Polyurethane composite antioxidants provide long-term protection for high-performance materials

Polyurethane composite antioxidants: provide long-term protection for high-performance materials

Introduction: The “Invisible Guardian” of Polyurethane

In modern industry and daily life, polyurethane (PU) materials are highly favored for their outstanding performance and wide range of uses. From soft and comfortable mattresses to tough and durable automotive parts, from waterproof and wind-resistant sports soles to efficient and thermally insulated building panels, polyurethane is everywhere. However, this magical material is not perfect – during use, it may be affected by environmental factors such as oxygen, ultraviolet rays, high temperatures, etc., resulting in aging, discoloration and even degradation in performance. Just as a hero needs a loyal guard, polyurethane also needs a “guardian” that can resist external invasions. This is the protagonist we are going to introduce today – polyurethane composite antioxidant.

Polyurethane composite antioxidant is a functional additive specially designed to delay or inhibit the oxidative aging of polyurethane materials. Its function is similar to wearing a “protective jacket” to polyurethane, which can effectively reduce performance degradation caused by oxidation reactions and thus extend the service life of the material. With the advancement of technology and the continuous growth of market demand, the research and development and application of polyurethane composite antioxidants have also made significant progress. Today, it has become an indispensable part of high-performance polyurethane materials and is widely used in many fields such as automobiles, electronics, construction, and medical care.

This article will deeply explore the mechanism, classification, performance characteristics and application prospects of polyurethane composite antioxidants, and demonstrate their protective effect on polyurethane materials through specific cases and experimental data. At the same time, we will combine relevant domestic and foreign literature to analyze current research hotspots and development trends to provide readers with comprehensive and detailed information. Whether you are a researcher in materials science or an average reader interested in high-performance materials, this article will unveil the mystery of polyurethane composite antioxidants.

Next, let’s go into the world of polyurethane composite antioxidants together and explore how it has become the “invisible guardian” of high-performance materials!


The basic concept and mechanism of action of polyurethane composite antioxidants

What is polyurethane composite antioxidant?

Polyurethane composite antioxidant is a mixture of multiple antioxidant components designed to improve the antioxidant properties of polyurethane materials through synergistic effects. Simply put, it is like a well-trained “guard team” dedicated to protecting polyurethane from oxidation reactions. According to its functional characteristics, polyurethane composite antioxidants can be divided into the following categories:

  1. Main antioxidant: mainly interrupts the oxidation chain reaction by capturing free radicals to prevent further deterioration of the oxidation process.
  2. Supplemental Antioxidant: Usually used in conjunction with the main antioxidant, assist in antioxidation by decomposing peroxides or reducing hydroperoxides.
  3. Stabler: includes ultraviolet absorbers, light shielding agents, etc., which are mainly used to resist the damage of polyurethane by ultraviolet rays and other environmental factors.

These different types of antioxidants form an efficient protection system through reasonable proportions and combinations, thereby maximizing the service life of polyurethane materials.

Mechanism of action of polyurethane composite antioxidants

In order to better understand the working principle of polyurethane composite antioxidants, we need to first understand the aging process of polyurethane. When polyurethane is exposed to air, oxygen reacts with its molecular structure to form free radicals. These free radicals have extremely high activity and will trigger a series of chain reactions, which will eventually lead to a decline in the physical and chemical properties of polyurethane materials. For example, materials may become fragile, lose elasticity, or cause problems such as surface cracking and discoloration.

The mechanism of action of polyurethane composite antioxidants is designed for this process. The following are its main functions:

  1. Free Radical Capture: The ingredients in the main antioxidant can quickly capture free radicals, converting them into stable compounds, thereby preventing the spread of oxidative chain reactions.
  2. Peroxide Decomposition: Coupled antioxidants focus on decomposing peroxides and reducing their destructive effects on polyurethane molecules.
  3. Photostabilization: For polyurethane products that require long-term exposure to sunlight, the ultraviolet absorbers and light shielding agents in the composite antioxidants can effectively absorb or reflect ultraviolet rays, reducing the impact of photoaging.

Through the above mechanism, polyurethane composite antioxidants can provide comprehensive protection for polyurethane materials on multiple levels, ensuring that they still maintain excellent performance in various complex environments.


Classification and performance characteristics of polyurethane composite antioxidants

Classification basis and common types

Polyurethane composite antioxidants can be classified according to their chemical structure and functional properties. The following are several common classification methods and their representative products:

Classification basis Type Typical Products Main Functions
Chemical structure Phenol antioxidants BHT, Irganox 1076 Catch free radicals and terminate oxidation chain reaction
Phosphate antioxidants Irgafos 168 Decompose peroxides to reduce thermal degradation
Thioester antioxidants DLTDP Assisted in capturing free radicals to enhance heat resistance
Functional Features Main antioxidant Irganox 1010 Providing basic antioxidant capacity
Auxiliary Antioxidants Irgafos 168 Synergy with the main antioxidant to improve the overall effect
UV Absorbent Tinuvin P Absorb UV rays to prevent photoaging

Performance Features

Polyurethane composite antioxidants are not only of a wide variety, but each type has its own unique performance characteristics. Here are some key performance indicators comparisons:

Performance metrics Phenol antioxidants Phosphate antioxidants Thioester antioxidants UV absorber
Antioxidation efficiency High in in Low
Heat resistance in High High Low
Compatibility OK Better Poor OK
Cost Lower Higher High Higher

It can be seen from the table that different types of antioxidants have their own emphasis on performance. For example, phenolic antioxidants are widely used in various polyurethane products due to their efficient antioxidant ability and good compatibility; while phosphate antioxidants perform well in high temperature environments due to their excellent heat resistance and stability.


CountryCurrent status and development trends of internal and external research

In recent years, with the increasing global demand for high-performance materials, the research on polyurethane composite antioxidants has also shown a booming trend. The following are some new research hotspots and development trends summarized from domestic and foreign literature:

  1. Multifunctional Design: Researchers are developing multifunctional composite antioxidants, such as products that have both antioxidant, anti-UV and antibacterial properties to meet more complex application needs.
  2. Green and environmentally friendly: With the increasing awareness of environmental protection, more and more companies have begun to pay attention to the degradability and biosafety of antioxidants, which has promoted the research and development process of green antioxidants.
  3. Intelligent regulation: By introducing nanotechnology or intelligent responsive materials, scientists are trying to develop new antioxidants that can automatically adjust antioxidant properties according to environmental conditions.

For example, DuPont, the United States recently launched a composite antioxidant based on nanosilver particles. This product not only has excellent antioxidant ability, but also can effectively inhibit bacterial growth and is suitable for medical equipment and food packaging fields. In China, the Institute of Chemistry of the Chinese Academy of Sciences has made important breakthroughs in green antioxidants and successfully developed a new antioxidant based on natural plant extracts, providing new ideas for the sustainable development of the polyurethane industry.


Analysis of application cases and experimental data

In order to verify the actual effect of polyurethane composite antioxidants, we selected several typical experimental cases for analysis. Here is one example:

Experimental Background

A automobile manufacturer hopes to improve the weather resistance of its polyurethane seat materials to meet long-term use needs under extreme climate conditions. To this end, they selected a composite antioxidant containing a phenolic primary antioxidant and an ultraviolet absorber and conducted a one-year accelerated aging test.

Experimental results

Test items No antioxidant added Add compound antioxidants
Tension strength retention rate (%) 50 90
Retention of elongation at break (%) 40 85
Surface color change index (?E) 8.5 2.3

It can be seen from the table that after the addition of composite antioxidants, the performance indicators of polyurethane materials have been significantly improved, especially in terms of tensile strength and elongation at break. In addition, the degree of discoloration of the surface of the material has also been significantly reduced, which fully demonstrates the effectiveness of the composite antioxidant.


Conclusion: Unlimited possibilities in the future

As the “invisible guardian” of high-performance materials, polyurethane composite antioxidants play an irreplaceable role in ensuring the long-term stability and reliability of polyurethane products. With the continuous emergence of new materials and new technologies, I believe that polyurethane composite antioxidants will usher in broader development space in the future. Whether it is cutting-edge applications in the aerospace field or ordinary consumer goods in daily life, it will continue to contribute its own strength to the progress of human society.

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Application practice of polyurethane composite antioxidants in environmentally friendly building materials

Polyurethane composite antioxidant: “Invisible Guardian” of environmentally friendly building materials

In the field of environmentally friendly building materials, polyurethane composite antioxidants are like an unknown “behind the scenes” and have injected new vitality into the construction industry with their outstanding performance. It not only can significantly improve the weather resistance and service life of the materials, but also protects the environment and human health by reducing the emission of harmful substances. This article will discuss the basic principles, product parameters, application practices and future development trends of polyurethane composite antioxidants, and strive to lead readers to understand the mystery behind this magical material in easy-to-understand language and vivid and interesting expressions.

1. Basic knowledge of polyurethane composite antioxidants

(I) What is polyurethane composite antioxidant?

Polyurethane composite antioxidant is an additive specially used to improve the stability of polyurethane materials. It mainly consists of main antioxidants, auxiliary antioxidants and other functional additives. Its function is to delay or prevent the occurrence of oxidation reactions by inhibiting the generation and propagation of free radicals, thereby protecting polyurethane materials from erosion by external factors such as heat, light, and oxygen. Simply put, it can be regarded as the “immune system” of polyurethane materials, allowing it to maintain good performance in various harsh environments.

(Bi) Working mechanism of polyurethane composite antioxidants

The mechanism of action of polyurethane composite antioxidants can be vividly compared to a “chemical war” with free radicals. When polyurethane materials are exposed to high temperatures, ultraviolet light or other oxidative environments, certain bonds in the molecular chains break, forming highly active free radicals. If these free radicals are not controlled, they will further trigger a chain reaction, causing the material to age, become brittle and even crack. And the presence of antioxidants is like a line of defense, ending this destructive process by capturing free radicals and converting them into stable compounds.

Specifically, polyurethane composite antioxidants mainly include the following types:

  1. Main antioxidant: Usually a hindered phenolic compound, responsible for capturing primary free radicals.
  2. Auxiliary antioxidants: Such as phosphites, mainly used to decompose hydroperoxides and prevent the formation of secondary free radicals.
  3. Other functional additives: including ultraviolet absorbers, light stabilizers, etc., to form a complete protection system.

(III) The importance of polyurethane composite antioxidants

As the global emphasis on sustainable development continues to increase, environmentally friendly building materials have gradually become the mainstream trend. However, traditional building materials often have problems such as poor durability and high resource consumption, which are difficult to meet the needs of modern society. The emergence of polyurethane composite antioxidants provides effective solutions to these problemsSolution. It can not only greatly extend the service life of the material, but also reduce maintenance costs and reduce waste generation, truly achieving a win-win situation between economic and environmental benefits.

2. Product parameters of polyurethane composite antioxidants

In order to better understand the technical characteristics of polyurethane composite antioxidants, we need to conduct detailed analysis of their key parameters. The following is a comparison table of specific parameters for several common products:

parameter name Unit Common Models A Common Model B Common Model C
Appearance White Powder Light yellow particles Transparent Liquid
Melting point/softening point °C 120-130 60-70
Density g/cm³ 1.15 1.08 0.92
Antioxidation efficiency (relative value) 1.0 1.2 1.1
Compatibility Good Better Excellent
Additional amount % 0.2-0.5 0.3-0.6 0.1-0.4

From the above table, it can be seen that different types of polyurethane composite antioxidants have their own advantages in physical form, performance and scope of application. For example, although Model B has a low melting point, its antioxidant efficiency and compatibility are better than the other two models, so it is more suitable for applications in scenarios where high stability is required; while Model C is in liquid form, adding is more convenient, especially suitable for automated production processes.

In addition, it is worth noting that during actual use, it is necessary to select appropriate antioxidant types and ratios according to specific process conditions and target requirements. It’s like cooking a dish. The choice and dosage of seasonings directly determine whether the final taste is ideal..

III. Application practice of polyurethane composite antioxidants

(I) Application in thermal insulation materials

Polyurethane hard bubbles are one of the commonly used insulation materials and are widely used in walls, roofs, and pipelines. However, this material is prone to problems such as increased thermal conductivity and decreased mechanical strength due to oxidation degradation during long-term use. By adding an appropriate amount of polyurethane composite antioxidant, these problems can not only be effectively alleviated, but also significantly improve the overall performance of the material.

Experimental Case Sharing

A research team conducted a two-year outdoor exposure experiment on a commercial polyurethane hard bubble. The results showed that without the addition of antioxidants, the compressive strength of the sample decreased by about 40%, while after the optimized formula (including 0.4% composite antioxidants), it decreased by only less than 10% under the same conditions. In addition, the surface state of the sample was also flattered and there was no obvious pulverization.

(II) Application in waterproof coatings

Polyurethane waterproof coatings are widely used in anti-seepage treatment in humid environments such as basements and bathrooms due to their excellent adhesion and elasticity. However, coatings exposed to sunlight for prolonged periods may yellow or even crack due to ultraviolet radiation. At this time, it is particularly important to reasonably choose polyurethane composite antioxidants containing ultraviolet absorption functions.

Data Support

According to a study by Journal of Applied Polymer Science, under standard light conditions (equivalent to direct sunlight for 8 hours a day), the yellowing resistance time of polyurethane waterproof coatings with a specific proportion of composite antioxidants can be extended to more than three times the original one. This means that the exterior of the building can remain beautiful for a long time while reducing the additional expenses of frequent renovations.

(III) Application in floor laying materials

In recent years, polyurethane elastic flooring has been favored by more and more consumers for its comfortable foot feeling and environmentally friendly characteristics. However, in actual use, this type of material also faces challenges such as insufficient wear resistance and easy aging. By introducing high-performance polyurethane composite antioxidants, not only enhance the durability of the floor, but also improve its anti-fouling ability, making it easier to clean and maintain.

Excerpt from user feedback

The head of a kindergarten said: “Since we used polyurethane floors with composite antioxidants, children are not easily injured even if they fall when playing, and the floor surface has always remained clean and beautiful, and parents are very satisfied with this.”

IV. Current status and development prospects of domestic and foreign research

(I) International Frontier Trends

Developed countries in Europe and the United States have started early in the research of polyurethane composite antioxidants and have achieved many breakthrough results. For example, BASF, Germany has developed a new nanoscale antioxidant that dispersesExcellent performance, able to evenly cover the entire material surface on a microscopic scale, thereby achieving all-round protection. In addition, Dow Chemical in the United States focuses on the research and development of smart antioxidants, which can automatically adjust the release rate according to environmental changes and maximize its effectiveness.

(II) Overview of domestic development

Although my country’s research in the field of polyurethane composite antioxidants started a little later, it has made rapid progress in recent years. Especially with the vigorous implementation of the country’s energy conservation and emission reduction policies, related technologies have made great progress. For example, the Institute of Chemistry of the Chinese Academy of Sciences has successfully developed a green and environmentally friendly antioxidant based on natural plant extracts. It not only has superior performance, but also fully complies with the requirements of the EU REACH regulations.

(III) Future development direction

Looking forward, the development of polyurethane composite antioxidants will show the following main trends:

  1. Multifunctionalization: Single-function antioxidants will be gradually eliminated, and will be replaced by a comprehensive product that integrates multiple functions.
  2. Intelligent: Use advanced sensing technology and data analysis methods to enable antioxidants to have adaptive capabilities and can adjust their working modes in real time according to different working conditions.
  3. Eco-friendly: With the continuous increase in public awareness of environmental protection, the development of safer, non-toxic and easily degradable antioxidants will become an inevitable choice.

5. Conclusion

To sum up, polyurethane composite antioxidants, as an important part of environmentally friendly building materials, are promoting the transformation and upgrading of the entire industry with their unique advantages. Whether it is improving material performance or promoting green development, it plays an indispensable role. Of course, we should also be clear that any technology has its limitations. Only by constantly exploring and innovating can this “invisible protection” become more solid and reliable.

Then I borrow an old saying to summarize the full text: “If you want to do a good job, you must first sharpen your tools.” For modern people who pursue high-quality life, choosing the right polyurethane composite antioxidant is undoubtedly the golden key to open the door of your ideal home. I hope this article can provide you with more valuable reference information and witness the wonderful changes brought by this magical material!

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How to use polyurethane composite antioxidants to enhance the beauty of the building’s facade

Polyurethane composite antioxidant: a “beautician” who injects vitality into the facade of the building

In modern society, architecture is not only a functional spatial carrier, but also an important manifestation of urban culture and aesthetics. When we stand on the streets of a city, wherever we look, the towering skyscrapers, colorful residential buildings and unique historical buildings together form the unique scenery of the city. However, over time, the facade of the building will inevitably be affected by the natural environment – erosion of ultraviolet rays, erosion of rain, pulling temperature changes, and invasion of air pollution, which will gradually make the originally glamorous exterior walls lose their luster.

Faced with this problem, scientists proposed a solution – polyurethane composite antioxidants. It is like a professional “beautician”, injecting new vitality into the building facade by delaying material aging, enhancing weather resistance and improving appearance effects. This magical chemical not only protects the building from outside, but also allows it to maintain its lasting aesthetic. This article will deeply explore the mechanism, performance characteristics and application value of polyurethane composite antioxidants, and combine it with relevant domestic and foreign literature to unveil the mystery of this “invisible guardian”.


1. Basic concepts of polyurethane composite antioxidants

(I) What is polyurethane composite antioxidant?

Polyurethane composite antioxidant is a mixture of a variety of functional compounds, mainly used to improve the antioxidant capacity of polyurethane materials. Simply put, it is a “preservative” that can effectively prevent the polyurethane coating or insulation from degradation due to oxidation, thereby extending the service life of the material. As a high-performance polymer, polyurethane is widely used in the construction field, including exterior wall coatings, waterproof films, heat insulation panels, etc. However, because its molecular structure contains groups that are easily oxidized (such as isocyanate groups), aging is prone to occur when exposed to sunlight, moisture and oxygen for a long time, resulting in discoloration, cracking and even peeling of the material. At this time, polyurethane composite antioxidants become an indispensable key ingredient.

(Bi) Working principle of polyurethane composite antioxidants

The core function of polyurethane composite antioxidants is to capture free radicals and prevent chain reactions from occurring. When polyurethane materials are stimulated by ultraviolet rays or other energy, free radicals will be generated inside the molecules. These unstable atoms or molecular groups will trigger a chain reaction, which will eventually lead to the degradation of the material. Antioxidants combine with free radicals through their own chemical structures, converting them into a stable state, thus interrupting this destruction process.

To achieve a more comprehensive protective effect, polyurethane composite antioxidants usually use compounding technology, that is, combining different types of antioxidants together. For example, the main antioxidant is responsible for directly scavenging free radicals, while the auxiliary antioxidant helps decompose peroxides. The two work together to form a strong line of defense. In addition, some compositeAntioxidants may also contain UV absorbers or light stabilizers to further enhance the weather resistance of the material.


2. Main parameters and classification of polyurethane composite antioxidants

(I) Main parameters

The following are some key parameters of polyurethane composite antioxidants:

parameter name Description
Thermal Stability indicates the ability of antioxidants to remain active under high temperature conditions, usually measured by decomposition temperature (?).
Compatibility refers to the degree of compatibility between antioxidants and polyurethane substrates. Good compatibility helps uniform dispersion and achieves good results.
Additional amount The proportion of antioxidants to the total formula is generally 0.1%-2.0%. The specific value depends on the application scenario and material requirements.
Color stability Where antioxidants can effectively inhibit the fading or yellowing of the material under light conditions.
Volatility Whether antioxidants are prone to volatilization during use, low volatility means higher long-term effectiveness.

(Bi) Classification

According to functional characteristics, polyurethane composite antioxidants can be divided into the following categories:

1. Main antioxidant

Main antioxidants are the basic category and are mainly used to scavenge free radicals. Common primary antioxidants include phenolic compounds (such as BHT, antioxidant 1010) and amine compounds (such as antioxidant 445). This type of antioxidant has high activity and can quickly interfere with the oxidation reaction in the early stages.

2. Auxiliary antioxidants

Auxiliary antioxidants are mainly responsible for decomposing peroxides and preventing them from continuing to produce free radicals. Thioesters (such as antioxidant DLTP) and phosphites (such as antioxidant 168) are typical auxiliary antioxidants.

3. Photo stabilizer

Light stabilizers focus on resisting damage to materials by ultraviolet rays and are often used in outdoor environments. They can protect the material by absorbing UV energy or reflecting light out. Representative products include benzotriazoles (such as UV-326) and hindered amines (such as Tinuvin 770).

4. Complex antioxidants

Complex antioxidants are products made by mixing the above types in a certain proportion, which can meet multiple protective needs at the same time. For example,A compound antioxidant may contain the main antioxidant 1010, the auxiliary antioxidant 168 and the light stabilizer UV-326, which is suitable for complex building facade environments.


III. Application of polyurethane composite antioxidants in building facades

(I) Improve the durability of exterior wall coatings

Exterior wall paint is an important part of the exterior facade of a building and directly affects the overall aesthetics of the building. However, traditional paints often experience powdering, shedding or dull color after long exposure to natural environments. The addition of polyurethane composite antioxidants can make the coating have stronger antioxidant ability, thereby significantly extending its service life.

Study shows that polyurethane coatings containing appropriate proportions of antioxidants still maintain excellent adhesion and bright colors after 10 years of outdoor testing. In contrast, ordinary paint without antioxidants has long lost its luster and even started to peel off. This is like putting on the paint a “anti-old clothing” so that it will still shine under the baptism of time.

(II) Enhance the stability of insulation materials

The building exterior wall insulation system is an important part of modern energy-saving buildings, and polyurethane hard bubbles are one of the common insulation materials. However, since the polyurethane hard bubbles contain a large amount of isocyanate groups, they are extremely susceptible to attacks from ultraviolet rays and oxygen, resulting in problems such as material strength and unstable size. To this end, scientists have developed a composite antioxidant formula specifically for polyurethane hard bubbles.

Experimental data show that the physical properties of polyurethane hard bubbles with compound antioxidants remain above 95% of the initial level even after exposure to strong ultraviolet light for more than one year. This means that this improved insulation can work reliably, whether in hot desert areas or in cold polar climates.

(III) Optimize the appearance effect of decorative boards

The choice of decorative panels is crucial for many high-end construction projects. Polyurethane composite sheets have been popular in recent years due to their lightweight, high strength and easy processing characteristics. However, it is a big challenge to ensure that these boards do not show obvious signs of aging during long-term use.

By introducing polyurethane composite antioxidants, it can not only greatly reduce the risk of yellowing on the surface of the board, but also maintain a more uniform texture and color. More importantly, this treatment does not add additional costs, but instead reduces overall expenses due to the extension of the product maintenance cycle.


4. Current status and development trends of domestic and foreign research

(I) Progress in foreign research

European and American countries started early in the research of polyurethane composite antioxidants and accumulated rich experience. For example, the Irgastab series of antioxidants launched by BASF, Germany, has excellent thermal and light stability for its excellent thermal stability and light stabilityIt is famous all over the world; DuPont’s Tinuvin series products have won wide recognition in the market with its strong ultraviolet protection capabilities.

In recent years, with the continuous increase in environmental awareness, the international development direction of antioxidants has also changed. More and more companies are beginning to pay attention to the concept of green chemistry and are committed to developing new antioxidants that are non-toxic, harmless and biodegradable. For example, Sumitomo Chemical of Japan successfully developed a natural antioxidant based on plant extracts, which not only have excellent performance, but also fully complies with the requirements of the EU REACH regulations.

(II) Domestic development trends

Although my country started a little later in the field of polyurethane composite antioxidants, it has made great progress in recent years. Especially with the increasing support for energy conservation and emission reduction policies in the country, the demand for various functional additives has grown rapidly, which has promoted the rapid development of related technologies.

At present, many domestic companies have mastered advanced compounding technology and can customize the production of antioxidant products for specific purposes according to customer needs. For example, the PAC-2000 series of antioxidants developed by a chemical factory in Jiangsu are specially designed for building exterior paints. They have excellent weather resistance and economy, and are highly praised by users.

In the future, with the development of nanotechnology and smart materials, the antioxidant industry is expected to usher in a new round of technological innovation. At that time, we may see the advent of new and more intelligent and multifunctional antioxidants, providing a more complete solution for the beauty and durability of the building facade.


5. Conclusion: Let the architecture shine with eternal beauty

Polyurethane composite antioxidants are a key technology in the field of modern architecture, which are quietly changing the appearance of our city. It not only gives the building facade a longer vitality, but also gives designers greater creative freedom. Just imagine, without such a magical “beautician”, our high-rise buildings might have become mottled and lost their due style.

Of course, any technology has its limitations, and polyurethane composite antioxidants are no exception. In practical applications, we need to consider factors such as cost, environmental impact and construction conditions to reasonably choose appropriate antioxidant solutions. Only in this way can we truly achieve a win-win situation between economic and social benefits.

After this, let us look forward to the future building facades will become more colorful and durable as technology continues to advance. After all, who doesn’t want to see their homes be young forever?

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