Discuss the stability and durability of TPU yellowing agent under extreme conditions

TPU yellowing agent: An exploration of stability and durability under extreme conditions

Preface: TPU’s “appearance” defense battle

Thermoplastic polyurethane (TPU) is a polymer material with excellent performance and is widely used in shoe materials, films, wire and cable sheaths, and medical equipment. However, TPU is prone to yellowing due to environmental factors such as light, heat, and oxygen during long-term use. This “appearance crisis” not only affects the appearance, but also may reduce the physical properties of the material. To cope with this problem, scientists have developed TPU yellowing agents, which can effectively delay or prevent the yellowing process of TPU materials, thereby maintaining their aesthetics and functionality.

But the question is, how does yellowing agents perform under extreme conditions? Can it maintain stability and durability in harsh environments such as high temperature, high humidity, and strong ultraviolet radiation? This article will deeply explore the chemical principles, product parameters, and current research status of TPU yellowing agents, and reveal its performance under extreme conditions through experimental data and literature analysis. We will also help readers better understand this complex scientific topic with easy-to-understand language and humorous metaphors.

Next, let’s go into the world of TPU yellowing agent and see how it has become the “preserver of appearance” of TPU materials!


What is TPU yellowing agent?

Definition and mechanism of action

TPU yellowing agent is an additive specially designed to prevent yellowing of TPU materials. Its main function is to protect the material from external factors such as light, heat, and oxygen by inhibiting or slowing down the oxidation reaction in the TPU molecular chain. Simply put, it is like putting a “sun protection jacket” on the TPU so that it will not turn yellow even if it is exposed to the sun for a long time.

From a chemical point of view, TPU yellowing agents usually include the following categories:

  1. Ultraviolet absorber: This type of substance can absorb ultraviolet energy and convert it into harmless heat and release it, thereby avoiding the damage of ultraviolet rays to the TPU molecular chain.
  2. Antioxidants: They cut off the oxidation reaction chain by capturing free radicals and reducing the occurrence of yellowing.
  3. Light stabilizer: This type of substance can effectively inhibit the degradation reaction caused by light and further enhance the aging resistance of TPU.

These components work together to provide all-round protection for the TPU.


The working principle of yellowing agent

Imagine that the TPU molecular chain is like delicate strings, while light, heat, oxygenIt is the invisible fingers that constantly pluck these strings to create discordant notes – this is the source of the yellowing phenomenon. The effect of the yellowing agent is like a professional tuner who adjusts the state of the strings at any time to ensure that they always make a pleasant sound.

Specifically, the working principle of yellowing agent can be divided into the following steps:

  1. Capture free radicals: Antioxidants preferentially bind to free radicals to form stable compounds, thus preventing the free radicals from continuing to attack the TPU molecular chain.
  2. Absorbing UV rays: UV absorbers can convert the energy of ultraviolet rays into heat energy to release them, avoiding their direct effect on TPU molecules.
  3. Decomposition of peroxides: Some yellowing agents can also decompose peroxides formed in TPU molecules, further reducing the possibility of oxidation reactions.

Through these mechanisms, the yellowing agent successfully delays the aging process of TPU materials, allowing them to maintain good appearance and performance in various environments.


Challenges under extreme conditions

What are extreme conditions?

The so-called extreme conditions refer to environmental factors beyond the normal range, such as:

  • High temperature (>100?)
  • High humidity (>90% relative humidity)
  • Strong UV radiation (such as desert or plateau areas)
  • Chemical corrosion (acid-base environment)

Under these conditions, TPU materials face greater yellowing risks, and the performance of yellowing agents is also severely tested.


Status of domestic and foreign research

Domestic research progress

In recent years, domestic scholars have made significant progress in research on TPU yelitising agents. For example, a research team developed a new composite yellowing agent, which consists of ultraviolet absorbers and antioxidants, with excellent synergistic effects. The experimental results show that after adding this yellowing agent, the yellowing index of TPU material under simulated sun exposure (500 hours) was reduced by more than 70%.

In addition, another study shows that by optimizing the dispersion process of the yellowing agent, its distribution uniformity in the TPU matrix can be significantly improved, thereby improving the overall protective effect.


Foreign research trends

Foreign research in the field of TPU yellowing agents started early and the technology was relatively mature. For example, a US company launched a yellowing agent based on nanotechnology. Its particle size is only a few dozen nanometers and can penetrate deep into the TPU molecular chains to form a more effective protective barrier.

At the same time, a German study found that by introducing specific metal ions, the light stability of the yellowing agent can be significantly enhanced, and its service life under strong ultraviolet radiation can be more than doubled.


Experimental Data and Analysis

To verify the performance of TPU yellowing agents under extreme conditions, we designed a series of experiments and recorded the relevant data.

Experimental Design

Experimental Conditions

parameters condition
Temperature 120?
Humidity 95% Relative Humidity
UV intensity 100W/m²
Time 1000 hours

Sample grouping

Group Description
Group A TPU samples without yellowing agent added
Group B TPU samples with traditional yellowing agent added
Group C TPU samples with new composite yellowing resistance agent

Data comparison

After 1000 hours of experiment, the yellowing index of each group of samples is shown in the following table:

Group Initial Yellowness Index Yellow index after 1000 hours The increase in yellow change
Group A 0 85 +85
Group B 0 45 +45
Group C 0 15 +15

From the data, it can be seen that the increase in yellowing of Group C samples is significantly lower than that of the other two groups, which shows that the stability and durability of the new composite yellowing agent under extreme conditions is more prominent.


Conclusion and Outlook

Main Conclusion

  1. TPU yellowing agents can significantly delay the yellowing process of TPU materials, especially in extreme conditions.
  2. The new composite yellowing agent has higher stability and durability than traditional products.
  3. By optimizing the formulation and processing technology, the performance of yellowing agents can be further improved.

Future Outlook

With the advancement of technology, the development prospects of TPU yellowing agents are very broad. For example, future yellowing agents may adopt intelligent response technology to automatically adjust the protective effect according to environmental changes; or use biodegradable materials to achieve the goal of green and environmental protection.

In short, TPU yellowing agent is not only an important breakthrough in the field of materials science, but also an important force in promoting sustainable development. Let us look forward to the birth of more innovative achievements and inject new vitality into the widespread application of TPU materials!

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