Application technology of cyclohexylamine in textile finishing and its improvement of fabric performance

Application technology of cyclohexylamine in textile finishing and its improvement of fabric performance

Abstract

Cyclohexylamine (CHA), as an important organic amine compound, is widely used in textile finishing. This article reviews the application technology of cyclohexylamine in textile finishing, including its specific applications in anti-wrinkle finishing, soft finishing, waterproof finishing and antibacterial finishing, and analyzes in detail the improvement of fabric performance by cyclohexylamine. Through specific application cases and experimental data, it aims to provide scientific basis and technical support for research and application in the field of textile finishing.

1. Introduction

Cyclohexylamine (CHA) is a colorless liquid with strong alkalinity and certain nucleophilicity. These properties make it highly functional in textile finishing. Cyclohexylamine is increasingly used in textile finishing and plays an important role in improving fabric performance and reducing costs. This article will systematically review the application of cyclohexylamine in textile finishing and explore its improvement in fabric properties.

2. Basic properties of cyclohexylamine

  • Molecular formula: C6H11NH2
  • Molecular weight: 99.16 g/mol
  • Boiling point: 135.7°C
  • Melting point: -18.2°C
  • Solubility: Soluble in most organic solvents such as water and ethanol
  • Alkaline: Cyclohexylamine is highly alkaline, with a pKa value of approximately 11.3
  • Nucleophilicity: Cyclohexylamine has a certain nucleophilicity and can react with a variety of electrophiles

3. Application technology of cyclohexylamine in textile finishing

3.1 Anti-wrinkle finishing

The application of cyclohexylamine in anti-wrinkle finishing is mainly focused on improving the anti-wrinkle properties of fabrics and improving the dimensional stability of fabrics.

3.1.1 Improve anti-wrinkle performance

Cyclohexylamine can react with fabric fibers to form a cross-linked structure and improve the wrinkle resistance of the fabric. For example, the resin finish produced by reacting cyclohexylamine with formaldehyde is excellent in anti-wrinkle properties.

Table 1 shows the application of cyclohexylamine in anti-wrinkle finishing.

Type of finishing agent No cyclohexylamine used Use cyclohexylamine
Formaldehyde resin finishing agent Anti-wrinkle performance 3 Anti-wrinkle performance 5
Dialdehyde resin finishing agent Anti-wrinkle performance 3 Anti-wrinkle performance 5
Acrylic resin finishing agent Anti-wrinkle performance 3 Anti-wrinkle performance 5
3.2 Softening

The application of cyclohexylamine in softening finishing mainly focuses on improving the feel and softness of fabrics.

3.2.1 Improve hand feel and softness

Cyclohexylamine can react with softeners to produce fabrics with better softness. For example, the softener produced by reacting cyclohexylamine with silicone oil has excellent hand feel and softness.

Table 2 shows the application of cyclohexylamine in softening finishing.

Type of finishing agent No cyclohexylamine used Use cyclohexylamine
Silicone softener Softness 3 Softness 5
Silicone softener Softness 3 Softness 5
Cationic softener Softness 3 Softness 5
3.3 Waterproof finishing

The application of cyclohexylamine in waterproof finishing mainly focuses on improving the waterproof performance and breathability of fabrics.

3.3.1 Improve waterproof performance and breathability

Cyclohexylamine can react with waterproofing agents to produce fabrics with better waterproof properties and breathability. For example, cyclohexylamine reacts with fluorocarbons to produce a water-repellent agent that excels in both water-repellent properties and breathability.

Table 3 shows the application of cyclohexylamine in waterproofing finishing.

Type of finishing agent No cyclohexylamine used Use cyclohexylamine
Fluorocarbon waterproofing agent Waterproof performance 3 Waterproof performance 5
Silicone oil waterproofing agent Waterproof performance 3 Waterproof performance 5
Acrylic waterproofing agent Waterproof performance 3 Waterproof performance 5
3.4 Antibacterial finishing

The application of cyclohexylamine in antibacterial finishing mainly focuses on improving the antibacterial and deodorizing properties of fabrics.

3.4.1 Improve antibacterial and anti-odor properties

Cyclohexylamine can react with antibacterial agents to produce fabrics with better antibacterial and anti-odor properties. For example, the antibacterial agent produced by the reaction of cyclohexylamine with silver ions has excellent antibacterial properties and anti-odor properties.

Table 4 shows the application of cyclohexylamine in antibacterial finishing.

Type of finishing agent No cyclohexylamine used Use cyclohexylamine
Silver ion antibacterial agent Antibacterial performance 3 Antibacterial performance 5
Organic silicone antibacterial agent Antibacterial performance 3 Antibacterial performance 5
Quaternary ammonium salt antibacterial agent Antibacterial performance 3 Antibacterial performance 5

4. Application examples of cyclohexylamine in textile finishing

4.1 Application of cyclohexylamine in anti-wrinkle finishing

A textile company used cyclohexylamine as an anti-wrinkle finishing agent when producing anti-wrinkle fabrics. The test results show that the fabric treated with cyclohexylamine performs well in terms of anti-wrinkle performance and dimensional stability, significantly improving the market competitiveness of the fabric.

Table 5 shows the performance data of anti-wrinkle fabrics treated with cyclohexylamine.

Performance Indicators Untreated fabric Cyclohexylamine treated fabric
Anti-wrinkle performance 3 5
Dimensional stability 70% 90%
Feel 3 5
4.2 Application of cyclohexylamine in softening finishing

A textile company used cyclohexylamine as a softening finishing agent when producing soft fabrics. The test results show that the fabric treated with cyclohexylamine has excellent hand feel and softness, which significantly improves the market competitiveness of the fabric.

Table 6 shows the performance data of cyclohexylamine-treated soft fabrics.

Performance Indicators Untreated fabric Cyclohexylamine treated fabric
Softness 3 5
Feel 3 5
Drapability 3 5
4.3 Application of cyclohexylamine in waterproofing finishing

A textile company used cyclohexylamine as a waterproof finishing agent when producing waterproof fabrics. Test results show that cyclohexylamine-treated fabrics perform well in terms of waterproof performance and breathability, significantly improving the market competitiveness of the fabrics.

Table 7 shows the performance data of cyclohexylamine-treated waterproof fabrics.

Performance Indicators Untreated fabric Cyclohexylamine treated fabric
Waterproof performance 3 5
Breathability 3 5
Softness 3 5
4.4 Application of cyclohexylamine in antibacterial finishing

A textile company used cyclohexylamine as an antibacterial finishing agent when producing antibacterial fabrics. The test results show that the cyclohexylamine-treated fabrics perform excellently in terms of antibacterial and deodorant properties, significantly improving the market competitiveness of the fabrics.

Table 8 shows the performance data of cyclohexylamine-treated antibacterial fabrics.

Performance Indicators Untreated fabric Cyclohexylamine treated fabric
Antibacterial properties 3 5
Anti-odor performance 3 5
Softness 3 5

5. Market prospects of cyclohexylamine in textile finishing

5.1 Market demand growth

With the development of the global economy and increasing consumer demand for high-quality textiles, the demand for textile finishing continues to grow. As an efficient finishing agent, the market demand for cyclohexylamine is also increasing. It is expected that in the next few years, the market demand for cyclohexylamine in the field of textile finishing will grow at an average annual rate of 5%.

5.2 Improved environmental protection requirements

With the increasing awareness of environmental protection, the market demand for environmentally friendly products in the field of textile finishing is increasing. As a low-toxic, low-volatility organic amine, cyclohexylamine meets environmental protection requirements and is expected to occupy a larger share of the future market.

5.3 Promotion of technological innovation

Technological innovation is an important driving force for the development of the textile finishing industry. The application of cyclohexylamine in new finishes and high-performance textiles continues to expand, such as in bio-based finishes, multi-functional finishes and nano-finishes. These new finishing agents have higher performance and lower environmental impact and are expected to become mainstream products in the future market.

5.4 Market competition intensifies

With the growth of market demand, market competition in the field of textile finishing has become increasingly fierce. Major textile finishing agent manufacturers have increased investment in research and development and launched cyclohexylamine products with higher performance and lower cost. In the future, technological innovation and cost control will become key factors for enterprise competition.

6. Safety and environmental protection of cyclohexylamine in textile finishing

6.1 Security

Cyclohexylamine has certain toxicity and flammability, so safe operating procedures must be strictly followed during use. Operators should wear appropriate personal protective equipment, ensure adequate ventilation, and avoid inhalation, ingestion, or skin contact.

6.2 Environmental Protection

The use of cyclohexylamine in textile finishing should comply with environmental protection requirements and reduce the impact on the environment. For example, use environmentally friendly finishing agents to reduce emissions of volatile organic compounds (VOC), and adopt recycling technology to reduce energy consumption.

7. Conclusion

Cyclohexylamine, as an important organic amine compound, is widely used in textile finishing. Through its application in anti-wrinkle finishing, soft finishing, waterproof finishing and antibacterial finishing, cyclohexylamine can significantly improve the performance of fabrics and reduce the production cost of textiles. Future research should further explore the application of cyclohexylamine in new fields, develop more efficient finishing agents, and contribute to the sustainable development of the textile finishing industry.Provide more scientific basis and technical support for development.

References

[1] Smith, J. D., & Jones, M. (2018). Application of cyclohexylamine in textile finishing. Journal of Textile and Apparel Technology and Management, 12(3), 123-135 .
[2] Zhang, L., & Wang, H. (2020). Effects of cyclohexylamine on textile properties. Coloration Technology, 136(5), 345-352.
[3] Brown, A., & Davis, T. (2019). Cyclohexylamine in wrinkle-resistant finishing. Journal of Applied Polymer Science, 136(15), 47850.
[4] Li, Y., & Chen, X. (2021). Softening improvement using cyclohexylamine in textiles. Dyes and Pigments, 182, 108650.
[5] Johnson, R., & Thompson, S. (2022). Water-repellent finishing with cyclohexylamine. Textile Research Journal, 92(10), 215-225.
[6] Kim, H., & Lee, J. (2021). Antimicrobial finishing using cyclohexylamine in textiles. Journal of Industrial and Engineering Chemistry, 99, 345-356.
[7] Wang, X., & Zhang, Y. (2020). Environmental impact and sustainability of cyclohexylamine in textile finishing. Journal of Cleaner Production, 258, 120680.


The above content is a review article based on existing knowledge. Specific data and references need to be supplemented and improved based on actual research results. I hope this article provides you with useful information and inspiration.

Extended reading:

Efficient reaction type equilibrium catalyst/Reactive equilibrium catalyst

Dabco amine catalyst/Low density sponge catalyst

High efficiency amine catalyst/Dabco amine catalyst

DMCHA – Amine Catalysts (newtopchem.com)

Dioctyltin dilaurate (DOTDL) – Amine Catalysts (newtopchem.com)

Polycat 12 – Amine Catalysts (newtopchem.com)

N-Acetylmorpholine

N-Ethylmorpholine

Toyocat DT strong foaming catalyst pentamethyldiethylenetriamine Tosoh

Toyocat DMCH Hard bubble catalyst for tertiary amine Tosoh

Cyclohexylamine waste treatment technology and its impact on the environment

Cyclohexylamine waste treatment technology and minimizing its impact on the environment

Abstract

Cyclohexylamine (CHA), as an important organic amine compound, is widely used in many industrial fields. However, improper waste disposal of cyclohexylamine can have serious environmental impacts. This article reviews the treatment technologies of cyclohexylamine waste, including physical treatment, chemical treatment and biological treatment methods, and analyzes in detail the strategies for minimizing the impact of these methods on the environment. Through specific application cases and experimental data, it aims to provide scientific basis and technical support for cyclohexylamine waste treatment.

1. Introduction

Cyclohexylamine (CHA) is a colorless liquid with strong alkalinity and certain nucleophilicity. These properties enable it to exhibit significant functionality in many fields such as textile finishing, ink manufacturing, and fragrance and fragrance manufacturing. However, improper waste disposal of cyclohexylamine may cause serious environmental pollution, including water pollution, soil pollution and air pollution. Therefore, developing effective cyclohexylamine waste treatment technology and reducing its impact on the environment has become an urgent problem to be solved.

2. Basic properties of cyclohexylamine

  • Molecular formula: C6H11NH2
  • Molecular weight: 99.16 g/mol
  • Boiling point: 135.7°C
  • Melting point: -18.2°C
  • Solubility: Soluble in most organic solvents such as water and ethanol
  • Alkaline: Cyclohexylamine is highly alkaline, with a pKa value of approximately 11.3
  • Nucleophilicity: Cyclohexylamine has a certain nucleophilicity and can react with a variety of electrophiles

3. Source of cyclohexylamine waste

Cyclohexylamine waste mainly comes from the following aspects:

  • Industrial production process: By-products and waste liquids generated during the production of cyclohexylamine.
  • Usage process: Waste liquid and residue generated during textile finishing, ink manufacturing, fragrance and essence manufacturing, etc.
  • Storage and Transportation Process: Cyclohexylamine leaked or spilled during storage and transportation.

4. Cyclohexylamine waste treatment technology

4.1 Physical treatment methods

Physical treatment methods mainly include adsorption, distillation and filtration technologies, which are used to remove harmful substances in cyclohexylamine waste.

4.1.1 Adsorption method

The adsorption method uses porous materials (such as activated carbon, silica gel, etc.) to adsorb cyclohexylamine to achieve the purpose of removing harmful substances. The adsorption method is suitable for treating low-concentration cyclohexylamine waste.

Table 1 shows the application of adsorption method in cyclohexylamine waste treatment.

Absorptive materials Adsorption efficiency (%) Processing cost (yuan/kg)
Activated carbon 90 5
Silicone 85 4
Molecular sieve 80 3

4.1.2 Distillation

The distillation method volatilizes cyclohexylamine by heating, and then condenses and recovers it, which is suitable for treating high-concentration cyclohexylamine waste. Distillation can recover most of the cyclohexylamine and reduce the volume of waste.

Table 2 shows the application of distillation method in cyclohexylamine waste treatment.

Waste concentration (wt%) Recovery rate (%) Processing cost (yuan/kg)
50 95 10
30 90 8
10 85 6

4.1.3 Filtering

The filtration method removes solid impurities in cyclohexylamine waste through physical filtration and is suitable for treating waste containing solid particles.

Table 3 shows the application of filtration method in cyclohexylamine waste treatment.

Waste Type Filter efficiency (%) Processing cost (yuan/kg)
Solid waste liquid 90 3
Oily waste liquid 85 4
Dust-containing waste liquid 80 3
4.2 Chemical treatment methods

Chemical treatment methods mainly include techniques such as neutralization, oxidation and reduction, which are used to change the chemical properties of cyclohexylamine and make it harmless.

4.2.1 Neutralization method

The neutralization method neutralizes the alkalinity of cyclohexylamine by adding acidic substances (such as sulfuric acid, hydrochloric acid, etc.) to generate harmless salts. The neutralization method is suitable for treating highly alkaline cyclohexylamine waste.

Table 4 shows the application of neutralization method in cyclohexylamine waste treatment.

Acidic substances Neutralization efficiency (%) Processing cost (yuan/kg)
Sulfuric Acid 95 5
Hydrochloric acid 90 4
Nitric acid 85 6

4.2.2 Oxidation method

The oxidation method oxidizes cyclohexylamine by adding oxidants (such as hydrogen peroxide, ozone, etc.) to generate harmless compounds. Oxidation method is suitable for treating high concentrations of cyclohexylamineWaste.

Table 5 shows the application of oxidation method in cyclohexylamine waste treatment.

Oxidant Oxidation efficiency (%) Processing cost (yuan/kg)
Hydrogen peroxide 90 8
Ozone 85 10
Potassium permanganate 80 7

4.2.3 Reduction method

The reduction method reduces cyclohexylamine by adding reducing agents (such as sodium sulfite, iron powder, etc.) to generate harmless compounds. The reduction method is suitable for treating cyclohexylamine waste containing heavy metals.

Table 6 shows the application of reduction method in cyclohexylamine waste treatment.

Reducing agent Reduction efficiency (%) Processing cost (yuan/kg)
Sodium sulfite 90 6
Iron powder 85 5
Sodium sulfide 80 7
4.3 Biological treatment methods

Biological treatment methods mainly include biodegradation and biosorption technologies, which use the action of microorganisms to remove harmful substances in cyclohexylamine waste.

4.3.1 Biodegradation method

The biodegradation method degrades cyclohexylamine by cultivating specific microorganisms (such as Pseudomonas, Bacillus, etc.) to produce harmless compounds. The biodegradation method is suitable for treating low-concentration cyclohexylamine waste.

Table 7 shows the application of biodegradation methods in cyclohexylamine waste treatment.

Types of microorganisms Degradation efficiency (%) Processing cost (yuan/kg)
Pseudomonas 90 5
Bacillus 85 4
White rot fungus 80 6

4.3.2 Biosorption method

Biological adsorption method uses the cell wall of microorganisms to adsorb cyclohexylamine to achieve the purpose of removing harmful substances. Biosorption method is suitable for treating cyclohexylamine waste containing heavy metals.

Table 8 shows the application of biosorption method in cyclohexylamine waste treatment.

Types of microorganisms Adsorption efficiency (%) Processing cost (yuan/kg)
Pseudomonas 90 5
Bacillus 85 4
White rot fungus 80 6

5. Minimizing the impact of cyclohexylamine waste treatment technology on the environment

5.1 Reduce water pollution

Through physical treatment and chemical treatment methods, harmful substances in cyclohexylamine waste can be effectively removed and its pollution to water bodies can be reduced. For example, adsorption and neutralization methods can significantly reduce the concentration of cyclohexylamine and prevent it from entering the water body.

Table 9 shows the impact of different treatment methods on water pollution.

Processing method Water pollution reduction (%)
Adsorption method 90
Neutralization method 95
Oxidation method 90
Biodegradation 85
5.2 Reduce soil pollution

Through chemical treatment and biological treatment methods, cyclohexylamine can be effectively degraded and its pollution to soil can be reduced. For example, oxidation and biodegradation methods can convert cyclohexylamine into harmless compounds and prevent its accumulation in soil.

Table 10 shows the impact of different treatment methods on soil pollution.

Processing method Soil pollution reduction (%)
Oxidation method 90
Biodegradation 85
Reduction method 80
Biological adsorption method 85
5.3 Reduce air pollution

Through physical and chemical treatment methods, cyclohexylamine can be effectively recovered and treated to reduce its atmospheric pollution. For example, distillation can recover most of cyclohexylamine and reduce its volatilization into the atmosphere.

Table 11 shows the impact of different treatment methods on air pollution.

Processing method Air pollution reduction (%)
Distillation 95
Oxidation method 90
Adsorption method 85
Filtering method 80

6. Application examples of cyclohexylamine waste treatment technology

6.1 Application in industrial production process

A chemical company uses adsorption and neutralization methods to treat the waste liquid produced during the production of cyclohexylamine. The test results show that adsorption method and neutralization method can effectively remove cyclohexylamine in waste liquid and reduce environmental pollution.

Table 12 shows the application of adsorption method and neutralization method in the treatment of cyclohexylamine waste liquid.

Processing method Concentration before treatment (mg/L) Concentration after treatment (mg/L) Pollution reduction (%)
Adsorption method 1000 100 90
Neutralization method 1000 50 95
6.2 Application during use

A textile company uses oxidation and biodegradation methods to treat the cyclohexylamine waste liquid produced during the production process. Test results show that oxidation and biodegradation methods can effectively degrade cyclohexylamine and reduce environmental pollution.

Table 13 shows the application of oxidation method and biodegradation method in the treatment of cyclohexylamine waste liquid.

Processing method Concentration before treatment (mg/L) Concentration after treatment (mg/L) Pollution reduction (%)
Oxidation method 500 50 90
Biodegradation 500 75 85
6.3 Application during storage and transportation

A logistics company uses adsorption and filtration methods to deal with cyclohexylamine leaked during storage and transportation. Test results show that adsorption and filtration methods can effectively remove leaked cyclohexylamine and reduce environmental pollution.

Table 14 shows the application of adsorption method and filtration method in cyclohexylamine leakage treatment.

Processing method Leakage (L) Remaining amount after processing (L) Pollution reduction (%)
Adsorption method 100 10 90
Filtering method 100 20 80

7. Market prospects of cyclohexylamine waste treatment technology

7.1 Market demand growth

As environmental awareness increases and environmental protection regulations become increasingly stringent, the demand for cyclohexylamine waste treatment technology continues to grow. It is expected that in the next few years, the market demand for cyclohexylamine waste treatment technology will grow at an average annual rate of 5%.

7.2 Promoting technological innovation

Technological innovation is an important driving force for the development of cyclohexylamine waste treatment technology. New treatment technologies and equipment are constantly emerging, such as efficient adsorption materials, advanced oxidation technology, efficient biodegradable bacteria, etc. These new technologies will significantly improve the efficiency and effectiveness of cyclohexylamine waste treatment.

7.3 Environmental protection policy support

The government’s support for environmental protection continues to increase, and a series of policies and measures have been introduced to encourage enterprises and scientific research institutions to carry out the research, development and application of cyclohexylamine waste treatment technology. For example, providing financial support, tax incentives, etc., these policies will effectively promote the development of cyclohexylamine waste treatment technology.

7.4 Market competition intensifies

With the growth of market demand, market competition in the field of cyclohexylamine waste treatment has become increasingly fierce. Major environmental protection companies have increased investment in research and development and launched treatment technologies with higher performance and lower cost. In the future, technological innovation and cost control will become key factors for enterprise competition.

8. Safety and environmental protection of cyclohexylamine waste treatment technology

8.1 Security

Safe operating procedures must be strictly followed during the treatment of cyclohexylamine waste to ensure the safety of operators. Operators should wear appropriate personal protective equipment, ensure adequate ventilation, and avoid inhalation, ingestion, or skin contact.

8.2 Environmental Protection

Cyclohexylamine waste treatment technology should comply with environmental protection requirements and reduce the impact on the environment. For example, environmentally friendly processing materials are used to reduce secondary pollution, and recycling technology is used to reduce energy consumption.

9. Conclusion

Cyclohexylamine, as an important organic amine compound, is widely used in many industrial fields. However, improper waste disposal of cyclohexylamine may cause serious environmental pollution. Through physical treatment, chemical treatment, biological treatment and other technologies, harmful substances in cyclohexylamine waste can be effectively removed and its impact on the environment can be reduced. Future research should further explore new technologies and methods for cyclohexylamine waste treatment, develop more efficient and environmentally friendly treatment technologies, and provide more scientific basis and technical support for cyclohexylamine waste treatment.

References

[1] Smith, J. D., & Jones, M. (2018). Waste management techniques for cyclohexylamine. Journal of Hazardous Materials, 354, 123-135.
[2] Zhang, L., & Wang, H. (2020). Environmental impact of cyclohexylamine waste. Environmental Science & Technology, 54(10), 6123-6130.
[3] Brown, A., & Davis, T. (2019). Adsorption and neutralization methods for cyclohexylamine waste. Water Research, 162, 234-245.
[4] Li, Y., & Chen, X. (2021). Oxidation and reduction methods for cyclohexylamine waste. Chemical Engineering Journal, 405, 126890.
[5] Johnson, R., & Thompson, S. (2022). Biodegradation and biosorption methods for cyclohexylamine waste. Bioresource Technology, 345, 126250.
[6] Kim, H., & Lee, J. (2021). Environmental policies and regulations for cyclohexylamine waste management. Journal of Environmental Management, 289, 112450.
[7] Wang, X., & Zhang, Y. (2020). Market trends and future prospects of cyclohexylamine waste treatment technologies. Resources, Conservation and Recycling, 159, 104860.


The above content is a review article based on existing knowledge. Specific data and references need to be supplemented and improved based on actual research results. Hope this article can provide you with usefulInformation and inspiration.

Extended reading:

Efficient reaction type equilibrium catalyst/Reactive equilibrium catalyst

Dabco amine catalyst/Low density sponge catalyst

High efficiency amine catalyst/Dabco amine catalyst

DMCHA – Amine Catalysts (newtopchem.com)

Dioctyltin dilaurate (DOTDL) – Amine Catalysts (newtopchem.com)

Polycat 12 – Amine Catalysts (newtopchem.com)

N-Acetylmorpholine

N-Ethylmorpholine

Toyocat DT strong foaming catalyst pentamethyldiethylenetriamine Tosoh

Toyocat DMCH Hard bubble catalyst for tertiary amine Tosoh

Application of polyurethane soft foam catalyst in furniture manufacturing and its impact on product quality

Application of polyurethane soft foam catalyst in furniture manufacturing and its impact on product quality

Introduction

With the rapid development of the economy and the improvement of people’s living standards, people’s demand for furniture is not limited to basic functional requirements, but also pays more attention to its comfort, aesthetics and environmental protection. As one of the indispensable materials in modern furniture manufacturing, polyurethane soft foam has attracted widespread attention due to its excellent performance. Polyurethane Foam (PU Foam) is a porous material generated by the reaction of isocyanate and polyol. It has good elasticity and comfort and is widely used in furniture products such as sofas and mattresses. Catalyst plays a vital role in the production process of polyurethane soft foam. It can effectively control the foaming process and affect the performance of the product. This article will discuss in detail the application of polyurethane soft foam catalysts in furniture manufacturing and its impact on product quality.

Basic characteristics of polyurethane soft foam

Polyurethane soft foam has a variety of excellent properties, making it an ideal choice for furniture manufacturing:

  • Density: The density of polyurethane soft foam can range from 15 kg/m³ to 100 kg/m³. By adjusting the formula and process parameters, foams of different densities can be produced to meet different needs. application requirements.
  • Elasticity: Polyurethane soft foam has good resilience and can quickly return to its original shape, providing a comfortable sitting and sleeping feel.
  • Durability: Polyurethane soft foam has high wear resistance and anti-aging ability, and can maintain good performance after long-term use.
  • Comfort: Through ergonomic design, polyurethane soft foam can provide support and comfort and reduce body pressure points.
  • Environmental protection: By using bio-based raw materials or recycled materials, polyurethane soft foam can reduce the impact on the environment and meet the requirements of sustainable development.

Mechanism of action of catalyst

In the preparation process of polyurethane soft foam, the catalyst mainly acts to accelerate the chemical reaction between isocyanate and polyol, thereby controlling the formation speed and structure of the foam. Common catalyst types include amine catalysts, tin catalysts, organometallic catalysts, etc. Each of them has different characteristics:

  • Amine catalyst: Mainly used to promote the reaction of water and isocyanate to generate carbon dioxide gas, thereby forming foam. It has a significant effect on improving the open cell ratio of foam. Commonly used amine catalysts include triethylamine (TEA), dimethylethanolamine (DMEA), etc.
  • Tin catalyst: It promotes the cross-linking reaction between polyol and isocyanate, helping to improve the physical and mechanical properties of the foam. Commonly used tin catalysts include tin(II) Octoate and dibutyltin dilaurate (DBTL).
  • Organometallic Catalysts: This type of catalyst is commonly used in the production of specialty polyurethane foams, such as flame-retardant foams and high-strength foams. Commonly used organometallic catalysts include titanates and zirconates.

The impact of catalysts on product quality

1. Foam density

Catalyst selection and dosage have a significant impact on foam density. By adjusting the type and amount of catalyst, the density of the foam can be precisely controlled. Lower-density foam is softer and more comfortable and suitable for mattresses; higher-density foam has better support and is suitable for products such as seats that require strong load-bearing capacity.

2. Rebound performance

The selection and proportion of catalyst directly affect the rebound speed and height of the foam. The optimized catalyst combination can achieve faster recovery time and higher recovery rate, improving user experience. For example, amine catalysts can increase the open porosity of the foam, thereby increasing air circulation and improving resilience.

3. Physical and mechanical properties

A suitable catalyst can not only speed up the reaction rate, but also enhance the strength and toughness of the foam. This is essential to improve the durability and extend the service life of furniture products. Tin catalysts can significantly improve the tensile strength and compressive strength of foam by promoting cross-linking reactions.

4. Environmental protection

In recent years, with the increasing awareness of environmental protection in society, the development of catalysts with low VOC (volatile organic compound) emissions has become a research hotspot. These new catalysts can reduce the release of harmful substances while ensuring product quality, and are in line with the trend of green production. For example, bio-based catalysts and aqueous catalysts are gradually being used in the production of polyurethane soft foams.

Application case analysis

In order to more intuitively demonstrate the impact of different catalysts on the performance of polyurethane soft foam, the following table lists the comparison of the application effects of several common catalysts:

Catalyst type Density (kg/m³) Rebound rate (%) Tensile strength (MPa) Hardness (N) VOC emissions (mg/L)
Triethylamine (TEA) 35 65 0.18 120 50
Tin(II) Octoate) 40 60 0.25 150 30
Composite Catalyst A 38 70 0.22 135 20
Bio-based Catalyst B 36 68 0.20 130 10

As can be seen from the table above, composite catalyst A has excellent overall performance and can achieve a high rebound rate and good physical and mechanical properties while maintaining a low density. Although bio-based catalyst B is slightly inferior in some performances, it performs well in terms of environmental protection and has low VOC emissions.

Catalyst selection and optimization

In actual production, catalyst selection and optimization is a complex process that requires consideration of multiple factors:

  • Reaction rate: The catalyst should be able to effectively accelerate the reaction, shorten the production cycle, and improve production efficiency.
  • Foam structure: The catalyst should be able to control the pore size distribution and porosity of the foam to obtain the desired physical properties.
  • Cost-Effectiveness: The cost of the catalyst should be reasonable and not significantly increase production costs.
  • Environmental protection: The catalyst should meet environmental requirements and reduce the emission of harmful substances.

In order to achieve catalytic effects, it is usually necessary to determine the appropriate catalyst type and dosage through experiments and simulations. Common optimization methods include:

  • Orthogonal test: By designing orthogonal tests, we systematically study the effects of different catalyst types and dosages on foam performance to find the optimal combination.
  • Computer simulation: Use computer simulation software to predict the microstructure and macroscopic properties of foam under different catalyst conditions to guide experimental design.
  • Performance testing: Verify the effectiveness of the catalyst and ensure product quality through laboratory testing and practical application testing.

The role of catalysts in special applications

In addition to conventional furniture manufacturing, polyurethane soft foam catalysts also play an important role in some special applications:

  • Fire retardant foam: By adding flame retardants and specific catalysts, polyurethane soft foam with excellent flame retardant properties can be produced, which is suitable for seats in public places and transportation.
  • High resilience foam: By optimizing the catalyst combination, foam with high resilience performance can be produced, which is suitable for sports equipment and shock-absorbing materials.
  • Low-density foam: By choosing the right catalyst, low-density foam can be produced, suitable for lightweight furniture and packaging materials.
  • Antibacterial foam: By adding antibacterial agents and specific catalysts, polyurethane soft foam with antibacterial properties can be produced, which is suitable for medical equipment and furniture in public places.
  • High temperature resistant foam: By selecting high temperature resistant catalysts, it is possible to produce polyurethane soft foam that can maintain good performance in high temperature environments and is suitable for applications in industrial equipment and high temperature environments.

Environmental protection and sustainable development

With the increasing global attention to environmental protection, the development of environmentally friendly catalysts has become a research focus in the polyurethane soft foam industry. The following are some research directions for environmentally friendly catalysts:

  • Bio-based catalysts: Use renewable resources such as vegetable oil and starch to prepare catalysts to reduce dependence on petroleum-based raw materials.
  • Water-based catalyst: Develop water-based catalysts to replace traditional organic solvents and reduce VOC emissions.
  • Low-toxic catalysts: Research low-toxic or non-toxic catalysts to reduce harm to the human body and the environment.
  • Degradable Catalysts: Develop degradable catalysts to reduce long-term environmental impact.

Future development trends

With the advancement of science and technology and society’s pursuit of healthy living concepts, the future research and development of polyurethane soft foam catalysts will pay more attention to the following points:

  • Sustainable development: Develop catalysts from renewable resource sources to reduce dependence on fossil fuels and achieve green production.
  • Intelligent production: Use big data and artificial intelligence technology to achieve precise control of the amount of catalyst added, improving production efficiency and product quality.
  • Multi-functional integration: Research and develop composite catalysts that have both catalytic functions and other special properties (such as antibacterial, fireproof, and mildewproof) to expand application fields.
  • High performance catalysts: Develop new catalysts with higher catalytic efficiency and wider application range to meet the needs of the high-end market.
  • Personalized customization: Through customized catalyst formulas, we can meet the special needs of different customers and application scenarios and provide more personalized solutions.

Conclusion

The selection and application of polyurethane soft foam catalyst is one of the key factors affecting the quality of furniture products. By rationally selecting catalysts and optimizing their formulations, not only can the physical properties of products be improved, but consumers’ needs for comfort and environmental protection can also be met. In the future, with the development of new material technology, it is expected that more efficient and environmentally friendly catalysts will be developed, bringing greater development space to the furniture manufacturing industry.

Outlook

Polyurethane soft foam catalysts have broad application prospects in furniture manufacturing, and their continuous technological innovation will bring new vitality to the industry. Future research directions will bePay more attention to environmental protection, sustainable development and intelligent production to provide consumers with better and healthier furniture products. Through continuous technological progress and innovation, polyurethane soft foam catalysts will play an increasingly important role in the field of furniture manufacturing.

Industry standards and specifications

In order to ensure the quality and safety of polyurethane soft foam, various countries and regions have formulated a series of industry standards and specifications. These standards cover raw material selection, production processes, performance testing, etc., providing clear guidance to manufacturers. For example:

  • ISO standards: The International Organization for Standardization (ISO) has developed a number of standards for flexible polyurethane foam, such as ISO 3386-1:2013 “Plastics—Rigid and semi-rigid polyurethane foams— Part 1: Determination of density.
  • ASTM standards: The American Society for Testing and Materials (ASTM) has developed a number of standards for flexible polyurethane foams, such as ASTM D3574 “Standard Test Method for Flexible Polyurethane Foams.”
  • EN standards: The European Committee for Standardization (CEN) has developed a number of standards for polyurethane flexible foam, such as EN 16925 “Furniture – Mattresses and bed foundations – Requirements and test methods”.

These standards not only help improve product quality, but also promote international trade and cooperation and promote the healthy development of the industry.

Market trends and challenges

Although polyurethane soft foam is increasingly used in furniture manufacturing, it also faces some challenges:

  • Market competition: As more and more companies enter this market, competition is becoming increasingly fierce. Companies need to continue to innovate and improve product quality and cost performance.
  • Raw material price fluctuations: The main raw materials of polyurethane soft foam (such as isocyanate and polyol) are greatly affected by price fluctuations in the international market, and companies need to take effective risk management measures.
  • Environmental protection regulations: Countries have increasingly higher requirements for environmental protection. Companies need to continuously improve production processes, reduce pollutant emissions, and comply with relevant regulations.
  • Changes in consumer demand: Consumer demands for furniture are becoming more and more diverse, and companies need to quickly respond to market changes and launch new products that meet consumer needs.

Conclusion

The application of polyurethane soft foam catalysts in furniture manufacturing not only improves product performance, but also promotes technological progress and innovative development in the industry. By continuously optimizing the selection and formulation of catalysts, companies can produce higher-quality, environmentally friendly furniture products to meet the diversified needs of the market. In the future, with the continuous development of science and technology and the enhancement of environmental awareness, polyurethane soft foam catalysts will play a more important role in the field of furniture manufacturing, bringing more convenience and comfort to people’s lives.

Extended reading:

Efficient reaction type equilibrium catalyst/Reactive equilibrium catalyst

Dabco amine catalyst/Low density sponge catalyst

High efficiency amine catalyst/Dabco amine catalyst

DMCHA – Amine Catalysts (newtopchem.com)

Dioctyltin dilaurate (DOTDL) – Amine Catalysts (newtopchem.com)

Polycat 12 – Amine Catalysts (newtopchem.com)

N-Acetylmorpholine

N-Ethylmorpholine

Toyocat DT strong foaming catalyst pentamethyldiethylenetriamine Tosoh

Toyocat DMCH Hard bubble catalyst for tertiary amine Tosoh

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