Background and application of low-density sponge catalyst SMP
Sponge Metal Porous (SMP) is a new catalytic material, and has been widely used in the chemical, energy and environment fields in recent years. Its unique three-dimensional porous structure imparts its excellent physical and chemical properties, allowing it to exhibit excellent catalytic activity and selectivity in a variety of reactions. The main components of SMP are usually metals or metal oxides, such as nickel, copper, iron, cobalt, etc. These metals are prepared into sponge-like structures with high specific surface area and large porosity through special processes.
SMP development stems from the need for improved traditional catalysts. Traditional solid catalysts often have problems such as large mass transfer resistance and low utilization rate of active sites, resulting in low production efficiency and high cost. The porous structure of SMP can significantly reduce mass transfer resistance, increase the contact area between reactants and catalyst, thereby improving catalytic efficiency. In addition, SMP’s low density characteristics make it lighter in mass per unit volume, reducing transportation and storage costs while also reducing equipment load.
SMP has a wide range of applications, covering multiple fields such as petrochemicals, fine chemicals, and environmental protection governance. For example, during petroleum refining, SMP can be used for hydrocracking, desulfurization and other reactions, effectively improving the quality of oil products; in the field of fine chemicals, SMP can be used for organic synthesis, polymerization, etc., significantly shortening the reaction time and improving the product Yield; In terms of environmental protection management, SMP can be used for waste gas treatment, waste water treatment, etc., effectively remove harmful substances and reduce environmental pollution.
With the global emphasis on green chemical industry and sustainable development, SMP, as an efficient and environmentally friendly catalytic material, is gradually becoming the first choice for industrial production. This article will conduct in-depth analysis on how SMP can reduce production costs and improve efficiency in practical applications from the aspects of product parameters, production costs, efficiency improvement, etc., and discuss in detail with domestic and foreign literature.
Product parameters of low-density sponge catalyst SMP
The performance of the low-density sponge catalyst SMP is closely related to its physical and chemical parameters. In order to better understand the advantages of SMP, the following is a detailed introduction to its main product parameters:
1. Density
One of the big features of SMP is its low density. Typically, the density range of SMP is 0.1-0.5 g/cm³, which is much lower than the density of conventional catalysts (usually 3-7 g/cm³). Low density not only means that the catalyst mass per unit volume is lighter, but also makes SMP more economical during transportation and storage. In addition, low density helps reduce the mechanical load of the equipment and extend the service life of the equipment.
parameters | Unit | Scope |
---|---|---|
Density | g/cm³ | 0.1-0.5 |
2. Porosity
The high porosity of SMP is one of the key factors in its excellent performance. The porosity is usually between 80% and 95%, which means there are a large number of voids inside the SMP that can accommodate more reactants and products, promoting the mass transfer process. High porosity not only increases the contact area between the reactants and the catalyst, but also reduces mass transfer resistance, thereby accelerating the reaction rate.
parameters | Unit | Scope |
---|---|---|
Porosity | % | 80-95 |
3. Specific surface area
Specific surface area refers to the total surface area of ??a unit mass catalyst, which is an important indicator for measuring catalyst activity. The specific surface area of ??SMP is usually between 100-500 m²/g, which is much higher than the specific surface area of ??conventional catalysts (typically 10-50 m²/g). High specific surface area means more active sites, which helps to improve the selectivity and conversion of catalytic reactions.
parameters | Unit | Scope |
---|---|---|
Specific surface area | m²/g | 100-500 |
4. Average pore size
The average pore size of SMP is usually between 1-10 ?m, depending on its preparation process and application scenario. Larger pore sizes are conducive to the diffusion of macromolecular reactants and reduce mass transfer resistance, while smaller pore sizes help improve catalyst selectivity. Therefore, the pore size distribution of SMP can be optimized for different reaction requirements.
parameters | Unit | Scope |
---|---|---|
Average aperture | ?m | 1-10 |
5. Thermal Stability
SMP has good thermal stability and can be used in high temperature environmentsMaintain its structure and catalytic activity. Studies have shown that SMP can maintain high catalytic activity within the temperature range of 400-600°C, which makes it suitable for high-temperature reactions such as hydrocracking, desulfurization, etc. In addition, the thermal stability of SMP is also reflected in its anti-sintering ability, and even under long-term high-temperature operation, SMP will not undergo significant structural changes.
parameters | Unit | Scope |
---|---|---|
Thermal Stability | °C | 400-600 |
6. Chemical Stability
The chemical stability of SMP is also one of its important characteristics. Because its surface is rich in active metals or metal oxides, SMP can still maintain high catalytic activity in acidic, alkaline or oxidative environments. For example, under acidic conditions, SMP can maintain its catalytic activity by adjusting the oxidation state of the surface metal; in an oxidative environment, SMP can prevent metal loss by forming a stable oxide layer. This chemical stability makes SMP suitable for a variety of complex chemical reactions.
parameters | Unit | Scope |
---|---|---|
Chemical Stability | pH | 2-12 |
7. Mechanical strength
Although SMP has a low density, its mechanical strength is not inferior to that of conventional catalysts. Through the optimization of the preparation process, the mechanical strength of SMP can reach 1-5 MPa, which is sufficient to meet the operating requirements of stirring, flow and other in industrial production. In addition, the mechanical strength of the SMP can be further improved by adding appropriate support materials or modifiers to accommodate more demanding operating conditions.
parameters | Unit | Scope |
---|---|---|
Mechanical Strength | MPa | 1-5 |
8. Catalytic activity
The catalytic activity of SMP is one of its important performance indicators. Studies have shown that SMP exhibits excellent catalytic activity in various reactions, especially in reactions such as hydrogenation, oxidation, and reduction. For example, in hydrogen replenishmentIn the cracking reaction, SMP’s catalytic activity is 20%-50% higher than that of traditional catalysts and has higher selectivity. In addition, the catalytic activity of SMP is closely related to its metal components, pore structure and other factors, and its catalytic performance can be optimized by adjusting these parameters.
parameters | Unit | Scope |
---|---|---|
Catalytic Activity | mol/(g·h) | 0.1-1.0 |
Application of low-density sponge catalyst SMP in different fields
SMP, as an efficient catalytic material, has shown significant application advantages in many fields. The following are specific application cases of SMP in three major areas: petrochemical, fine chemical and environmental protection governance.
1. Petrochemical field
In the petrochemical field, SMP is widely used in hydrocracking, desulfurization, isomerization and other reactions, significantly improving the quality and yield of oil products. Here are some specific application cases:
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Hydrocracking: Hydrocracking is an important process for converting heavy crude oil into light fuel oil. Traditional hydrocracking catalysts have problems such as large mass transfer resistance and low utilization rate of active sites, resulting in low reaction efficiency. With its high porosity and large specific surface area, SMP can significantly reduce mass transfer resistance and increase the contact area between reactants and catalysts, thereby improving the conversion and selectivity of hydrocracking. Studies have shown that when SMP is used as a hydrocracking catalyst, the reaction conversion rate can be increased by 20%-30%, and the product yield also increases accordingly.
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Desulfurization: Sulfide is a common impurity in petroleum, which will reduce the quality of oil and pollute the environment. Traditional desulfurization catalysts are prone to inactivate at high temperatures, resulting in poor desulfurization effect. SMP has good thermal stability and chemical stability, can maintain high catalytic activity under high temperature environments, and effectively remove sulfides in petroleum. Experimental results show that the sulfur removal rate of SMP in the desulfurization reaction can reach more than 95%, which is far higher than the level of traditional catalysts.
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Isomerization: Isomerization is the process of converting linear alkanes into branched alkanes, which can increase the octane number of gasoline. The high specific surface area and abundant active sites of SMP make it exhibit excellent catalytic properties in isomerization reactions. The study found that when using SMP as an isomerization catalyst, the octane number of gasoline can be increased by 3-5 units, and the reaction time is shortened by about 50%.
2. Fine Chemicals Field
In the field of fine chemicals, SMP is widely used in organic synthesis, polymerization, drug synthesis and other processes, significantly improving the reaction efficiency and product quality. Here are some specific application cases:
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Organic Synthesis: SMP has wide application prospects in organic synthesis. For example, in olefin hydrogenation reactions, SMP can significantly improve the selectivity and conversion of the reaction. Studies have shown that when SMP is used as a catalyst, the conversion rate of the olefin hydrogenation reaction can reach more than 98%, and the amount of by-products is extremely small. In addition, SMP can also be used for hydrogenation of aromatic compounds, dehalogenation of halogenated hydrocarbons, and other reactions, and exhibit excellent catalytic properties.
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Polymerization: SMP also has important applications in polymerization. For example, during the synthesis of polypropylene, SMP as a catalyst can significantly increase the speed and yield of the polymerization reaction. The study found that when using SMP as a catalyst, the molecular weight distribution of polypropylene is more uniform and the product quality has been significantly improved. In addition, SMP can also be used in other types of polymerization reactions, such as polyethylene, polyethylene, etc., and exhibits good catalytic effects.
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Drug Synthesis: SMP also has important application value in drug synthesis. For example, during the synthesis of certain drug intermediates, SMP can significantly improve the selectivity and yield of the reaction. Studies have shown that when using SMP as a catalyst, the synthesis reaction time of certain drug intermediates was reduced by about 30%, and the amount of by-products was significantly reduced. In addition, SMP can also be used in the synthesis of chiral drugs, showing excellent stereoselectivity.
3. Environmental protection governance field
In the field of environmental protection management, SMP is widely used in waste gas treatment, waste water treatment, soil restoration and other processes, significantly improving the efficiency of pollutant removal. Here are some specific application cases:
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Exhaust Gas Treatment: SMP has important application value in exhaust gas treatment. For example, during the catalytic combustion of volatile organic compounds (VOCs), SMP can significantly improve combustion efficiency and reduce the emission of harmful gases. Studies have shown that when using SMP as a catalyst, the removal rate of VOCs can reach more than 99%, and the combustion temperature is 100-200°C lower than that of traditional catalysts, which significantly reduces energy consumption. In addition, SMP can also be used to remove harmful gases such as nitrogen oxides (NOx), sulfur dioxide (SO?), and exhibit excellent catalytic performance.
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Wastewater treatment: SMP is in wasteThere are also important applications in water treatment. For example, during the treatment of printing and dyeing wastewater, SMP can effectively remove organic dyes and heavy metal ions from the water. Studies have shown that when using SMP as a catalyst, the removal rate of organic dyes in the printing and dyeing wastewater can reach more than 95%, and the removal rate of heavy metal ions can also reach more than 90%. In addition, SMP can also be used for other types of wastewater treatment, such as papermaking wastewater, electroplating wastewater, etc., showing good treatment effects.
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Soil Repair: SMP also has certain application prospects in soil restoration. For example, during the repair of contaminated soil, SMP can effectively remove organic pollutants and heavy metals from the soil. Studies have shown that when SMP is used as a repair agent, the degradation rate of organic pollutants in the soil can reach more than 80%, and the fixation rate of heavy metals can also reach more than 70%. In addition, SMP can also be used for other types of soil repair, such as oil-contaminated soil, pesticide-contaminated soil, etc., showing good repair results.
A Ways to Reduce Production Costs by Low-Density Sponge Catalyst SMP
SMP, a low-density sponge catalyst, not only outperforms traditional catalysts in performance, but also significantly reduces production costs through various means. The following are the specific measures for SMP to reduce costs:
1. Reduce raw material consumption
The low density properties of SMP make its mass lighter per unit volume, so the amount of catalyst required is greatly reduced in the same volume of reactors. According to experimental data, when using SMP as a catalyst, the amount of the catalyst is only 1/3 to 1/5 of that of the conventional catalyst. This not only reduces the procurement costs of raw materials, but also reduces the costs of transportation and storage. In addition, the high porosity and large specific surface area of ??SMP enable it to fully utilize each active site during the reaction, further improving the utilization rate of the catalyst and reducing waste.
2. Reduce equipment investment
The low density and high porosity of SMP make it less demanding on the equipment during the reaction. First, SMP’s lightweight properties reduce the mechanical load of the equipment, extend the service life of the equipment, and reduce the cost of equipment maintenance and replacement. Secondly, the high porosity and large specific surface area of ??SMP enable reactants and products to enter and exit the catalyst more smoothly, reducing mass transfer resistance and reducing the demand for high-pressure equipment. Research shows that when using SMP as a catalyst, the pressure of the reactor can be reduced by 20%-30%, thereby reducing investment in high-pressure equipment.
3. Reduce energy consumption
The high catalytic activity and good thermal stability of SMP enable it to significantly reduce energy consumption during the reaction. First, the high catalytic activity of SMP allows the reaction to be carried out at lower temperatures, reducing the energy consumption of the heating equipment. For example, in hydrocracking reactions, when SMP is used as a catalyst, the reaction temperature can be reduced by 50-100°C, thereby reducing the power consumption of the heating equipment. Secondly, the high porosity and large specific surface area of ??SMP enable the reactants and products to diffuse more quickly, reducing the energy consumption of the stirring equipment. Studies have shown that when using SMP as a catalyst, the power consumption of the stirring equipment can be reduced by 30%-50%.
4. Shorten the reaction time
The high porosity and large specific surface area of ??SMP enable the reactants and products to diffuse more rapidly, thereby shortening the reaction time. For example, in organic synthesis reactions, when SMP is used as a catalyst, the reaction time can be shortened by 50%-70%, thereby improving production efficiency. In addition, the high catalytic activity of SMP allows the reaction to achieve a higher conversion rate in a shorter time, further shortening the reaction cycle. Studies have shown that when using SMP as a catalyst, the reaction time of certain reactions can be shortened from hours to minutes, significantly improving production efficiency.
5. Improve product yield
The high selectivity and high catalytic activity of SMP enable it to significantly improve product yield during the reaction. For example, in hydrocracking reaction, when using SMP as a catalyst, the yield of light fuel oil can be increased by 10%-20%, thereby increasing the added value of the product. In addition, the high selectivity of SMP makes the amount of by-products produced very small, reducing the difficulty of subsequent separation and purification, and further reducing production costs. Studies have shown that when using SMP as a catalyst, the by-product generation of certain reactions can be reduced by 50%-80%, significantly improving the purity and quality of the product.
6. Extend the life of the catalyst
The high thermal stability and chemical stability of SMP enable it to maintain high catalytic activity for a long time during the reaction, thereby extending the service life of the catalyst. Studies have shown that SMP can maintain high catalytic activity under harsh conditions such as high temperature, high pressure, acidic, alkaline, etc., and the service life of the catalyst can be extended by 2-3 times. This not only reduces the frequency of catalyst replacement, reduces the procurement cost of catalysts, but also reduces the downtime caused by catalyst deactivation, further improving production efficiency.
A Ways to Improve Efficiency of Low-Density Sponge Catalyst SMP
In addition to reducing production costs, SMP also significantly improves production efficiency through various means. The following are the specific measures for SMP to improve efficiency:
1. Accelerate the mass transfer process
The high porosity and large specific surface area of ??SMP enable the reactants and products to diffuse more rapidly, thereby accelerating the mass transfer process. Studies have shown that the mass transfer coefficient of SMP is 2-3 times higher than that of traditional catalysts, which allows reactants to reach the active site faster and products can leave the catalyst surface faster, avoiding the occurrence of accumulation. In addition, the high porosity of SMP allows reactants and products to be distributed more evenly within the catalyst, reducing mass transfer resistance.The mass transfer efficiency is further improved. Experimental results show that when using SMP as a catalyst, the mass transfer efficiency of certain reactions can be increased by 50%-80%, significantly shortening the reaction time.
2. Increase the reaction rate
The high catalytic activity of SMP results in a significant increase in the reaction rate. Studies have shown that SMP has a catalytic activity of 20%-50% higher than that of conventional catalysts, which allows the reaction to be completed in a shorter time. In addition, the high selectivity of SMP makes the incidence of side reactions extremely low, further increasing the reaction rate. For example, in hydrocracking reaction, when using SMP as a catalyst, the reaction rate can be increased by 30%-50%, thereby improving production efficiency. In addition, the high catalytic activity of SMP allows the reaction to be carried out at lower temperatures, reducing the energy consumption of the heating equipment and further improving the production efficiency.
3. Improve selectivity
The high selectivity of SMP results in very small amount of by-product generation, thereby improving the selectivity of the target product. Studies have shown that SMP can reach more than 95% selectivity in some reactions, which is much higher than the level of traditional catalysts. For example, in organic synthesis reactions, when SMP is used as a catalyst, the selectivity of the target product can be increased by 20%-30%, thereby reducing the difficulty of subsequent separation and purification and further improving production efficiency. In addition, the high selectivity of SMP makes the reaction conditions more gentle, reduces the requirements for the equipment, and further improves the production efficiency.
4. Reduce the reaction temperature
The high catalytic activity of SMP allows the reaction to be carried out at lower temperatures, thereby reducing the reaction temperature. Studies have shown that when using SMP as a catalyst, the reaction temperature of some reactions can be reduced by 50-100°C, which not only reduces the energy consumption of the heating equipment, but also reduces the requirements for the equipment. In addition, the lower reaction temperature makes the reaction conditions more gentle, reduces the occurrence of side reactions, and further improves the selectivity and yield of the reaction. Experimental results show that when using SMP as a catalyst, the reaction temperature of some reactions can be reduced by 50-100°C, significantly improving production efficiency.
5. Shorten the reaction cycle
The high catalytic activity and high selectivity of SMP enable the reaction to be completed in a shorter time, thereby shortening the reaction cycle. Studies have shown that when using SMP as a catalyst, the reaction time of certain reactions can be shortened from hours to minutes, significantly improving production efficiency. In addition, the high porosity and large specific surface area of ??SMP enable the reactants and products to diffuse more rapidly, further shortening the reaction cycle. Experimental results show that when using SMP as a catalyst, the reaction time of some reactions can be shortened by 50%-70%, significantly improving production efficiency.
6. Improve equipment utilization
The high catalytic activity and high selectivity of SMP enable the reaction to proceed at lower temperatures and pressures, thereby reducingLower equipment requirements. Research shows that when using SMP as a catalyst, the pressure of the reactor can be reduced by 20%-30%, and the energy consumption of the heating equipment can be reduced by 30%-50%, which not only reduces the investment and maintenance costs of the equipment, but also improves the equipment’s Utilization. In addition, the high porosity and large specific surface area of ??SMP enable the reactants and products to diffuse more quickly, reduce mass transfer resistance, and further improve the utilization rate of the equipment. Experimental results show that when using SMP as a catalyst, the utilization rate of the equipment can be increased by 20%-30%, significantly improving production efficiency.
Conclusion and Outlook
To sum up, the low-density sponge catalyst SMP has shown significant advantages in many fields due to its unique physical and chemical characteristics. The low density, high porosity, large specific surface area and other characteristics not only improve its catalytic performance, but also significantly reduces production costs and improves production efficiency through various channels. Specifically, SMP reduces production costs by reducing raw material consumption, reducing equipment investment, reducing energy consumption, shortening reaction time, improving product yield, and extending catalyst life; by accelerating the mass transfer process, increasing reaction rate, and improving selectivity , reduce reaction temperature, shorten reaction cycle, and improve equipment utilization, etc. to improve production efficiency.
In the future, with the continuous optimization of SMP preparation process and the advancement of technology, the application scope of SMP will be further expanded. Researchers can further optimize its catalytic performance and expand its application fields by regulating the pore structure, metal components, surface properties and other parameters of SMP. In addition, SMP’s green manufacturing and sustainable development will also become the focus of future research. By developing more environmentally friendly preparation methods to reduce energy consumption and waste emissions in SMP production, the widespread application of SMP in industrial production will be further promoted.
In short, SMP, as an efficient and environmentally friendly catalytic material, is gradually becoming the first choice for industrial production. With the continuous advancement of technology and the continuous expansion of applications, SMP will surely play a more important role in the future chemical, energy and environmental protection fields.
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