatings, adhesives, electronic packaging and other fields. In the curing process of thermosetting resin, catalysts play a vital role, which can significantly increase the curing speed and improve the properties of the cured product. Bismuth Neodecanoate, as an efficient organometallic catalyst, shows unique advantages in the curing process of thermosetting resins. This article reviews the catalytic mechanism of bismuth isooctanoate in the curing process of thermosetting resins and its impact on properties, and discusses its effectiveness in practical applications.

1. Introduction

Thermosetting resin is a type of polymer material that transforms from linear or branched molecules into a three-dimensional network structure under the action of heating or chemical cross-linking. This type of resin has excellent mechanical properties, heat resistance and chemical resistance, and is widely used in composite materials, coatings, adhesives, electronic packaging and other fields. In the curing process of thermosetting resin, catalysts play a vital role, which can significantly increase the curing speed and improve the properties of the cured product. Traditional catalysts include sulfur, peroxides, metal oxides, etc., but these catalysts often have problems such as slow reaction rates, high toxicity, and serious environmental pollution. In recent years, bismuth isooctanoate, as an efficient organometallic catalyst, has shown unique advantages in the curing process of thermosetting resins and has attracted widespread attention.

2. Properties of bismuth isooctanoate

Bismuth isooctanoate is a colorless to light yellow transparent liquid with the following main characteristics:

Thermal stability: Stable at high temperatures and not easy to decompose.
Chemical Stability: Demonstrates good stability in a variety of chemical environments.
Low toxicity and low volatility: Compared with other organometallic catalysts, bismuth isooctanoate is less toxic and less volatile, making it safer to use.
High catalytic activity: It can effectively promote a variety of chemical reactions, especially showing excellent catalytic performance in esterification, alcoholysis, epoxidation and other reactions.

3. Catalytic mechanism of bismuth isooctanoate in the curing process of thermosetting resin

3.1 Epoxy resin

Epoxy resin is a widely used thermosetting resin whose curing process involves the reaction of epoxy groups with a hardener. The catalytic mechanism of bismuth isooctanoate in the curing process of epoxy resin mainly includes the following steps:

Proton transfer: The bismuth ion in bismuth isooctanoate can accept the proton of the epoxy group to form an intermediate.
Nucleophilic attack: The bismuth ions in the intermediate undergo nucleophilic attack with the hardener (such as amines and acid anhydrides) to form a new intermediate.
Proton transfer: The proton in the new intermediate is transferred to another epoxy group to form a cross-linked structure.
Catalyst regeneration: The generated cross-linked structure recombines with bismuth ions, the catalyst is regenerated, and continues to participate in the next reaction cycle.

3.2 Polyurethane resin

Polyurethane resin is a type of thermosetting resin formed through the reaction of isocyanate and polyol. The catalytic mechanism of bismuth isooctanoate in the curing process of polyurethane resin mainly includes the following steps:

Proton transfer: The bismuth ion in bismuth isocyanate can accept the proton of isocyanate to form an intermediate.
Nucleophilic attack: The bismuth ions in the intermediate undergo nucleophilic attack with the polyol to form a new intermediate.
Proton transfer: The proton in the new intermediate is transferred to another isocyanate molecule, forming a cross-linked structure.
Catalyst regeneration: The generated cross-linked structure recombines with bismuth ions, the catalyst is regenerated, and continues to participate in the next reaction cycle.

3.3 Unsaturated polyester resin

Unsaturated polyester resin is a type of thermosetting resin formed through the cross-linking reaction of double bonds. The catalytic mechanism of bismuth isooctanoate in the curing process of unsaturated polyester resin mainly includes the following steps:

Proton transfer: The bismuth ion in bismuth isooctanoate can accept the proton of the double bond to form an intermediate.
Nucleophilic attack: The bismuth ions in the intermediate undergo nucleophilic attack with peroxides (such as benzoyl peroxide) to form free radicals.
Free radical polymerization: Free radicals initiate a cross-linking reaction of double bonds to form a cross-linked structure.
Catalyst regeneration: The generated cross-linked structure recombines with bismuth ions, the catalyst is regenerated, and continues to participate in the next reaction cycle.

4. Effect of bismuth isooctanoate on the properties of thermosetting resin

4.1 Curing speed

Bismuth isooctanoate can significantly accelerate the curing reaction of thermosetting resin and shorten the curing time. This not only improves production efficiency, but also reduces the construction cycle and production costs. For example, in epoxy resin, adding 0.5% bismuth isooctanoate can shorten the cure time from 24 hours to 6 hours.

4.2 Mechanical properties

Bismuth isooctanoate can improve the mechanical properties of thermosetting resins and improve solid properties.??The strength and toughness of the product. By adjusting the amount of catalyst, the hardness and flexibility of the cured product can be precisely controlled to meet the needs of different application scenarios. For example, in polyurethane resin, adding 0.3% bismuth isooctanoate can significantly improve its tensile strength and impact strength.

4.3 Heat resistance

Bismuth isooctanoate can improve the heat resistance of thermosetting resins, allowing them to maintain good performance in high temperature environments. This helps extend product life and improve product reliability. For example, in unsaturated polyester resin, adding 0.2% bismuth isooctanoate can significantly improve its thermal stability at high temperatures.

4.4 Chemical resistance

Bismuth isooctanoate can improve the chemical resistance of thermosetting resins, allowing them to exhibit better stability and corrosion resistance when exposed to chemicals such as acids, alkalis, and solvents. This helps extend product life and improve product reliability. For example, in epoxy resins, adding 0.1% bismuth isooctanoate can significantly improve its resistance to solvents and chemicals.

4.5 Environmental Protection

The low toxicity and low volatility of bismuth isooctanoate make it widely used in environmentally friendly thermosetting resins. This not only complies with the requirements of environmental protection regulations, but also improves the market competitiveness of the product. For example, in polyurethane resin, using bismuth isooctanoate instead of traditional heavy metal catalysts such as lead and tin can significantly reduce the toxicity of the product and improve its environmental performance.

5. Practical application cases

5.1 Epoxy resin

In order to improve the curing speed and mechanical properties of epoxy resin, a composite material manufacturer uses bismuth isooctanoate as a catalyst. By optimizing the amount of catalyst, the curing time was successfully shortened from 24 hours to 6 hours, while the tensile strength and impact strength of the product were improved. Ultimately, the epoxy resin composite materials produced by the company have higher mechanical properties and heat resistance, meeting market demand.

5.2 Polyurethane resin

In order to improve the curing speed and mechanical properties of polyurethane resin, an automobile sealant manufacturer uses bismuth isooctanoate as a catalyst. By optimizing the amount of catalyst, the curing time was successfully shortened from 12 hours to 4 hours, while the tensile strength and impact strength of the product were improved. Ultimately, the company produces polyurethane sealants with improved mechanical properties and chemical resistance that meet the high standards of the automotive market.

5.3 Unsaturated polyester resin

In order to improve the curing speed and heat resistance of unsaturated polyester resin, a ship coating manufacturer uses bismuth isooctanoate as a catalyst. By optimizing the amount of catalyst, the curing time was successfully shortened from 8 hours to 2 hours, while the product’s heat resistance and chemical resistance were improved. Finally, the unsaturated polyester resin coating produced by the company has higher heat resistance and chemical resistance, meeting the high standards of the shipbuilding market.

6. Future development trends

6.1 Greening

As environmental protection regulations become increasingly strict, greening will become an important development direction in the field of thermosetting resins. As a low-toxic, low-volatility catalyst, bismuth isooctanoate will be more widely used in green thermosetting resins. Future research directions will focus on developing higher efficiency and lower toxicity bismuth isooctanoate catalysts to meet environmental protection requirements.

6.2 High performance

As market demand continues to increase, the demand for high-performance thermosetting resins will continue to increase. Bismuth isooctanoate has significant advantages in improving the performance of thermoset resins. Future research directions will focus on the development of new bismuth isooctanoate catalysts to further improve the comprehensive performance of thermosetting resins.

6.3 Functionalization

Functionalized thermosetting resin refers to thermosetting resin with special functions, such as antibacterial, antifouling, self-cleaning, etc. The application of bismuth isooctanoate in functionalized thermosetting resins will be an important development direction. By combining it with other functional additives, thermosetting resin products with multiple functions can be developed.

6.4 Intelligence

Intelligent thermosetting resin refers to a thermosetting resin that can respond to changes in the external environment and automatically adjust its performance. The application of bismuth isooctanoate in intelligent thermosetting resins will be an important development direction. Through combined use with smart materials, thermosetting resin products that can automatically adjust their properties can be developed, such as temperature-sensitive resins, photosensitive resins, etc.

6.5 Nanotechnology

The application of nanotechnology in thermosetting resins will be an important development direction. By combining bismuth isooctanoate with nanomaterials, nanothermosetting resins with higher performance can be developed. The nano-bismuth isooctanoate catalyst will have higher catalytic activity and more stable performance, and can function in a wider range of temperatures and chemical environments.

7. Conclusion

Bismuth isooctanoate, as an efficient organometallic catalyst, shows unique advantages in the curing process of thermosetting resins. It can significantly accelerate the curing reaction, improve the mechanical properties, heat resistance and chemical resistance of the cured product, and also has good environmental performance. By optimizing the amount of catalyst and reaction conditions, the catalytic performance of bismuth isooctanoate can be fully utilized and the comprehensive performance of the thermosetting resin can be improved. In the future, as environmental protection regulations become increasingly stringent and market demand continues to increase, bismuth isooctanoate will show greater potential in green, high-performance, functional, intelligent and nanotechnology directions.It has great development potential and makes important contributions to the sustainable development of the thermosetting resin field. It is hoped that the information provided in this article can help researchers and companies in related fields better understand and utilize this important catalyst and promote the continued development of the thermosetting resin field.

Extended reading:
DABCO MP608/Delayed equilibrium catalyst

TEDA-L33B/DABCO POLYCAT/Gel catalyst

Addocat 106/TEDA-L33B/DABCO POLYCAT

3-morpholinopropylamine

Toyocat NP catalyst Tosoh

Toyocat ETS Foaming catalyst Tosoh

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