Environmentally friendly polyurethane hardener ingredients

Environmentally friendly polyurethane hardeners are developed to meet the growing needs for environmental protection. This type of hardener can not only effectively improve the hardness and wear resistance of polyurethane materials, but also has the characteristics of low VOC (volatile organic compound) content, non-toxic, and harmless. The following is a detailed introduction to the ingredients of environmentally friendly polyurethane hardener.


Environmentally friendly polyurethane hardener ingredients

As environmental awareness continues to increase, all walks of life are seeking more environmentally friendly alternatives. In the polyurethane industry, the development and application of environmentally friendly hardeners has become an important trend. Environmentally friendly polyurethane hardeners not only improve product performance but also reduce environmental impact.

1. Ingredient introduction

Environmentally friendly polyurethane hardeners usually contain the following main ingredients:

  • Isocyanates: Isocyanates used in environmentally friendly hardeners are usually low-VOC types, such as low-odor HDI (hexamethylene diisocyanate) trimer or isophorone diisocyanate (IPDI) etc.
  • Polyols: The polyols used in environmentally friendly polyurethane hardeners are usually polyols prepared from bio-based or renewable resources, such as castor oil polyols, soybean oil polyols, etc.
  • Catalyst: Environmentally friendly catalysts, such as low-odor organotin catalysts or amine catalysts, can promote the cross-linking reaction between isocyanates and polyols.
  • Additives: Including antioxidants, light stabilizers, etc., used to improve the aging resistance and weather resistance of the product.
  • Fillers: Such as nano-silica, etc., used to improve the hardness and wear resistance of the material.

2. Basis for ingredient selection

  • Low VOC: Choosing low VOC ingredients can reduce the emission of harmful substances and reduce potential risks to human health.
  • Bio-based raw materials: Polyols produced from renewable resources can reduce dependence on petroleum resources and reduce carbon footprint.
  • Compatibility: All ingredients need to have good compatibility to ensure that the hardener and polyurethane base material can be evenly dispersed to form a stable system.
  • Reactivity: The ingredients should be reactive enough to cross-link with the polyurethane base to form a dense network structure.

3. Examples of specific ingredients

The following is an example of the specific ingredients of an environmentally friendly polyurethane hardener:

  • Isocyanate: HDI trimer, 100 parts
  • Polyol: Castor oil modified polyether polyol (hydroxyl value approximately 56 mg KOH/g), 50 parts
  • Catalyst: low-odor organotin catalyst, 0.5 parts
  • Antioxidant: Antioxidant 1010, 0.5 part
  • Light stabilizer: UV absorber UV-P, 1 part
  • Filler: Nanosilica, 5 parts

4. Functions and effects of ingredients

  • Isocyanate: Reacts with polyols to form a polyurethane network, improving the hardness and wear resistance of the material.
  • Polyol: Reacts with isocyanate to form polyurethane segments, which affects the performance of the product.
  • Catalyst: Accelerates the reaction process and ensures rapid curing.
  • Antioxidants: Prevent material aging and extend service life.
  • Light stabilizer: Improve the light resistance of the material and reduce degradation caused by ultraviolet radiation.
  • Fillers: Increase hardness and wear resistance while improving the material’s heat resistance and dimensional stability.

5. Application cases

  • Architectural coatings: Environmentally friendly polyurethane hardeners are used in architectural coatings to improve the hardness and weather resistance of the coating and extend the maintenance cycle of the building.
  • Furniture surface treatment: Adding environmentally friendly hardeners to the surface coating of furniture can improve surface hardness and reduce scratches during daily use.
  • Sports venues: Environmentally friendly polyurethane hardeners are used in the construction of sports venues such as runways, which can improve the wear resistance of the venue and extend its service life.

6. Notes

  • Storage conditions: Environmentally friendly polyurethane hardener should be stored in a cool, dry place away from direct sunlight.
  • Mixing Ratios: Mix hardener with other ingredients in recommended ratios to ensure performance.
  • Safe use: Although environmentally friendly hardeners reduce the use of harmful substances, you still need to take appropriate safety measures during use, such as wearing protective gloves and glasses.

7. Conclusion

Environmentally friendly polyurethane hardeners not only improve the performance of polyurethane materials but also reduce their impact on the environment by using low-VOC, bio-based and other environmentally friendly ingredients. With the advancement of technology and the tightening of environmental regulations, environmentally friendly polyurethane hardeners will be widely used in more fields in the future.


Please note that the above provides a general introduction. When using it specifically, it is recommended to refer to the relevant product manuals or consult professional technical personnel for more detailed technical support and suggestions.

Extended reading:

N-Ethylcyclohexylamine – Manufacturer of N,N-Dicyclohexylmethylamine and N,N-Dimethylcyclohexylamine – Shanghai Ohans Co., LTD

CAS 2273-43-0/monobutyltin oxide/Butyltin oxide – Manufacturer of N,N-Dicyclohexylmethylamine and N,N-Dimethylcyclohexylamine – Shanghai Ohans Co., LTD

T120 1185-81-5 di(dodecylthio) dibutyltin – Amine Catalysts (newtopchem.com)

DABCO 1027/foaming retarder – Amine Catalysts (newtopchem.com)

DBU – Amine Catalysts (newtopchem.com)

bismuth neodecanoate – morpholine

DMCHA – morpholine

amine catalyst Dabco 8154 – BDMAEE

2-ethylhexanoic-acid-potassium-CAS-3164-85-0-Dabco-K-15.pdf (bdmaee.net)

Dabco BL-11 catalyst CAS3033-62- 3 Evonik Germany – BDMAEE

Special hardener for polyurethane coatings

Special hardener for polyurethane coatings is a special hardener designed to improve the hardness, wear resistance, chemical resistance and other properties of polyurethane coatings additive. This type of hardener can not only improve the physical properties of the coating, but also maintain or enhance its original properties, such as gloss, adhesion and weather resistance. The following is a detailed introduction to special hardeners for polyurethane coatings.


Special hardener for polyurethane coatings

Polyurethane coatings are widely used in many industries due to their excellent performance, such as construction, automobiles, furniture, electronics and other fields. In order to further improve the performance of polyurethane coatings, especially in terms of hardness, special hardeners for polyurethane coatings have become an indispensable part.

1. Mechanism of action of hardener

Special hardeners for polyurethane coatings react with active ingredients in polyurethane coatings to form a denser cross-linked network, thereby improving the hardness and other physical properties of the coating. The addition of hardeners can make the paint surface harder, reduce damage caused by scratches and abrasions, and also improve its chemical resistance and weather resistance.

2. Classification of hardeners

Special hardeners for polyurethane coatings can be divided into several categories based on their chemical structure and functional properties:

  • Isocyanate hardener: This type of hardener contains multiple isocyanate groups, which can cross-link with the hydroxyl groups in polyurethane coatings to form a stronger coating film.
  • Epoxy resin hardener: Enhances the hardness and chemical resistance of the coating film by reacting the epoxy group with the hydroxyl or amine group.
  • Silane coupling agent: This type of hardener can improve the adhesion between the coating and the substrate, and can also increase the hardness of the coating film.
  • Other functional hardeners: Including certain special modifiers, such as polymers containing special functional groups, which can further improve the performance of the coating film.

3. Factors to consider when choosing a hardener

When choosing a suitable hardener for polyurethane coatings, you need to consider the following aspects:

  • Performance requirements: Depending on the application, there are different requirements for the performance of the coating, such as hardness, wear resistance, gloss, etc.
  • Reactivity: The hardener should have good reactivity and be able to react quickly with the active ingredients in the polyurethane coating.
  • Compatibility: Hardeners need to have good compatibility with other ingredients in the paint to avoid precipitation or delamination.
  • Environmental protection: Choose hardeners with low VOC (volatile organic compounds) content to comply with environmental regulations.

4. Application cases of hardener

  • Automobile coating: In automobile coating, the use of high-performance hardeners can significantly improve the hardness and scratch resistance of the body coating and extend the service life of the coating.
  • Architectural coatings: In building exterior wall coatings, the addition of hardeners can improve the weather resistance and pollution resistance of the coating and maintain the long-term beauty of the wall.
  • Furniture coatings: Polyurethane coatings for furniture can increase the hardness of the furniture surface by adding hardeners and reduce scratches and wear during daily use.

5. Common brand recommendations

  • Shuode: The polyurethane hardener provided by Shuode is known for its high performance and stability and is suitable for many types of polyurethane coatings.
  • Longying: Although the LYH-210 textile hardening resin launched by Longying is mainly used for textile post-processing, it is also suitable for polyurethane coatings that require increased hardness.
  • Dulux: Hardener products under the Dulux brand, such as DM-1 model, are suitable for hardening treatment on concrete surfaces and can also be used in polyurethane coatings to improve their hardness and wear resistance. sex.

6. Precautions for use

  • Mixing Ratios: Mix hardener and coating strictly according to the recommended ratios provided by the manufacturer to ensure performance.
  • Conditions of use: Pay attention to the use temperature and humidity conditions of the hardener to avoid affecting its performance.
  • Safety: Take appropriate safety measures during use, such as wearing protective gloves and glasses, and ensuring the work area is well ventilated.

7. Conclusion

Special hardeners for polyurethane coatings play an important role in improving coating performance. Through reasonable selection and use of hardeners, not only the hardness of the coating film can be improved, but also its wear resistance, chemical resistance and weather resistance can be enhanced to meet the needs of different application scenarios. In actual applications, the appropriate type of hardener should be selected according to specific needs and the manufacturer’s operating instructions should be strictly followed.


Please note that the above provides a general introduction to hardeners specifically designed for polyurethane coatings. When using it specifically, it is recommended to refer to the relevant product manuals or consult professional technical personnel for more detailed technical support and suggestions.

Extended reading:

N-Ethylcyclohexylamine – Manufacturer of N,N-Dicyclohexylmethylamine and N,N-Dimethylcyclohexylamine – Shanghai Ohans Co., LTD

CAS 2273-43-0/monobutyltin oxide/Butyltin oxide – Manufacturer of N,N-Dicyclohexylmethylamine and N,N-Dimethylcyclohexylamine – Shanghai Ohans Co., LTD

T120 1185-81-5 di(dodecylthio) dibutyltin – Amine Catalysts (newtopchem.com)

DABCO 1027/foaming retarder – Amine Catalysts (newtopchem.com)

DBU – Amine Catalysts (newtopchem.com)

bismuth neodecanoate – morpholine

DMCHA – morpholine

amine catalyst Dabco 8154 – BDMAEE

2-ethylhexanoic-acid-potassium-CAS-3164-85-0-Dabco-K-15.pdf (bdmaee.net)

Dabco BL-11 catalyst CAS3033-62- 3 Evonik Germany – BDMAEE

Treatment methods of tributyltin oxide and analysis of its impact on the environment

### Treatment methods of tributyltin oxide and analysis of its impact on the environment

#### Introduction

tributyltin oxide (TBT), as a common organometallic compound, is widely used in industry, agriculture and daily life. However, its negative impact on the environment, especially aquatic ecosystems, has attracted widespread concern. This article aims to explore the treatment methods of TBT and its impact on the environment.

#### 1. Basic information about tributyltin oxide

Tributyltin oxide (chemical formula: C12H27SnO) is a colorless or light yellow liquid. Due to its good solubility and chemical stability, it is used in coatings, plastic stabilizers, pesticides and antibacterial agents, etc. fields are applied. Understanding its basic properties is essential for subsequent processing and environmental assessment.

#### Treatment method of di- and tributyltin oxide

The main purpose of TBT treatment methods is to reduce its pollution to the environment, which specifically include but are not limited to the following:

1. **Physical Treatment**:
– **Adsorption method**: Use activated carbon or other porous materials to adsorb TBT in water, and then remove it through physical separation.
– **Precipitation method**: Add a suitable precipitant to make TBT form a water-insoluble precipitate, and then separate it through filtration and other methods.

2. **Chemical Treatment**:
– **Redox Method**: Change the chemical form of TBT by adding oxidizing or reducing agents to convert it into less toxic compounds.
– **Neutralization method**: For TBT released in an acidic or alkaline environment, its toxic effects can be reduced by adding appropriate alkali or acid for neutralization treatment.

3. **Biological Treatment**:
– **Microbial Degradation**: Utilize the ability of certain microorganisms (such as bacteria, fungi, etc.) to metabolize TBT and decompose it into harmless or low-harm substances.
– **Phytoremediation**: TBT in soil or water is absorbed by planting plants with strong tolerance, and is degraded or fixed through the metabolism of plants.

4. **Engineering processing**:
– **Closed cycle system**: Establish a closed cycle system during production and use to reduce TBT emissions and leakage.
– **Recycling**: Recycle waste containing TBT and put it back into the production process after purification.

#### 3. Impact of tributyltin oxide on the environment

TBT has caused significant impacts on the environment due to its bioaccumulation and ecotoxicity, mainly including:

1. **Bioaccumulative**: TBT is highly fat-soluble and easily accumulates through the food chain, posing a greater threat to top predators.
2. **Ecotoxicity**: TBT is highly toxic to aquatic organisms, especially causing serious interference to the reproductive systems of marine organisms such as shellfish, affecting the reproductive capacity and sexual differentiation of populations.
3. **Immune system suppression**: TBT can suppress the immune system of aquatic organisms and increase their susceptibility to diseases.
4. **Nervous system damage**: Exposure to high concentrations of TBT may also cause damage to the nervous system of aquatic organisms, affecting their behavior and survival ability.

#### 4. Environmental Impact Assessment and Control Strategy

In order to assess the impact of TBT on the environment and develop effective control strategies, a series of measures need to be taken:

1. **Environmental Monitoring**: Regularly monitor water bodies, sediments and biological samples to determine the presence level and distribution of TBT.
2. **Risk Assessment**: Establish a comprehensive risk assessment framework based on factors such as TBT’s exposure pathways, toxic effects, and ecosystem sensitivity.
3. **Legal supervision**: Pass legislation to restrict or prohibit the use of TBT in certain high-risk areas, such as antifouling paint and other products that may cause pollution to water bodies.
4. **Development of alternatives**: Actively develop safer and more environmentally friendly alternatives to reduce the demand for TBT.
5. **Environmental Remediation**: For polluted areas, physical, chemical or biological methods are used for environmental remediation.
6. **Public Education**: Raise the public’s understanding of harmful substances such as TBT and enhance environmental protection awareness.

#### 5. Case Study

Some countries and regions have taken actions to deal with the environmental pollution caused by TBT. For example:

– **International Cooperation**: The International Maritime Organization (IMO) regulates the use of TBT in ship antifouling paint.
– **Domestic Legislation**: Many countries and regions have passed legislation to restrict or prohibit the use of TBT in specific products.
– **Environmental Remediation Projects**: Implement targeted environmental remediation projects, such as river, lake and ocean cleanup plans.

#### 6. Conclusion

Tributyltin oxide, as a multifunctional organometallic compound, plays an important role in multiple industries. However, its negative impact on the environment cannot be ignored. Through scientific and reasonable treatment methods and strict environmental management measures, TBT’s pollution to the environment can be effectively reduced and the ecological balance protected. Future research directions will focus more on developing green alternatives and improving the efficiency of existing treatment technologies to achieve sustainable economic and environmental development.

#### 7. Outlook

With the advancement of science and technology and the increasing awareness of environmental protection in society, it is expected that the management of harmful substances such as TBT will become more stringent. At the same time, the research and development of new materials and processes will also provide more possibilities to reduce the use of TBT. Future research efforts will continue to focus on finding greener alternatives and…Improve existing treatment technologies to mitigate the long-term environmental impact of TBT.

Extended reading:

cyclohexylamine

Tetrachloroethylene Perchloroethylene CAS:127-18-4

NT CAT DMDEE

NT CAT PC-5

N-Methylmorpholine

4-Formylmorpholine

Toyocat TE tertiary amine catalyst Tosoh

Toyocat RX5 catalyst trimethylhydroxyethyl ethylenediamine Tosoh

NT CAT DMP-30

NT CAT DMEA