The use of dibutyltin dilaurate as an efficient catalyst in plastic products

Introduction

Dibutyltin dilaurate (DBTDL), as an efficient organometallic catalyst, is widely used in the production of plastic products. This article will discuss the specific application of DBTDL in the plastics industry and its mechanism of action, and analyze its advantages and disadvantages.

1. Basic properties of dibutyltin dilaurate

Dibutyltin dilaurate (DBTDL) is a commonly used organometallic catalyst with the following basic properties:

  • Chemical formula: C22H46O2Sn
  • Appearance: colorless to light yellow transparent liquid
  • Boiling point: approximately 210°C (under vacuum conditions)
  • Melting point: -45°C
  • Solubility: Soluble in most organic solvents

2. Application in plastic products

The application of dibutyltin dilaurate in the production of plastic products is mainly reflected in the following aspects:

  1. PVC Stabilizer
    • Soft PVC: In soft PVC products, DBTDL serves as an auxiliary heat stabilizer, which can improve the thermal stability and processing performance of PVC.
    • Rigid PVC: For rigid PVC products, DBTDL can also play a role in enhancing material performance, especially in situations where transparency is required.
  2. Catalyst
    • Polyurethane foam: In the production process of polyurethane foam, DBTDL acts as a catalyst to promote the reaction between isocyanate and polyol and accelerate foam curing.
    • Polyester resin: Used to catalyze the curing of unsaturated polyester resin to improve reaction rate and product quality.
  3. Modifier
    • Elastomer: Adding DBTDL to some elastomer materials can improve their elasticity and mechanical strength.

3. Mechanism of action

The reason why DBTDL can play an important role in plastic products is closely related to its unique chemical structure and catalytic activity:

  1. Catalytic Mechanism
    • Promote reaction: DBTDL reduces the reaction activation energy by interacting with the active groups in the reactants, thereby accelerating the reaction process.
    • Stabilized intermediates: The intermediates formed during the reaction can be stabilized by DBTDL to prevent side reactions.
  2. Thermal Stability
    • Improve heat resistance: DBTDL can react with unstable chlorine free radicals in PVC, reduce dehydrochlorination reaction, and improve the thermal stability of the material.
    • Delay aging: During long-term use, DBTDL can continue to play a role in delaying the aging process of materials.

4. Analysis of advantages and disadvantages

  1. Advantages
    • High efficiency: As a catalyst, DBTDL can exert significant catalytic effect at a lower concentration and improve production efficiency.
    • Versatility: In addition to its role as a catalyst, DBTDL can improve the thermal stability and mechanical properties of materials.
    • Wide range of application: Suitable for the production of a variety of plastic products, such as PVC, polyurethane foam, etc.
  2. Disadvantages
    • Environmental issues: DBTDL contains heavy metal tin, which may cause environmental pollution during its production, use and disposal.
    • Health risks: Long-term exposure to DBTDL may have adverse effects on human health, and necessary protective measures need to be taken.
    • Regulatory restrictions: With the tightening of environmental regulations, the use of DBTDL is subject to certain restrictions, especially in food contact materials.

5. Application case studies

  1. PVC Flooring
    • Case Background: A PVC flooring manufacturer used a heat stabilizer containing DBTDL in its production process.
    • Application effect: The addition of DBTDL significantly improves the thermal stability and service life of PVC flooring, allowing the product to gain a good reputation in the market.
    • Environmental protection: In order to reduce the impact on the environment, the company actively develops new environmentally friendly heat stabilizers and gradually reduces the proportion of DBTDL used.
  2. Polyurethane foam
    • Case Background: A polyurethane foam manufacturer introduced DBTDL as a catalyst in the production process.
    • Application effect: The addition of DBTDL greatly shortens the foam curing time and improves production efficiency.
    • Health and Safety: The company is aware of the potential health risks of DBTDL, strengthens safety protection measures in the workplace, and conducts regular health checks on workers.

6. Future development direction

With the growing demand for environmentally friendly materials, the future development trend of the plastics industry will be more inclined to develop and use more environmentally friendly and safer alternatives. This includes but is not limited to:

  1. Bio-based catalysts: Research and develop catalysts based on natural renewable resources to reduce environmental impact.
  2. Non-toxic or low-toxic catalysts: Explore a new generation of catalysts that do not contain heavy metals to improve material safety.
  3. Multifunctional composite materials: Composite technology integrates multiple functions into a single material to improve overall performance.
  4. Circular economy model: Promote the use of recyclable and degradable plastic products to reduce the burden of waste on the environment.

7. Conclusion

Dibutyltin dilaurate, as an efficient organometallic catalyst, plays an important role in the production of plastic products. However, its potential environmental and health risks cannot be ignored. Through technological innovation and strict regulatory management, the adverse effects of DBTDL on the environment and human health can be minimized while ensuring the development of the plastics industry. Future research and practice will pay more attention to sustainability and social responsibility, and promote the development of the plastics industry in a greener and healthier direction.


This article provides a study of the use of dibutyltin dilaurate in plastic products. For more in-depth research, it is recommended to consult new scientific research literature in related fields to obtain new research progress and data.

Extended reading:

cyclohexylamine

Tetrachloroethylene Perchloroethylene CAS:127-18-4

NT CAT DMDEE

NT CAT PC-5

N-Methylmorpholine

4-Formylmorpholine

Toyocat TE tertiary amine catalyst Tosoh

Toyocat RX5 catalyst trimethylhydroxyethyl ethylenediamine Tosoh

NT CAT DMP-30

NT CAT DMEA

How to properly store dibutyltin dilaurate to extend its service life

Introduction

Dibutyltin dilaurate (DBTDL), as an efficient catalyst, is widely used in many industrial fields. Correct storage methods are essential to maintain its performance and extend its service life. This article will introduce in detail the correct storage method of DBTDL and the scientific principles behind it.

1. Basic storage requirements

To ensure that the quality of DBTDL is not affected, the following are some basic storage requirements:

  1. Sealed storage

    • Use sealed containers to store DBTDL to avoid contact with moisture or other impurities in the air to prevent chemical changes.
  2. Cryogenic storage

    • Save DBTDL at a lower temperature as much as possible to reduce the speed of chemical reactions and extend its service life.
  3. Store away from light

    • Light may accelerate certain chemical reactions, so DBTDL should be stored in a cool place away from direct sunlight.
  4. Dry environment

    • Keep the storage environment dry to avoid the impact of high humidity on DBTDL.
  5. Keep away from fire

    • DBTDL is a flammable chemical and should be kept away from fire and heat sources to avoid accidents.
  6. Independent storage

    • It is best to store DBTDL separately and avoid mixing it with other chemicals to prevent cross-contamination.

2. Selection of storage environment

  1. Warehouse conditions

    • Choose a warehouse with good ventilation and moderate temperature for storage.
    • The temperature should be controlled within the room temperature range (about 15°C to 25°C) and avoid high or low temperature environments.
  2. Packaging materials

    • Use high-quality airtight containers, such as glass bottles or stainless steel buckets, and make sure the seals are intact.
    • Packaging materials should be compatible with DBTDL and should not react chemically.
  3. Stacking method

    • When stacking in the warehouse, ensure that there is enough space between containers to facilitate air circulation.
    • Avoid stacking too high to prevent tipping or breakage.

3. Precautions during storage

  1. Clear labels

    • Clearly label each storage container with information such as chemical name, batch number, production date, and expiration date.
  2. Regular inspection

    • Regularly check whether the temperature, humidity and other parameters of the storage environment meet the requirements.
    • Check container seals to ensure there are no leaks or damage.
  3. Record Management

    • Establish detailed entry and exit records to track the usage of each batch of DBTDL.
    • Record any abnormal situations and take timely measures to deal with them.
  4. Safety training

    • Conduct safety training for all personnel involved in the storage and use of DBTDL to ensure that they understand the correct operating procedures and emergency response methods.

4. Special requirements for long-term storage

  1. Regularly replace containers

    • During long-term storage, the tightness of the container should be checked at regular intervals and replaced with new sealed containers as necessary.
  2. Temperature control

    • For DBTDL that needs to be stored for a long time, you can consider placing it in a specially designed low-temperature warehouse or refrigeration equipment.
  3. Moisture-proof measures

    • When storing in a high-humidity environment, additional moisture-proof measures should be taken, such as using hygroscopic agents.
  4. Regular sampling inspection

    • For long-term storage of DBTDL, samples should be taken regularly for quality testing to ensure that its chemical properties have not changed.

5. Case Analysis

Suppose a chemical company encounters the following problems when storing DBTDL:

  • Leaking container: A minor crack in one of the containers due to improper handling.
  • Ambient temperature fluctuation: Seasonal changes in the area where the warehouse is located cause frequent changes in indoor temperature.
  • Chaos in inventory management: The lack of an effective inventory management system resulted in the failure to process some expired DBTDL in a timely manner.

To solve these problems, the company has taken the following measures:

  • Strengthen container management: Re-evaluate the sealing performance of all storage containers and replace problematic containers in a timely manner.
  • Optimize storage conditions: Install air conditioning systems to maintain constant temperature and humidity in the warehouse.
  • Improve the information system: Establish an electronic inventory management system to realize real-time monitoring of each batch of DBTDL.

6. Summary

Correct storage of dibutyltin dilaurate can not only ensure its stable performance, but also effectively extend its service life. By following the above storage requirements and making appropriate adjustments based on specific application scenarios, the value of DBTDL can be maximized. In the future, with science and technologyWith the advancement of technology and the improvement of environmental awareness, the storage and management of DBTDL will be more strict and scientific.

7. Outlook

With the continuous emergence of new materials and new technologies, the storage of chemicals will pay more attention to environmental protection and safety in the future. Enterprises should actively adopt advanced management concepts and technical means to improve the safety management level of chemicals and contribute to sustainable development.


This article provides comprehensive guidance on the correct storage of dibutyltin dilaurate. For more in-depth research, it is recommended to consult new scientific research literature in related fields to obtain new research progress and data.

Extended reading:

cyclohexylamine

Tetrachloroethylene Perchloroethylene CAS:127-18-4

NT CAT DMDEE

NT CAT PC-5

N-Methylmorpholine

4-Formylmorpholine

Toyocat TE tertiary amine catalyst Tosoh

Toyocat RX5 catalyst trimethylhydroxyethyl ethylenediamine Tosoh

NT CAT DMP-30

NT CAT DMEA

Optimization of dibutyltin dilaurate treatment process and its performance in elastomer materials

Optimization of dibutyltin dilaurate treatment process and its performance in elastomer materials

Introduction

Dibutyltin dilaurate (DBTDL), as an efficient catalyst and stabilizer, is widely used in the production of elastomer materials. This article will discuss the optimization method of DBTDL treatment process and its specific performance in elastomer materials, aiming to improve the performance and production efficiency of the material.

1. Treatment process optimization of dibutyltin dilaurate

  1. Raw material selection and pretreatment

    • High-purity raw materials: Select high-purity dibutyltin oxide and lauric acid as raw materials to ensure product purity and performance.
    • Pretreatment: Pretreatment of raw materials, such as drying, filtration, etc., to remove impurities and improve reaction efficiency.
  2. Optimization of reaction conditions

    • Temperature control: Strictly control the reaction temperature, usually within the range of 120-150°C, to ensure the smooth progress of the reaction.
    • Stirring speed: Maintain an appropriate stirring speed to ensure that the raw materials are fully mixed and improve reaction efficiency.
    • Reaction time: Adjust the reaction time according to the actual situation to ensure that the reaction is completed, usually 2-4 hours.
    • Pressure control: In a closed reaction system, control the appropriate reaction pressure to prevent the loss of volatile substances.
  3. Optimization of catalyst addition amount

    • Experimental design: Determine the amount of catalyst added through orthogonal experimental design. Usually, the amount of DBTDL added is between 0.1% and 1%.
    • Performance test: Determine the amount of elastomer added by testing the properties of elastomer materials at different amounts, such as tensile strength, elongation at break, etc.
  4. Post-processing and purification

    • Dehydration: The water produced during the reaction can be removed through a water separator to promote the reaction toward the product.
    • Refining: The product is further purified through methods such as distillation or extraction to remove residual raw materials and other impurities.
    • Drying: Dry the refined DBTDL in a vacuum drying oven to remove residual moisture and solvent.
    • Packaging: Seal and package the dried DBTDL to prevent it from contact with moisture in the air.

2. Performance of dibutyltin dilaurate in elastomer materials

  1. Improve vulcanization performance

    • Accelerate the vulcanization reaction: DBTDL can significantly accelerate the vulcanization reaction, shorten the vulcanization time, and improve production efficiency.
    • Increase the degree of vulcanization: DBTDL helps to increase the degree of vulcanization, form a more uniform vulcanization network structure, and improve the performance of the material.
  2. Improve physical and mechanical properties

    • Tensile strength: After adding DBTDL, the tensile strength of elastomer materials is significantly improved, usually by 10%-20%.
    • Elongation at break: The addition of DBTDL can increase the elongation at break of elastomer materials and enhance the flexibility and tear resistance of the material.
    • Hardness: An appropriate amount of DBTDL can adjust the hardness of elastomer materials to meet different application requirements.
  3. Improve thermal stability

    • Thermal Aging Performance: DBTDL can improve the thermal stability of elastomer materials and reduce performance degradation during thermal aging.
    • High temperature performance: Under high temperature conditions, DBTDL can maintain stable material performance and extend the service life of the material.
  4. Improve processing performance

    • Fluidity: DBTDL can improve the fluidity of elastomer materials and improve operability during processing.
    • Surface finish: After adding DBTDL, the surface finish of the elastomer material is improved and surface defects are reduced.

3. Experimental analysis and case studies

  1. Experimental Design

    • Raw material selection: Use high-purity dibutyltin oxide and lauric acid.
    • Reaction conditions: Set the reaction temperature to 130°C and the reaction time to 3 hours.
    • Catalyst addition amount: Test the DBTDL addition amount of 0.1%, 0.5% and 1.0% respectively.
    • Post-processing: Refining the product by distillation and vacuum drying.
  2. Experimental results

    • Purity Testing: HPLC test results show that the purity of DBTDL reaches 99.5%.
    • Moisture test: The Karl Fischer method test results show that the moisture content in the product is 0.1%.
    • Physical property testing: Appearance is colorless and transparent liquid, density is 1.02 g/cm³, viscosity is 150 mPa·s.
  3. Performance testing

    • Tensile strength: After adding 0.5% DBTDL, the tensile strength of the elastomer material increased by 15%.
    • Breaking elongationElongation: After adding 0.5% DBTDL, the elongation at break of the elastomer material increased by 20%.
    • Hardness: After adding 0.5% DBTDL, the hardness of the elastomer material is moderate to meet the application requirements.
    • Thermal stability: After adding 0.5% DBTDL, the thermal aging performance of the elastomer material is significantly improved, and the high temperature performance is stable.
  4. Application Cases

    • High-performance tires: A tire manufacturer uses elastomer materials with 0.5% DBTDL added in the production of high-performance tires. Test results show that the tire’s wear resistance and tear resistance are significantly improved, and its service life is extended.
    • Sealing materials: A sealing material manufacturer used elastomer materials with 0.5% DBTDL added in the production process. The test results show that the sealing performance and aging resistance of the sealing material are significantly improved, meeting customer needs.

4. Conclusion and outlook

Through the optimization of the treatment process of dibutyltin dilaurate and its application in elastomer materials, we have reached the following conclusions:

  1. Process Optimization: By optimizing raw material selection, reaction conditions, catalyst addition, post-treatment and other steps, the purity and performance of DBTDL can be significantly improved.
  2. Performance improvement: The application of DBTDL in elastomer materials can significantly improve the tensile strength, elongation at break, hardness and thermal stability of the material, and improve the processing performance of the material.
  3. Wide application: DBTDL has excellent application performance in high-performance tires, sealing materials and other fields, and has broad application prospects.

Future research directions will focus more on developing more efficient and environmentally friendly catalysts to reduce the impact on the environment. In addition, by further optimizing the usage conditions of DBTDL, such as addition amount, reaction temperature, etc., its application effect in elastomer materials can be further improved and provide technical support for the development of related industries.

5. Suggestions

  1. Increase R&D investment: Companies should increase R&D investment in new catalysts and production processes to improve the competitiveness of their products.
  2. Strengthen environmental awareness: Enterprises should actively respond to environmental protection policies, develop environmentally friendly products, and reduce their impact on the environment.
  3. Expand application fields: Enterprises should actively expand the application of DBTDL in other fields, such as medical care, construction, etc., to find new growth points.
  4. Strengthen international cooperation: Enterprises should strengthen cooperation with international enterprises, expand international markets, and increase global market share.

This article provides a detailed introduction to the optimization of the dibutyltin dilaurate treatment process and its application in elastomeric materials. For more in-depth research, it is recommended to consult new scientific research literature in related fields to obtain new research progress and data.

Extended reading:

cyclohexylamine

Tetrachloroethylene Perchloroethylene CAS:127-18-4

NT CAT DMDEE

NT CAT PC-5

N-Methylmorpholine

4-Formylmorpholine

Toyocat TE tertiary amine catalyst Tosoh

Toyocat RX5 catalyst trimethylhydroxyethyl ethylenediamine Tosoh

NT CAT DMP-30

NT CAT DMEA

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