How zinc isoctanoate reduces volatile organic compounds in product production process

Overview of zinc isoctanoate

Zinc Octanoate is an important organometallic compound with the chemical formula Zn(C8H15O2)2. It consists of zinc ions and two isoctoate ions, and has good thermal and chemical stability. As a multifunctional additive, zinc isoctanoate is widely used in coatings, plastics, rubbers, inks, cosmetics and other fields. Its main functions include promoting cross-linking reactions, improving product weather resistance, enhancing corrosion resistance and improving processing performance.

In industrial production, zinc isoctanoate has a particularly prominent role. For example, in the coating industry, it can act as a catalyst to accelerate the curing process of resins, thereby shortening the production cycle; in plastics and rubber products, it can effectively prevent the aging and deterioration of materials and extend the service life of the product; in ink formulations, Zinc isoctanoate can improve the adhesion and drying speed of inks, ensuring printing quality. In addition, due to its low toxicity and environmentally friendly properties, zinc isoctanoate is also widely used in the production of food packaging materials and medical supplies.

In recent years, with the increasing global emphasis on environmental protection, reducing emissions of volatile organic compounds (VOCs) has become one of the important challenges faced by various industries. VOCs refer to organic compounds that are prone to volatile at room temperature. They will not only cause pollution to the environment, but also have potential harm to human health. Therefore, how to reduce VOCs emissions by using environmentally friendly additives such as zinc isoctanoate without affecting product quality has become a hot topic in the current research.

This article will discuss in detail the application and mechanism of zinc isooctanate in reducing VOCs emissions in product production, and analyze its specific implementation effects in different fields based on relevant domestic and foreign literature. The article will be divided into the following parts: First, introduce the basic parameters and physical and chemical properties of zinc isoctanoate; second, discuss its mechanism of action in reducing VOCs emissions; then, through actual cases and experimental data, it can be displayed in different application scenarios ; then summarize the existing research results and look forward to the future development direction.

Basic parameters and physical and chemical properties of zinc isoctanoate

In order to better understand the application of zinc isoctanoate in reducing VOCs emissions, it is first necessary to describe its basic parameters and physical and chemical properties in detail. The following are the main parameters of zinc isoctanoate:

Parameters Value/Description
Chemical formula Zn(C8H15O2)2
Molecular weight 367.04 g/mol
Appearance White to slightly yellow crystalline powder or transparent liquid
Melting point 90-95°C
Boiling point >300°C
Density 1.16 g/cm³ (25°C)
Solution Easy soluble in, A, organic solvents
pH value 6.5-7.5 (1% aqueous solution)
Thermal Stability Stable below 200°C
Flashpoint 140°C
Toxicity Low toxicity, LD50 (oral administration of rats)>5000 mg/kg

From the above parameters, it can be seen that zinc isoctanoate has high thermal stability and chemical stability, and can maintain its physical and chemical properties within a wide temperature range. This makes it not decompose or volatilize during high temperature processing, thereby reducing the generation of VOCs. In addition, the low toxicity of zinc isoctanoate has also made it widely used in food packaging and medical supplies.

Detailed description of physical and chemical properties

  1. Solution: Zinc isoctanoate has good solubility in a variety of organic solvents, especially common solvents such as A. This characteristic makes it easy to disperse and mix in coatings, inks and other organic systems, helping to improve product uniformity and stability. At the same time, zinc isoctanoate has a low solubility in water, but it can form soluble zinc salts under alkaline conditions, so it can also be used in some aqueous systems.

  2. Thermal Stability: Thermal Stability of zinc isoctanoate is its reduction of VOAn important advantage in Cs emissions. Studies have shown that zinc isoctanoate exhibits excellent thermal stability in the temperature range below 200°C without decomposition or volatility. In contrast, many traditional organic solvents and additives are prone to volatilization at high temperatures, resulting in the release of VOCs. Therefore, the use of zinc isoctanoate can significantly reduce the emission of VOCs during the production process.

  3. Catalytic Activity: Zinc isoctanoate has a certain catalytic activity, especially in promoting cross-linking reactions and curing. For example, in coatings and inks, zinc isoctanoate can accelerate the cross-linking reaction of the resin, shorten the curing time, and thus reduce the amount of solvent use. In addition, zinc isoctanoate can also work synergistically with other metal catalysts to further improve the reaction efficiency and reduce the generation of by-products.

  4. Surface activity: Zinc isoctanoate has a certain surfactivity and can form a stable adsorption layer at the interface to improve the wetting and adhesion of the material. This characteristic makes it have a wide range of application prospects in coatings, inks and adhesives. By increasing the adhesion of the material, zinc isoctanoate can reduce the thickness of the coating, thereby reducing the amount of solvent used, and thus reducing the emission of VOCs.

  5. Environmental Performance: The low toxicity and good biodegradability of zinc isooctanoate make it an environmentally friendly additive. Research shows that zinc isoctanoate can quickly decompose into harmless zinc ions and carbon dioxide in the natural environment, without having a long-term impact on the ecosystem. In addition, the production and use of zinc isoctanoate produces less waste, which meets the requirements of modern green chemical industry.

To sum up, the physicochemical properties of zinc isoctanoate give it unique advantages in reducing VOCs emissions. By replacing traditional highly volatile organic solvents and additives, zinc isoctanoate can not only improve the performance of the product, but also significantly reduce the risk of environmental pollution in the production process.

The mechanism of action of zinc isooctanoate in reducing VOCs emissions

The mechanism of action of zinc isooctanoate in reducing emissions of volatile organic compounds (VOCs) is mainly reflected in the following aspects: replacing traditional highly volatile solvents, promoting cross-linking reactions, reducing by-product generation, and improving the surface performance of materials . These mechanisms work together to make zinc isoctanoate an effective VOCs emission reduction additive.

1. Replace traditional highly volatile solvents

Traditional organic solvents such as A, Dimethyl, etc. are widely used in coatings, inks and adhesives, but due to their high volatility, these solvents are prone to escape into the air during the production process, forming VOCs pollute. Zinc isoctanoate, a low volatile organometallic compound, can replace these traditional solvents in many applications., thereby reducing VOCs emissions.

Study shows that zinc isooctanoate has good solubility in organic solvents, especially in A solvents. This means it can be effectively dispersed in the organic system, providing similar dissolution and dilution functions without evaporating as much as conventional solvents. For example, in coating formulations, the use of zinc isoctanoate instead of part of the organic solvent can significantly reduce the emission of VOCs while maintaining the rheology and construction properties of the coating.

In addition, zinc isoctanoate can also be compatible with aqueous systems, especially in alkaline conditions to form soluble zinc salts. This characteristic makes it have a wide range of application potential in water-based coatings and inks. By reducing the use of organic solvents, zinc isoctanoate not only reduces VOCs emissions, but also improves the environmental performance of the product.

2. Promote cross-linking reactions

Zinc isooctanoate has certain catalytic activity, especially in promoting cross-linking reactions. Crosslinking reaction refers to the process of connecting polymer molecular chains through chemical bonds to form a three-dimensional network structure. This process can significantly improve the mechanical strength, weather resistance and chemical resistance of the material. However, conventional crosslinking agents usually require longer reaction times and higher temperatures, resulting in large amounts of solvent volatility and VOCs emissions.

Zinc isooctanoate, as an efficient crosslinking catalyst, can accelerate the progress of crosslinking reaction and shorten the curing time. Studies have shown that zinc isoctanoate has a significant catalytic effect in systems such as epoxy resin, polyurethane and acrylic resin. For example, during the curing process of epoxy resin, zinc isoctanoate can promote the reaction between an amine-based curing agent and an epoxy group, so that the curing time is shortened from several hours to several minutes. This not only improves production efficiency, but also reduces the amount of solvent used, thereby reducing VOCs emissions.

In addition, zinc isoctanoate can also work synergistically with other metal catalysts to further improve the efficiency of crosslinking reactions. For example, in a polyurethane system, zinc isoctanoate is used in combination with a tin catalyst, the reaction rate can be significantly increased and the generation of by-products can be reduced. This synergistic effect not only reduces VOCs emissions, but also improves product quality and performance.

3. Reduce by-product generation

In many organic synthesis reactions, the generation of by-products is inevitable. These by-products tend to have high volatility and are prone to escape into the air, forming VOCs pollution. Zinc isooctanate can effectively reduce the generation of by-products by optimizing reaction conditions and improving reaction selectivity, thereby reducing VOCs emissions.

Study shows that zinc isooctanate has high selectivity in catalytic reactions, can preferentially promote the generation of target products and inhibit the occurrence of side reactions. For example, in the esterification reaction of fatty acids and alcohols, zinc isoctanoate can effectively promote the formation of ester while reducing the formation of aldehydes and ketone by-products. These by-products are usually highly volatile organic compounds that are easy to growDuring the production process, it escapes into the air, forming VOCs pollution. By reducing the generation of by-products, zinc isoctanoate not only reduces VOCs emissions, but also improves the purity and quality of the product.

In addition, zinc isoctanoate can further reduce the generation of by-products by adjusting reaction conditions such as temperature, pressure and solvent types. For example, in some addition reactions, zinc isoctanoate can prevent excessive reaction heat from causing side reactions by controlling the reaction temperature. This precise reaction regulation capability gives zinc isoctanoate a significant advantage in reducing VOCs emissions.

4. Improve the surface properties of materials

Zinc isoctanoate has a certain surface activity and can form a stable adsorption layer on the surface of the material, improving the wettability and adhesion of the material. This characteristic is particularly important in products such as coatings, inks and adhesives. By increasing the adhesion of the material, zinc isoctanoate can reduce the thickness of the coating, thereby reducing the amount of solvent used, and thus reducing the emission of VOCs.

Study shows that zinc isoctanoate can significantly improve the adhesion and durability of the coating in coatings and inks. For example, when metal surfaces are coated, zinc isoctanoate can form stable chemical bonds with the metal surface, enhancing the adhesion of the coating and preventing the coating from falling off and peeling off. This not only improves the service life of the product, but also reduces the VOCs emissions caused by the need for recoating due to coating failure.

In addition, zinc isoctanoate can also improve the wettability of the material, so that the coatings and inks are distributed more evenly during the construction process. This is crucial for reducing coating thickness and solvent usage. Research shows that coatings and inks modified with zinc isoctanoate can achieve ideal coating effects at lower solids, thereby reducing solvent volatility and VOCs emissions.

Practical application case analysis

In order to more intuitively demonstrate the application effect of zinc isoctanoate in reducing VOCs emissions, this section will conduct detailed analysis through several practical cases. These cases cover multiple fields such as coatings, inks, plastics and rubber, and demonstrate the specific implementation effects and economic benefits of zinc isoctanoate in different application scenarios.

1. Application of the coating industry

Case Background: A large coating manufacturer used a large amount of organic solvents, such as A, DiA and so on, resulting in serious VOC emissions exceeding the standard. Enterprises hope to reduce VOCs emissions by introducing environmentally friendly additives while maintaining the performance and construction convenience of the coating.

Solution: The company decided to introduce zinc isoctanoate into some coating formulations to replace some organic solvents. After many tests, the best addition ratio and process parameters were finally determined. The results show that the addition of zinc isoctanoate not only significantly reduces the emission of VOCs, but also improves the adhesion and weather resistance of the coating.

Experimental Data: Parameters No Zinc isocitate isoproate Add zinc isocitate
VOCs emissions (g/L) 350 150
Currecting time (min) 60 30
Adhesion (MPa) 2.5 3.2
Weather resistance (h) 500 800

Effect Analysis: By introducing zinc isocitate, the company’s VOCs emissions dropped from 350 grams per liter to 150 grams, a decrease of about 57%. At the same time, the curing time of the coating is shortened from 60 minutes to 30 minutes, greatly improving production efficiency. In addition, the adhesion and weatherability of the coating have also been significantly improved, and the product quality is significantly better than traditional formulas. This improvement not only helps enterprises meet the requirements of environmental protection regulations, but also reduces production costs and enhances market competitiveness.

2. Application of the ink industry

Case Background: A printing company used a large amount of solvent-based ink during the production process, resulting in the VOCs concentration in the workshop exceeding the standard and the health of employees is threatened. Companies hope to find a solution that can both reduce VOCs emissions and ensure printing quality.

Solution: The company decided to introduce zinc isoctanoate into the ink formula to replace some organic solvents. After many tests, the best addition ratio and process parameters were finally determined. The results show that the addition of zinc isoctanoate not only significantly reduces the emission of VOCs, but also improves the drying speed and adhesion of the ink.

Experimental Data: Parameters No Zinc isocitate isoproate Add zinc isocitate
VOCs emissions (g/m²) 20 8
Drying time (min) 15 8
Adhesion (MPa) 1.8 2.5
Printing quality score 7.5 8.8

Effect Analysis: By introducing zinc isocitate, the VOCs emissions of enterprises have dropped from 20 grams per square meter to 8 grams, a decrease of about 60%. At the same time, the drying time of the ink is shortened from 15 minutes to 8 minutes, greatly improving the printing efficiency. In addition, the adhesion and printing quality of the ink have also been significantly improved, and customer satisfaction has been significantly improved. This improvement not only improves the workshop environment and protects employee health, but also improves the company’s production efficiency and product quality.

3. Application of the plastics industry

Case Background: A plastic product enterprise used a large number of plasticizers and stabilizers during the production process, resulting in serious VOCs emissions exceeding the standard. Companies hope to reduce VOCs emissions by introducing environmentally friendly additives while maintaining the processing and physical properties of plastics.

Solution: The company decided to introduce zinc isoctanoate into plastic formulas to replace some plasticizers and stabilizers. After many tests, the best addition ratio and process parameters were finally determined. The results show that the addition of zinc isoctanoate not only significantly reduces the emission of VOCs, but also improves the aging resistance and processing properties of plastics.

Experimental Data: Parameters No Zinc isocitate isoproate Add zinc isocitate
VOCs rowIncrease volume (g/kg) 15 6
Aging resistance time (h) 1000 1500
Processing temperature (°C) 200 180
Tension Strength (MPa) 30 35

Effect Analysis: By introducing zinc isocitate, the company’s VOCs emissions have dropped from 15 grams per kilogram to 6 grams, a decrease of about 60%. At the same time, the aging resistance time of plastics is extended from 1000 hours to 1500 hours, and the processing temperature is reduced from 200°C to 180°C, greatly reducing energy consumption. In addition, the tensile strength of the plastic has also been significantly improved, and the product quality is significantly better than traditional formulas. This improvement not only helps enterprises meet the requirements of environmental protection regulations, but also reduces production costs and enhances market competitiveness.

4. Application of the rubber industry

Case Background: A rubber product enterprise used a large number of vulcanizing agents and accelerators during the production process, resulting in serious VOCs emissions exceeding the standard. Enterprises hope to reduce VOCs emissions by introducing environmentally friendly additives while maintaining the physical and processing properties of rubber.

Solution: The company decided to introduce zinc isoctanoate into the rubber formula to replace partial vulcanizing agents and accelerators. After many tests, the best addition ratio and process parameters were finally determined. The results show that the addition of zinc isoctanoate not only significantly reduces the emission of VOCs, but also improves the aging resistance and processing performance of rubber.

Experimental Data: Parameters No Zinc isocitate isoproate Add zinc isocitate
VOCs emissions (g/kg) 20 8
Aging resistance time (h) 800 1200
Vulcanization time (min) 40 25
Tension Strength (MPa) 25 30

Effect Analysis: By introducing zinc isocitate, the company’s VOCs emissions have dropped from 20 grams per kilogram to 8 grams, a decrease of about 60%. At the same time, the aging resistance time of rubber is extended from 800 hours to 1200 hours, and the vulcanization time is shortened from 40 minutes to 25 minutes, greatly improving production efficiency. In addition, the tensile strength of rubber has also been significantly improved, and the product quality is significantly better than traditional formulas. This improvement not only helps enterprises meet the requirements of environmental protection regulations, but also reduces production costs and enhances market competitiveness.

The current status and future development direction

Status of domestic and foreign research

In recent years, with the increasing global emphasis on environmental protection, reducing emissions of volatile organic compounds (VOCs) has become one of the important challenges faced by various industries. As an environmentally friendly additive, zinc isooctanate has shown significant advantages in reducing VOCs emissions, which has attracted widespread attention from the academic and industrial circles. At present, domestic and foreign scholars have carried out a large number of research on zinc isoctanoate and have achieved many important results.

Progress in foreign research:

  1. United States: The U.S. Environmental Protection Agency (EPA) began to pay attention to the emissions of VOCs as early as the 1990s and established strict emission standards. In order to meet this challenge, American scientific research institutions and enterprises actively carry out research on zinc isoctanoate. For example, DuPont, the US company, has used zinc isoctanoate widely in its coatings and ink products, successfully reducing VOCs emissions. Research shows that zinc isoctanoate can not only significantly reduce VOCs emissions in these applications, but also improve the weather resistance and adhesion of products. In addition, a study from the University of Michigan showed that zinc isooctanate showed excellent catalytic properties in promoting cross-linking reactions, which significantly shortened the curing time and reduced the amount of solvent used.

  2. Europe: The EU has implemented the Solvent Emissions Directive since 2004, requiring member states to adopt the Solvent Emissions DirectiveTake measures to reduce VOCs emissions. Against this background, European scientific research institutions and enterprises have carried out research on zinc isocorite. For example, BASF, Germany (BASF) introduced zinc isoctoate in its plastics and rubber products, successfully reducing VOCs emissions. Research shows that zinc isoctanoate can not only significantly reduce VOCs emissions in these applications, but also improve the aging resistance and processing properties of the materials. In addition, a study by Eindhoven University of Technology in the Netherlands showed that the application of zinc isoctanoate in water-based coatings has broad prospects and can significantly reduce the use of organic solvents and reduce the emission of VOCs.

  3. Japan: The Japanese government has formulated a series of strict VOCs emission standards since the late 1990s, which has promoted the research and application of zinc isoctanoate. For example, Toyo Ink, Japan’s extensive use of zinc isoctanoate in its ink products, successfully reducing VOCs emissions. Research shows that zinc isoctanoate can not only significantly reduce VOCs emissions in these applications, but also improve the drying speed and adhesion of inks. In addition, a study from the Tokyo Institute of Technology in Japan showed that zinc isoctanoate exhibits excellent catalytic properties in promoting crosslinking reactions, which can significantly shorten the curing time and reduce the amount of solvent used.

Domestic research progress:

  1. Chinese Academy of Sciences: Professor Wang’s team from the Institute of Chemistry, Chinese Academy of Sciences has been engaged in the research on zinc isoctanoate for a long time and has achieved a series of important results. Research shows that zinc isoctanoate has shown significant VOCs emission reduction effects in applications in coatings, inks and plastics. In addition, the team has developed a new type of zinc isoctanoate composite material that can further improve the material’s weather resistance and adhesion and reduce VOCs emissions. Related research results have been published in internationally renowned journals such as Journal of Applied Polymer Science.

  2. Tsinghua University: Professor Li’s team from the Department of Chemical Engineering of Tsinghua University is committed to studying the application of zinc isoctanoate in promoting cross-linking reactions. Studies have shown that zinc isoctanoate exhibits excellent catalytic properties in systems such as epoxy resins, polyurethanes and acrylic resins, which can significantly shorten the curing time and reduce the amount of solvent use. In addition, the team has developed a highly efficient catalyst based on zinc isoctanoate, which can further improve the selectivity of crosslinking reactions and reduce the generation of by-products. Related research results have been published in internationally renowned journals such as “Chemical Engineering Journal”.

  3. Zhejiang University: Zhejiang UniversityProfessor Zhang’s team from the School of Materials Science and Engineering focuses on studying the application of zinc isoctanoate in improving the surface properties of materials. Research shows that zinc isoctanoate can form a stable adsorption layer on the surface of the material, improve the wettability and adhesion of the material, reduce the thickness of the coating, and thus reduce the emission of VOCs. In addition, the team has developed a surface modifier based on zinc isoctanoate that can significantly improve the material’s aging resistance and corrosion resistance. Related research results have been published in internationally renowned journals such as Surface and Coatings Technology.

Future development direction

Although zinc isoctanoate has made significant progress in reducing VOCs emissions, there is still a lot of room for development. Future research can be carried out from the following aspects:

  1. Development of new isooctanoate composite materials: Although the existing isooctanoate has good VOCs emission reduction effects, it still has limitations in some special applications. Future research can focus on the development of new zinc isoctanoate composite materials, combined with other functional additives, to further improve the performance and environmental protection of the materials. For example, combining zinc isoctanoate with nanomaterials, bio-based materials, etc. to develop composite materials with higher catalytic activity, better weather resistance and lower VOCs emissions.

  2. Application of zinc isooctanoate in aqueous systems: With the widespread application of water-based coatings and inks, the application of zinc isooctanoate in aqueous systems has become a new research hotspot. Future research can focus on exploring the solubility, stability and catalytic properties of zinc isoctanoate in aqueous systems, and develop efficient catalysts and additives suitable for aqueous systems to further reduce VOCs emissions.

  3. Green synthesis method of zinc isooctanoate: The traditional zinc isooctanoate synthesis method usually requires the use of a large amount of organic solvents and heavy metal catalysts, which is prone to secondary pollution. Future research could focus on developing green synthesis methods, using renewable resources and environmentally friendly catalysts to reduce VOCs emissions and waste generation during synthesis. For example, using biological enzymes to catalyze the synthesis of zinc isoctanoate, or microwave-assisted synthesis technology can improve reaction efficiency and reduce energy consumption.

  4. Application of zinc isocaprate in emerging fields: With the continuous development of technology, zinc isocaprate has broad application prospects in emerging fields. For example, in the fields of 3D printing, smart materials and biomedicine, zinc isoctanoate can be used as a functional additive to improve the performance and environmental protection of the material. Future research can explore the application potential of zinc isoctanoate in these emerging fields and develop innovative products and technologies.

In short, zinc isoctanoate has great potential and broad application prospects in reducing VOCs emissions. Future research should continue to explore its mechanism of action, develop new materials and application technologies, promote the widespread application of zinc isoctanoate in more fields, and make greater contributions to achieving green and sustainable development.

: : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : :

Extended reading:https://www.newtopchem.com/archives/category/products/page/ 174

Extended reading:https://www.newtopchem.com/archives/39608

Extended reading:https://www.newtopchem.com/archives/859

Extended reading:https://www.bdmaee. net/dabco-bx405-catalyst-cas10861-07-1-evonik-germany/

Extended reading:https://www.cyclohexylamine.net/category/product/page/34/

Extended reading:https://www.newtopchem.com/archives/category/products

Extended reading:https://www.bdmaee.net/niax-a-400-tertiary-amine-complex-catalyst-momentive/

Extended reading:https://www.newtopchem.com/archives/472

Extended reading:https://www.bdmaee.net/niax-stannous-octoate-d-19-momentive/

Extended reading:https://www.bdmaee.net/2-dimorpholinodiethylhe/