Physical and chemical properties of butyltin mercaptide

Butylmercaptostannane is an organotin compound with a chemical formula of C4H10OSSn and a CAS number of 26410-42-4. As an important class of organometallic compounds, butyltin mercaptide plays an important role in the chemical and industrial fields, especially in the application of polyvinyl chloride (PVC) stabilizers.

Physical properties

  • Appearance and status: Tin butyl mercaptide usually appears as a colorless and transparent liquid, which is clear and free of impurities in its pure state.
  • Density: Its density is approximately 1.13 g/cm³, measured at room temperature (20°C).
  • Refractive index: At the same room temperature, the refractive index of butyltin mercaptide is approximately 1.580.
  • Melting point and boiling point: The specific values ??are not clearly stated in public information, but since it is in a liquid state at room temperature, it can be speculated that its melting point is lower than room temperature and its boiling point is higher than the normal use temperature.
  • Solubility: Butyltin mercaptide has good solubility in most organic solvents, such as dichloromethane, tetrahydrofuran, etc., but its solubility in water is limited.

Chemical properties

  • Thermal stability: Butyltin mercaptide has high thermal stability and can function under high temperature conditions of PVC processing, effectively inhibiting the thermal degradation of PVC.
  • Redox properties: Organotin compounds containing thiol groups (-SH) often show certain reducing properties and can react with oxidants.
  • Coordination ability: The thiol group in butyltin mercaptide can be used as a ligand to form a complex with metal ions, which is also one of its important mechanisms as a PVC stabilizer.
  • Reactivity: Reacts with unstable chlorine atoms in PVC to prevent dehydrochlorination reaction, thereby improving the thermal stability and processing performance of PVC.
  • Odor: Butyltin mercaptide may have a distinctive odor related to its thiol group, but its odor is generally considered to be milder than that of other sulfur-containing compounds.

Safety and environmental considerations

  • Toxicity: Organotin compounds usually have some toxicity, and butyltin mercaptide is no exception. Prolonged or heavy exposure may cause adverse effects on human health, especially on the nervous and reproductive systems.
  • Environmental Impact: Organotin compounds degrade slowly in the natural environment and may cause harm to aquatic life. Therefore, strict environmental protection regulations should be followed when using and handling products containing butyltin mercaptide.

Precautions for use

Due to its potential health and environmental risks, the use of tin butylmercaptide requires strict compliance with safety guidelines. In industrial production, operators should wear appropriate personal protective equipment such as gloves, protective glasses and respiratory masks to reduce the risk of direct contact and inhalation. In addition, discarded butyltin mercaptide and the products it contains should be disposed of in accordance with hazardous waste treatment standards to avoid environmental pollution.

Conclusion

Butyltin mercaptide, as a member of organotin stabilizers, plays an indispensable role in PVC processing with its unique physical and chemical properties. missing role. However, its use also comes with safety and environmental considerations, and appropriate precautions need to be taken to ensure user safety and environmental sustainability.

Extended reading:

CAS:2212-32-0 – Manufacturer of N,N-Dicyclohexylmethylamine and N,N-Dimethylcyclohexylamine – Shanghai Ohans Co., LTD

N,N-Dicyclohexylmethylamine – Manufacturer of N,N-Dicyclohexylmethylamine and N,N-Dimethylcyclohexylamine – Shanghai Ohans Co ., LTD

bismuth neodecanoate/CAS 251-964-6 – Amine Catalysts (newtopchem.com)

stannous neodecanoate catalysts – Amine Catalysts (newtopchem.com)

polyurethane tertiary amine catalyst/Dabco 2039 catalyst – Amine Catalysts (newtopchem.com)

DMCHA – morpholine

N-Methylmorpholine – morpholine

Polycat 41 catalyst CAS10294-43-5 Evonik Germany – BDMAEE

Polycat DBU catalyst CAS6674-22-2 Evonik Germany – BDMAEE

The role and advantages of butyltin mercaptide as a PVC stabilizer

Butylmercaptostannane, an organotin compound, is used in polyvinyl chloride due to its excellent thermal stability and transparency. (PVC) processing plays a vital role. As a widely used thermoplastic, PVC is widely used in many industries such as construction, packaging, wires and cables due to its excellent mechanical properties and processing properties. However, PVC is susceptible to degradation due to heat and light during processing and use, resulting in performance deterioration. Therefore, adding effective stabilizers has become the key to improving the quality of PVC and extending its service life.

Stabilization mechanism of butyltin mercaptide

Butyltin mercaptide is an efficient PVC stabilizer. Its mechanism of action is mainly reflected in the following aspects:

  1. Inhibit dehydrochlorination reaction: PVC is prone to dehydrochlorination reaction at high temperatures, leading to molecular chain breakage and degradation. Butyltin mercaptide can capture free radicals and interrupt this chain reaction, thereby protecting the PVC molecular chain from damage.
  2. Eliminate unstable chlorine atoms: Unstable chlorine atoms on the PVC molecular chain are “hot spots” that trigger degradation. Butyltin mercaptide is able to react with these unstable chlorine atoms, converting them into a more stable structure, reducing the chance of chain breakage.
  3. Chelation: The thiol group in butyltin mercaptide can form a chelate with the metal ions on the PVC molecular chain, reducing the catalytic effect of the metal ions and further inhibiting the degradation reaction. .
  4. Antioxidant effect: Butyltin mercaptide can also provide antioxidant protection to prevent PVC from aging due to oxidation during processing and use.

Advantages of butyltin mercaptide

Compared with traditional lead salt or calcium zinc stabilizers, butyltin mercaptide shows the following advantages in PVC stabilizers:

  1. Thermal Stability: Butyltin mercaptide has excellent thermal stability and can provide lasting protection under the high temperature conditions of PVC processing, ensuring the processing performance and product quality of PVC products.
  2. Transparency: For transparent or translucent PVC products, tin butyl mercaptide can provide excellent transparency and will not cause fogging or discoloration like some metal soap stabilizers. .
  3. Compatibility: Tin butyl mercaptide has good compatibility with PVC and is easy to disperse in the PVC complex without affecting the surface properties and electrical properties of the product.
  4. Fluidity: Compared with other organotin stabilizers, butyltin mercaptide has better fluidity, which is beneficial to the flow of materials during PVC processing and improves processing efficiency.
  5. Synergistic effect: Tin butyl mercaptide can work synergistically with other stabilizers such as antioxidants and light stabilizers to jointly improve the overall performance of PVC.

Application cases

In rigid PVC products, such as pipes, profiles and plates, butyltin mercaptide is used as the main stabilizer or co-stabilizer, which can Significantly improves the thermal and color stability of products, especially under long-term outdoor use conditions. In addition, in soft PVC, such as films and cable insulation materials, butyltin mercaptide can also exert its excellent stabilizing effect and extend product life.

Conclusion

As a PVC stabilizer, butyltin mercaptide provides comprehensive protection for PVC products with its unique chemical structure and stabilizing mechanism, making it perform well in a wide range of industrial applications. However, considering the environmental and health effects of organotin compounds, the industry is also constantly exploring more environmentally friendly alternatives, such as calcium-zinc composite stabilizers, in order to reduce the burden on the environment while maintaining product performance.

Extended reading:

CAS:2212-32-0 – Manufacturer of N,N-Dicyclohexylmethylamine and N,N-Dimethylcyclohexylamine – Shanghai Ohans Co., LTD

N,N-Dicyclohexylmethylamine – Manufacturer of N,N-Dicyclohexylmethylamine and N,N-Dimethylcyclohexylamine – Shanghai Ohans Co ., LTD

bismuth neodecanoate/CAS 251-964-6 – Amine Catalysts (newtopchem.com)

stannous neodecanoate catalysts – Amine Catalysts (newtopchem.com)

polyurethane tertiary amine catalyst/Dabco 2039 catalyst – Amine Catalysts (newtopchem.com)

DMCHA – morpholine

N-Methylmorpholine – morpholine

Polycat 41 catalyst CAS10294-43-5 Evonik Germany – BDMAEE

Polycat DBU catalyst CAS6674-22-2 Evonik Germany – BDMAEE

Environmentally friendly substitute for dioctyltin oxide

Di-n-octyltin oxide (DOTO) is widely used in polyurethane, polycarbonate and other materials due to its efficient catalytic properties. It is widely used in the field of organic synthesis. However, in recent years, the international use of dioctyltin oxide has been increasingly restricted due to its potential bioaccumulation and potential toxicity to the environment and human health, especially its effects on the reproductive system. The EU REACH regulations and other international standards have set strict restrictions on its use. Therefore, finding environmentally friendly alternatives to dioctyltin oxide has become an urgent need in the industry.

Criteria for selecting alternatives

Ideal environmentally friendly alternatives should have the following properties:

  • Efficient catalytic activity: It can effectively catalyze related chemical reactions to ensure production efficiency.
  • Low-toxic or non-toxic: Little impact on human health and the ecological environment.
  • Biodegradability: Ability to break down in the natural environment, reducing long-term cumulative risks.
  • Cost-effectiveness: Compared with dioctyltin oxide, it has equivalent or better economic benefits.
  • Stability: Remains stable during storage and use and is not prone to deterioration.

Examples of environmentally friendly alternatives

1. Organobismuth compounds

Organobismuth compounds (such as tributylbismuth oxide) as catalysts have been considered as effective alternatives to dioctyltin oxide due to their low bioaccumulation potential and relatively low toxicity. They show good catalytic activity in the synthesis of polyurethanes and polycarbonates, and in some applications the catalytic efficiency is even higher than that of dioctyltin oxide.

2. Zinc Compounds

Zinc compounds, such as zinc acetate, are also being explored as environmentally friendly catalysts. Although their catalytic efficiency may be slightly lower than that of dioctyltin oxide, zinc compounds can still meet the needs of industrial production by optimizing reaction conditions and catalyst formulations.

3. Titanate Catalyst

Titanate catalysts, such as titanium tetrabutoxide, have high catalytic activity and good thermal stability. They have proven effective in the manufacture of polyurethane foam while reducing negative environmental impact.

4. Organic Amine Catalyst

Organic amine catalysts, such as dimethylcyclohexylamine, have gradually become alternatives to dioctyltin oxide due to their high selectivity and environmental friendliness. They can effectively promote the reaction between isocyanates and polyols in polyurethane synthesis and have less impact on the environment.

5. Solid Acid Catalyst

Solid acid catalysts, such as zeolites, silica-supported metal oxides, are being developed for various organic synthesis reactions, including the synthesis of polyurethanes, due to their high catalytic activity, recyclability, and environmental compatibility.

Research and Development

Although several environmentally friendly alternatives have been discovered and are beginning to be used in industry, the search for more efficient and environmentally friendly catalysts remains an active area of ??research. Advances in new materials science and green chemistry are expected to bring about new breakthroughs. For example, new catalysts prepared through nanotechnology or biocatalysts developed through bioengineering methods may become alternatives to dioctyltin oxide in the future.

Conclusion

With the increasing global awareness of environmental protection, research on alternatives to dioctyltin oxide has become an important topic in the fields of chemistry and materials science. Organic bismuth compounds, zinc compounds, titanate catalysts, organic amine catalysts and solid acid catalysts are currently relatively mature environmentally friendly alternatives. In the future, as scientific researchers continue to explore new catalysts, we are expected to see more efficient and environmentally friendly catalysts used in industrial production, contributing to the promotion of green chemistry and sustainable development. Continuous innovation in this field not only helps reduce pressure on the environment, but also promotes the transformation of the chemical industry into a more environmentally friendly and healthy direction.

Extended reading:

CAS:2212-32-0 – Manufacturer of N,N-Dicyclohexylmethylamine and N,N-Dimethylcyclohexylamine – Shanghai Ohans Co., LTD

N,N-Dicyclohexylmethylamine – Manufacturer of N,N-Dicyclohexylmethylamine and N,N-Dimethylcyclohexylamine – Shanghai Ohans Co ., LTD

bismuth neodecanoate/CAS 251-964-6 – Amine Catalysts (newtopchem.com)

stannous neodecanoate catalysts – Amine Catalysts (newtopchem.com)

polyurethane tertiary amine catalyst/Dabco 2039 catalyst – Amine Catalysts (newtopchem.com)

DMCHA – morpholine

N-Methylmorpholine – morpholine

Polycat 41 catalyst CAS10294-43-5 Evonik Germany – BDMAEE

Polycat DBU catalyst CAS6674-22-2 Evonik Germany – BDMAEE