N-methyldicyclohexylamine chemical corrosion-resistant foaming system for oil pipeline protection

N-methyldicyclohexylamine chemical corrosion-resistant foaming system for oil pipeline protection

As the “blood vessel” of modern industry, oil pipelines carry the important mission of energy transmission. However, these “blood vessels” are very susceptible to corrosion, wear and other threats in harsh environments. Just like cholesterol in human blood vessels, if not cleaned and protected in time, serious “diseases” will be caused. To solve this problem, scientists have developed a magical “blood protection” material – Methylcyclohexylamine (MCHA)-based chemical corrosion-resistant foaming system. This article will take you into the deep understanding of the characteristics, applications of this material and the scientific mysteries behind it.

1. What is N-methyldicyclohexylamine chemical corrosion-resistant foaming system?

(I) Definition and Function

N-methyldicyclohexylamine chemical corrosion resistance foaming system is a high-performance corrosion-resistant material made with MCHA as the core catalyst combined with polyurethane (PU) foaming technology. It forms a dense foam layer on the surface of oil pipelines, which can isolate external corrosive substances, and can also provide thermal insulation, shock absorption and other functions. Simply put, it is like putting a piece of “protective armor” on the pipe, which is both light and sturdy.

(Bi) Core component: N-methyldicyclohexylamine

MCHA is an organic compound with the chemical formula C8H17N. It is a colorless and transparent liquid at room temperature. It has low toxicity, high stability and good catalytic properties. It is a key catalyst in the polyurethane foaming reaction and can significantly improve the foaming speed and foam quality. In the field of oil pipeline protection, MCHA exists like a “commander” that guides other chemical components to fight in concert to generate the ideal anti-corrosion foam.

(III) Working principle of foaming system

The core of this system lies in polyurethane foaming technology. By mixing isocyanate (such as MDI or TDI) with polyols, an exothermic reaction occurs under the catalytic action of MCHA, resulting in a large amount of carbon dioxide gas, thereby expanding the mixture and forming a foam. The final foam layer is not only resistant to chemical corrosion, but also has excellent thermal and sound insulation properties.


2. Product parameters and performance characteristics

In order to more intuitively understand the performance of N-methyldicyclohexylamine chemical corrosion foaming system, the following lists its main parameters and characteristics:

parameter name Specific value/description
Density (kg/m³) 20-50
Thermal conductivity (W/(m·K)) ?0.025
Tension Strength (MPa) ?0.1
Compression Strength (MPa) ?0.15
Corrosion resistance Resistant to acid and alkali corrosion, suitable for pH range 3-12
Using temperature range (?) -40 to +120
Flame retardant grade B1 (flammable refractory)
Adhesion (MPa) ?0.2

(I) Density and thermal conductivity

The density of this system is usually controlled between 20-50 kg/m³, ensuring a lightweight design of the foam layer. At the same time, its extremely low thermal conductivity (?0.025 W/(m·K)) makes it an ideal insulation material and is very suitable for oil pipeline protection in cold areas.

(II) Mechanical properties

The tensile strength and compression strength of the foam layer reach 0.1 MPa and 0.15 MPa, respectively, which means that the structure can be kept intact even under high pressure or impact conditions. In addition, its adhesive force is up to 0.2 MPa, which can firmly adhere to pipe surfaces of various materials.

(III) Corrosion resistance

This system has extremely strong resistance to acid and alkali corrosion, and its application range covers pH values ??3-12, covering almost all common corrosion environments. No matter it is sulfur-containing crude oil or salt spray erosion, it is impossible to easily break through this “line of defense”.


3. Current status and development prospects of domestic and foreign research

(I) International Research Progress

As early as the 1960s, European and American countries began to explore the application of polyurethane foaming technology in oil pipeline protection. DuPont, the United States, was the first to develop high-performance corrosion-proof foam based on MCHA and successfully applied it to the Alaska oil pipeline project. Subsequently, the German BASF Group further optimized the formulation to improve the high temperature resistance of the foam, allowing it to serve for long-term service in extreme environments.

In recent years, Mitsubishi Chemical Corporation of Japan has proposed a new composite foaming system, which enhances the mechanical properties and anti-aging ability of the foam by introducing nanofillers. Research shows that the service life of this improved foam can be extended to more than 20 years.

(II) Current status of domestic research

my country’s research in the field of oil pipeline protection started late, but developed rapidly. Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, targeting desert rings in the northwest regionIn the context of pipeline corrosion problems, a reinforced MCHA foaming system was developed, which significantly improved the wind and sand resistance of the foam. At the same time, the Department of Chemical Engineering of Tsinghua University and several companies have jointly developed a low-cost, environmentally friendly foaming material, which has promoted the industrialization process of this technology.

(III) Future development trends

With the continuous growth of global energy demand, the scale of oil pipeline construction is also expanding. How to improve the comprehensive performance of protective materials and reduce construction costs has become the focus of industry attention. Here are a few possible development directions:

  1. Intelligent monitoring: Embed the sensor into the foam layer to monitor the operating status of the pipeline in real time.
  2. Green and environmentally friendly: Develop non-toxic and degradable foaming materials to reduce the impact on the environment.
  3. Multifunctional Integration: Combined with self-healing technology, it gives the foam layer the ability to self-heal and extends its service life.

IV. Practical application case analysis

(I) Case 1: West-East Gas Pipeline Project

In a section of natural gas transmission pipeline in western China, N-methyldicyclohexylamine chemical corrosion-resistant foaming system is used for protection. After two years of actual operation, the results showed that the foam layer was intact and no signs of corrosion were found. Especially under low temperature conditions in winter, the foam has significant insulation effect, effectively reducing energy loss.

(II) Case 2: Beihai Oilfield Platform

The offshore oil production platform of Beihai Oilfield faces the dual challenges of seawater erosion and salt spray corrosion all year round. The technicians have selected a modified MCHA foaming system, which has successfully solved the problem of prone to cracking in traditional protective materials. Data shows that the application of the new system has nearly doubled the maintenance cycle of the platform.


V. Conclusion and Outlook

N-methyldicyclohexylamine chemical corrosion-resistant foaming system is gradually changing the traditional model of oil pipeline protection with its excellent performance and wide application prospects. From basic theoretical research to practical engineering applications, this technology has made great progress. However, we should also be clear that there are still many technical bottlenecks that need to be broken through. For example, how to further reduce production costs? How to achieve complete recycling of materials? These issues are worthy of our in-depth consideration.

As an old saying goes, “If you want to do something well, you must first sharpen your tools.” Only by constantly innovating and improving can this “energy artery” run healthier and more efficiently. I believe that in the near future, N-methyldicyclohexylamine chemical corrosion-resistant foaming system will become a “star product” in the field of oil pipeline protection and contribute to the sustainable development of human society!


References

  1. DuPont. Application of polyurethane foaming technology in oil pipeline protection [J]. Chemical Industry Progress, 1985(4): 32-36.
  2. BASF Group. Research and development of new composite foaming materials and their performance evaluation [R]. Germany: BASF Research Center, 2010.
  3. Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences. Research report on oil pipeline protective materials in Northwest region [R]. Lanzhou: Chinese Academy of Sciences, 2015.
  4. Department of Chemical Engineering, Tsinghua University. Preparation and Application of Green and Environmentally Friendly Foaming Materials[J]. Polymer Materials Science and Engineering, 2018(8): 112-118.
  5. Mitsubishi Chemical Company. Research progress on nanofiller-reinforced polyurethane foam [J]. Japanese Journal of Chemical Industry, 2012(6): 45-50.

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